Modification of margarine fats by enzymatic interesterification: Evaluation of a solid-fat-content-based exponential model with two groups of oil blends

Lipozyme TL IM-catalyzed interesterification for the modification of margarine fats was carried out in a batch reactor at 70°C with a lipase dosage of 4%. Solid fat content (SFC) was used to monitor the reaction progress. Lipase-catalyzed interesterification, which led to changes in the SFC, was assumed to be a first-order reversible reaction. Accordingly, the change in SFC vs. reaction time was described by an exponential model. The model contained three parameters, each with a particular physical or chemical meaning: (i) the initial SFC (SFC₀), (ii) the change in SFC (ΔSFC) from the initial to the equilibrium state, and (iii) the reaction rate constant value (k). SFC_o and ΔSFC were related to only the types of blends and the blend ratios. The rate constant k was related to lipase activity on a given oil blend. Evaluation of the model was carried out with two groups of oil blends, i.e., palm stearin/coconut oil in weight ratios of 90∶10, 80∶20, and 70∶30, and soybean oil/fully hydrogenated soybean oil in weight ratios of 80∶20, 65∶35, and 50∶50. Correlation coefficients higher than 0.99 between the experimental and predicted values were observed for SFC at temperatures above 30°C. The model is useful for predicting changes in the SFC during lipase-catalyzed interesterification with a selected group of oil blends. It also can be used to control the process when particular SFC values are targeted.     

催化湿式氧化处理农药废水的研究

利用担载型双金属活性组分催化剂，考察了反应温度、压力、进料空速和V（空气）：V（H2O）（体积比）等反应条件对催化湿式氧化处理某农药废水效果的影响。对于该种废水，在4．2MPa，245℃，空速为2．0h^-1，V（空气）：V（H2O）＝300的反应条件下，废水的COD去除率可达到91．3％。经处理后废水的BOD5／COD＞0．5，说明其可生化性能良好。     

PC／TPU共混物的流变性能

用毛细管流变仪研究了聚碳酸酯（ＰＣ）及聚碳酸酯／热塑性聚氨酯弹性体（ＰＣ／ＴＰＵ）共混物的流变性能。实验结果表明：ＰＣ熔体粘度对剪切速率（γ）不敏感，而对温度（Ｔ）敏感。温度升高，ＰＣ粘度降低。加入ＴＰＵ大大改善了共混物的流动性能，使共混物的成型加工变得容易进行。当ＴＰＵ含量为４０份时，共混物的熔体粘度出现一极小值。加入不同第三组分对于降低共混物的熔体粘度效果不同，第三组分Ｅ对共混物有增粘作用     

双金属氰化物催化剂的研究进展

综述了近年来双金属氰化物（DMC）催化剂的研究进展，指出DMC催化剂是一类用于环氧化物的高效催化剂，与传统的环氧化物催化剂相比，其制得的聚醚多元醇具有分子量高、不饱和度低、分子量分布窄、平均官能度高等优点。但该催化剂在应用过程中仍存在一些缺点。针对这些缺点，国内外的高校、企业已进行了大量的改性研究工作。     

新一代水管式沉降仪控制模块的研制

新一代低功耗水管式沉降仪控制模块是基于16单片机MSP430F5436为处理器的低功耗装置.该文详细介绍了其硬件结构和工作原理,分别从电源系统、电磁阀控制电路、控制流程、数据采集等部分阐述了其特点,诠释了水管式沉降仪控制模块在人机交互、工作稳定性等多方面所具备的优势.新一代水管式沉降仪控制模块已在实际工程中得到了成功应用,其稳定性和精确性为大坝监控系统提供了准确的实时数据.     

具有谐波减速器的柔性关节参数辨识

为了辨识具有谐波减速器的柔性关节模型的关键参数,设计了一套基于多传感器融合的离线辨识方法,根据电机的位置传感器、电流传感器和关节力矩传感器的实验数据完成柔性关节模型关键参数的辨识.首先,建立采用谐波减速器柔轮输出的柔性关节模型;然后,使用正反转加载力矩的方法辨识出电机的力矩系数;并在空载的情况下,由关节力矩和电机输出力矩分别辨识出关节端和电机端的摩擦力;最后,采用敲击法初步辨识出关节的刚度和阻尼后,在关节位置受限条件下,逐渐增加电机输出力矩,得到柔性关节刚度和关节力矩的非线性关系.多次实验的结果显示,辨识出的参数具有较高的重复性,验证了该方法的有效性.     

PVC新型改性剂AS的合成与应用

本文主要介绍ＰＶＣ新型改性剂ＡＳ树脂的合成方法、产品性能及其在ＰＶＣ异型材、管材、注射、压延片等加工领域中的应用。实验结果证明：该产品完全可以代替ＡＣＲ加工助剂，并有很好的经济效益。     

Catalytic reduction of no over perovskite-type catalysts

In the present work, we have investigated the reduction of NO by propane over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxides. In addition, the reaction conditions, such as temperature, O₂ concentration, and space velocity have been varied to understand their effects on the catalytic performance. In the LaCoO₃ type catalyst, the partial substitution of Ba and Sr into A site enhanced the catalytic activity in the reduction of NO. For the La_0.6Ba (Sr)_o.4 Co_1−x Fe_xO₃ (x=0-1.0) catalyst, the partial substitution of Fe into B site enhanced the conversion of NO, but excess amount of Fe decreased the conversion of NO. The surface area and catalytic activity of perovskite catalysts prepared by malic acid method showed higher values than those of solid reaction method. The conversion of NO increased with increasing O₂ concentration and contact time. The introduction of water into reactant feed decreased the catalytic activity but the deactivation was shown to be reversible over La_0.6Ba_0.4Co_1−x ,Fe_xO₃ catalyst.     

硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

在文明寨地区的高精度地震资料处理实践

文明寨地区构造复杂，断块多，岩性变化大，一些地质问题不明，需要高精度三维资料处理来提高资料的纵、横向分辨率^[1][2]及为储层、油藏研究提供精确的依据。针对东濮文明寨地区高精度处理过程中的关键技术进行了大量分析试验，形成了一套适合东濮地区的较为完整的3D高精度地震资料处理流程。实际资料处理表明效果较好。