改进Harris-Susan算法下砾石土料掺配均匀度评价

砾石土料掺配均匀程度对砾石土心墙坝的安全至关重要。数字图像处理方法被广泛应用于混合物识别领域,但在处理存在黏连特性的图像时易出现过分割与欠分割问题,导致评价结果精度不足。针对上述问题,本文提出改进Harris-Susan算法下砾石土料掺配均匀度评价方法。首先,改进Harris-Susan算法可分割欠分割区域并修复过分割区域,提高二值图像精度;其次,基于砾石邻域的概念,对图像进行单分位均匀度评价;最后,采用空间分布采样构建砾石土的空间均匀度评价指标。将该方法应用于大渡河双江口砾石土高心墙堆石坝工程建设中,本文方法相对统计准确率为0.935,较Otsu算法（0.353）和分水岭算法（-3.101）提升明显。结果表明,本文方法结果与筛分法高度一致,同时可有效节省人力、物力与时间成本,评价效率更高,具有很强的工程应用价值。     

基于TRNSYS的气候变化下“冷-热-电”联供系统运行优化

气候变化导致的极端天气给建筑负荷和冷、热、电联供(combined cooling heating and power, CCHP)系统供能策略带来很大的影响,以上海市某医院为主要研究对象,采用PRECIS软件预测该地区2025至2100年的温度变化,利用TRNSYS软件搭建医院能耗模型计算气候变化影响下的全年逐时负荷,构建了考虑负荷变化影响的“冷-热-电”联供系统运行优化模型,最终生成适应气候变化的供能系统运行方案。负荷预测结果表明,极端高温现象导致建筑的冷、热负荷呈现波动变化趋势,可能造成供需失衡,即夏季高温制冷不足和冬天暖冬供暖过剩的问题。与传统优化模型相比,该模型生成的系统协同运行方案可以增强用户体验,实现降本增效。     

新型电力系统灵活性资源聚合两阶段调度优化模型

构建以新能源为主体的新型电力系统是实现碳达峰、碳中和目标的关键驱动力。传统的以可控煤电装机为主导的电源结构,转变为以强不确定性、弱可控的新能源为主体的新型电力系统,将面临着灵活性资源短缺等挑战。以提升新型电力系统灵活性为导向,提出了灵活性资源聚合两阶段调度优化模型。第一阶段模型考虑分时价格型需求响应,以净负荷波动最小为目标平滑负荷曲线;第二阶段模型考虑分段激励型需求响应市场交易机制,融合电化学储能、抽水蓄能、改造火电等灵活性资源,以系统运行成本最小为目标设计最优运行方案。最后,算例结果和场景对比表明,需求响应能够充分挖掘负荷跟随系统调节的互动能力;改造后火电机组能够降低煤耗水平,提高调节能力,加强与系统灵活性需求时空匹配;各类储能积极响应电力系统调峰,促进了新能源消纳。     

Surface Control and Electrical Tuning of MXene Electrode for Flexible Self-Powered Human–Machine Interaction

MXene materials emerge as promising candidates for energy harvesting and storage application. In this study, the effect of the surface chemistry on the work function of MXenes, which determines the performance of MXene-based triboelectric nanogenerator (TENG), is elucidated. First-principles calculations reveal that the surface functional group greatly influences MXene work function:  OH termination reduces the work function with respect to that of bare surface, while  F and  Cl increase it. Then, work functions are experimentally determined by Kelvin probe force microscopy. The MXene prepared by gentle etching at 40 °C for 48 h (GE_40/48) has the largest work function. Furthermore, an electron-cloud potential-well model is established to explain the mechanism of electron emission-dominated charge transfer and assemble a triboelectric device to verify experimentally its conclusions. It is found that GE_40/48 has the best performance with a 281 V open-circuit voltage, 9.7 µA short-current current, and storing 1.019 µC of charge, which is consistent with the model. Last, a patterned TENG is demonstrated for self-powered human–machine interaction application. This finding enhances the understanding of the inherent mechanism between the surface structure and the output performance of MXene-based TENG, which can be applied to other TENG based on 2D materials.     

High-Performance Green Thick-Film Ternary Organic Solar Cells Enabled by Crystallinity Regulation

The power conversion efficiency (PCE) of organic solar cells (OSCs) has reached high values of over 19%. However, most of the high-efficiency OSCs are fabricated by spin-coating with toxic solvents and the optimal photoactive layer thickness is limited to 100 nm, limiting practical development of OSCs. It is a great challenge to obtain ideal morphology for high-efficiency thick-film OSCs when using non-halogenated solvents due to the unfavorable film formation kinetics. Herein, high-efficiency ternary thick-film (300 nm) OSCs with PCE of 15.4% based on PM6:BTR-Cl:CH1007 are fabricated by hot slot-die coating using non-halogenated solvent (o-xylene) in the air. Compared to PM6:BTR-Cl:Y6 blends, the stronger pre-aggregation of CH1007 in solution induces the earlier aggregation of CH1007 molecules and longer aggregation time, and thus results in high and balanced crystallinity of donors and acceptor in CH1007-based ternary film, which led to high-carrier mobility and suppressed charge recombination. The ternary strategy is further used to fabricate high-efficiency, thick-film, large-area, and flexible devices processed from non-halogenated solvents, paving the way for industrial development of OSCs.     

Poly(pentahydropyrimidine)-Based Hybrid Hydrogel with Synergistic Antibacterial and Pro-Angiogenic Ability for the Therapy of Diabetic Foot Ulcers

Bacterial infection and impaired angiogenesis make the treatment of diabetic foot ulcers (DFU) extremely challenging. Cationic polymers are expected to treat infected wounds due to their excellent antibacterial properties, but still, it is difficult to meet the therapeutic needs of pro-angiogenesis and anti-infections due to their simple construction units and outmoded synthesis methods. Herein, a cationic poly(pentahydropyrimidine) (PPHP) library with strong modifiability is synthesized to construct a hybrid hydrogel with synergistic therapeutic effects for the treatment of infected DFUs. It is found that the as-synthesized hybrid hydrogel can up-regulate angiogenesis-related gene (HIF-1, VEGF, and bFGFR/bFGF) expression and targeted disruption of bacterial cell membranes, which finally promotes the healing of infected DFU (wound healing rate: 92%) within 10 days. This hydrogel, thus, holds great promise in developing new strategies to significantly enhance the treatment of DFU and other bacterial-infected pathological diagnoses.     

High-Performing Quasi-2D Perovskite Photodetectors with Efficient Charge Transport Network Built from Vertically Orientated and Evenly Distributed 3D-Like Phases

Quasi-two-dimensional (Q-2D) perovskites are emerging as one of the most promising materials for photodetectors. However, a significant challenge to Q-2D perovskites for photodetection is their insufficient charge transport ability, which is mainly attributed to their hybrid low-dimensional n-phase structure. This study demonstrates that evenly-distributed 3D-like phases with vertical orientation throughout the film can greatly facilitate charge transport and suppress charge recombination, outperforming the prevalent phase structure with a vertical dimension gradient. Based on such a phase structure, a Q-2D Ruddlesden−Popper perovskite self-powered photodetector achieving a combination of exceptional figures-of-merit is realized, including a responsivity of 0.45 AW⁻¹, a peak specific detectivity of 2.3 × 10¹³ Jones, a 156 dB linear dynamic range, and a rise/fall time of 2.89 µs/1.93 µs. The desired phase structure is obtained by utilizing a double-hole transport layer (HTL), combining hydrophobic PTAA and hydrophilic PEDOT: PSS. Besides, the dependence of the hybrid low-dimensional phase structure is also identified on the surface energy of the buried HTL substrate. This study gives insight into the correlation between Q-2D perovskites’ phase structure and performance, providing a valuable design guide for Q-2D perovskite-based photodetectors.     

Hydrated Bi-Ti-Bimetal Ethylene Glycol: A New High-Capacity and Stable Anode Material for Potassium-Ion Batteries

Potassium-ion batteries have emerged not only as low-cost alternatives to lithium-ion batteries, but also as high-voltage energy storage systems. However, their development is still encumbered by the scarcity of high-performance electrode materials that can endure successive potassium-ion uptake. Herein, a hydrated Bi-Ti bimetallic ethylene glycol (H-Bi-Ti-EG) compound is reported as a new high-capacity and stable anode material for potassium storage. H-Bi-Ti-EG possesses a long-range disordered layered framework, which helps to facilitate electrolyte ingress into the entire Bi nanoparticles. A suite of spectroscopic analyses reveals the in situ formation Bi nanoparticles within the organic polymer matrix, which can alleviate stresses caused by the huge volume expansion/contraction during deep cycles, thereby maintaining the superior structural integrity of H-Bi-Ti-EG organic anode. As expected, H-Bi-Ti-EG anode exhibits a high capacity and superior long-term cycling stability. Importantly for potassium storage, it can be cycled at current densities of 0.1, 0.5, 1, and 2 Ag⁻¹ for 800, 700, 1000, and even 6000 cycles, retaining charging capacities of 361, 206, 185, and 85.8 mAh g⁻¹, respectively. The scalable synthetic method along with the outstanding electrochemical performance of hydrated Bi-Ti-EG, which is superior to other reported Bi-based anode materials, places it as a promising anode material for high-performance potassium storage.     

Multifunctional Organic Potassium Salt Additives as the Efficient Defect Passivator for High-Efficiency and Stable Perovskite Solar Cells

Despite the rapid developments are achieved for perovskite solar cells (PSCs), the existence of various defects in the devices still limits the further enhancement of the power conversion efficiency (PCE) and the long-term stability of devices. Herein, the efficient organic potassium salt (OPS) of para-halogenated phenyl trifluoroborates is presented as the precursor additives to improve the performance of PSCs. Studies have shown that the 4-chlorophenyltrifluoroborate potassium salt (4-ClPTFBK) exhibits the most effective interaction with the perovskite lattice. Strong coordination between  BF₃⁻/halogen in anion and uncoordinated Pb²⁺/halide vacancies, along with the hydrogen bond between F in  BF₃⁻ and H in FA⁺ are observed. Thus, due to the synergistic contribution of the potassium and anionic groups, the high-quality perovskite film with large grain size and low defect density is achieved. As a result, the optimal devices show an enhanced efficiency of 24.50%, much higher than that of the control device (22.63%). Furthermore, the unencapsulated devices present remarkable thermal and long-term stability, maintaining 86% of the initial PCE after thermal test at 80 °C for 1000 h and 95% after storage in the air for 2460 h.     

Dispersion-Enabled Symmetry Switching of Photonic Angular-Momentum Coupling

Photonic spin-orbit interactions describe the interactions between spin angular momentum and orbital angular momentum of photons, which play essential roles in subwavelength optics. However, the influence of frequency dispersion on photonic angular-momentum coupling is rarely studied. Here, by elaborately designing the contribution of the geometric phase and waveguide propagation phase, the dispersion-enabled symmetry switching of photonic angular-momentum coupling is experimentally demonstrated. This notion may induce many exotic phenomena and be found in enormous applications, such as the spin-Hall effect, optical calculation, and wavelength division multiplexing systems. As a proof-of-concept demonstration, two metadevices, a multi-channel vectorial vortex beam generator and a phase-only hologram, are applied to experimentally display optical double convolution, which may offer additional degrees of freedom to accelerate computing and a miniaturization configuration for optical convolution without collimation operation. These results may provide a new opportunity for complex vector optical field manipulation and calculation, optical information coding, light-matter interaction manipulation, and optical communication.