Selective detection of alkanolamine vapors by ion mobility spectrometry with ketone reagent gases

The ion mobility (IMS) spectra of the alkanolamines, monoethanolamine (MEA), 3-amino-1-propanol (PRA), 4-amino-1-butanol (BUA), and 5-amino-1-pentanol (PEA) with acetone and 4-heptanone reagent gases have been measured using a hand-held spectrometer. Monomer and dimer peak patterns were observed for all the alkanolamines with acetone reagent gas. Drift times of monomer and dimer ion clusters for each alkanolamine increased linearly in order of size of alkyl group. Ammonia, Freon 22, and F76 diesel vapors, having similar or coincident mobilities, caused severe interference. Replacement of acetone with 4-heptanone reagent gas resulted in good separation by the altering drift times of product ions. The limit of detection was 0.005 ppm having a linear range of 0.005-0.7 ppm, and signal saturation occurred above 0.88 ppm. Detection was reversible, with a response time of 4 min and a slower recovery time of > 60 min, at vapor levels of 0.7 ppm and ambient nozzle and drift-region temperatures. In contrast to acetone chemistry, single-peak patterns were observed for the alkanolamines with the 4-heptanone reagent. Further, drift times unexpectedly remained stagnant with increasing alkyl-group size. From atmospheric pressure chemical ionization (APcI) tandem mass spectral identifications and collision induced studies, dynamic changes in product-ion equilibria in the IMS drift region compensated by differences in collision cross sections were suggested as the governing causes of the unusual mobility effect.     

Testbed for a scalable terabit optical local area network

The design of a fiber-optic local area network (LAN) demonstration system is described. A complete LAN system would consist of an array of 16 personal computers (PC's), where each PC has a network interface card (NIC) with a parallel fiber-optic datalink to a centralized optoelectronic switch core. The centralized core switches the data generated by 16 NIC's, up to 128 Gbit/s of bandwidth. The demonstrator is designed to scale to terabits of bandwidth by use of an emerging optoelectronic technology, i.e., integrated complementary metal-oxide semiconductor (CMOS) substrates with vertical-cavity surface-emitting laser (VCSEL) and photodetector optical input and output. A subset of the complete system was constructed and is operational. A prototype NIC card, with Motorola Optobus VCSEL transceivers for the optical datalinks, was constructed and is described. A prototype high-speed bipolar switch core, with statically configurable electrical positive-emitter coupled-logic 16 x 16 crossbar switches, CMOS field-programmable gate arrays, and Motorola Optobus transceivers, was constructed and is described. We successfully demonstrated the transmission of high-speed packetized data from one NIC card, through 10 m of parallel fiber ribbon and the centralized switch core, and back to the NIC. We summarize our experiences on the design and testing of our first demonstration system and our development toward a terabit switch core.     

Optimization of resolution and color reproduction by controlling luminance and contrast levels of a liquid-crystal display monitor

The image quality of a color liquid-crystal display monitor is studied by changing the contrast and the luminance levels. The resolution is assessed with modulation transfer function area (MTFA) that is measured at nine different combinations of the luminance and contrast. At these combinations, we measure the chromaticity coordinates and luminance of red-green-blue channels as a function of the digital-analog convert value. We analyze the relations among MTFA value, constant-channel chromaticity, color gamut, and maximum luminance of a white pattern. From the results, the combination of levels is found that provides both high resolution and good color reproduction.     

Bandwidth optimization of optical data links by use of error-control codes

A design approach to optimizing the bandwidth of optical data links while simultaneously decreasing the bit-error rate is proposed. Mathematical analysis indicates that bandwidth gains by factors of 10-60 with power gains of as much as 8.9 dB are possible. To achieve these performance levels requires several innovations. First, conventional forward error-correcting codes cannot be used because of their excessive hardware cost. A reasonably powerful multidimensional parity-based error-control code is proposed and analyzed. These codes offer excellent error detection and moderate error-correction capabilities. Most importantly, they can operate at the fast clock rates that are required. Second, a hybrid automatic-repeat-request protocol is exploited to correct complex error patterns. In thermal-noise-limited systems this unique combination allows the optical clock rate to be increased significantly, thereby resulting in large bandwidth increases. The proposed design approach can be used in optical data links in which propagation delays are moderate and is applicable to fibers that exploit wavelength-division multiplexing or time-division multiplexing, one-dimensional parallel-fiber ribbons, and two-dimensional optical data links that use free space or guided waves. Several design examples are illustrated.     

Accuracy and uncertainty of single-shot, nonresonant laser-induced thermal acoustics

We study the accuracy and uncertainty of single-shot nonresonant laser-induced thermal acoustics measurements of the speed of sound and the thermal diffusivity in unseeded atmospheric air from electrostrictive gratings as a function of the laser power settings. For low pump energies, the measured speed of sound is too low, which is due to the influence of noise on the numerical data analysis scheme. For pump energies comparable to and higher than the breakdown energy of the gas, the measured speed of sound is too high. This is an effect of leaving the acoustic limit, and instead creating finite-amplitude density perturbations. The measured thermal diffusivity is too large for high noise levels but it decreases below the predicted value for high pump energies. The pump energy where the error is minimal coincides for the speed of sound and for the thermal diffusivity measurements. The errors at this minimum are 0.03% and 1%, respectively. The uncertainties for the speed of sound and the thermal diffusivity decrease monotonically with signal intensity to 0.25% and 5%, respectively.     

A micromachined silicon depth probe for multichannel neural recording

A process of making a new type of silicon depth-probe microelectrode array is described using a combination of plasma and wet etch. The plasma etch, which is done using a low temperature oxide (LTO) mask, enables probe thickness to be controlled over a range from 5 to 90 mu. Bending tests show that the probe's mechanical strength depends largely on shank thickness. More force can be applied to thicker shanks while thinner shanks are more flexible. One can then choose a thickness and corresponding mechanical strength using the process developed. The entire probe shaping process is performed only at low temperature, and thus is consistent with the standard CMOS fabrication. Using the probe in recording from rat's somatosensory cortex, we obtained four channel simultaneous recordings which showed clear independence among channels with a signal-to-noise ratio performance comparable with that obtained using other devices.     

Field-programmable smart-pixel arrays: design, VLSI implementation, and applications

A smart-pixel array is a two-dimensional array of optoelectronic devices that combine optical inputs and outputs with electronic processing circuitry. A field-programmable smart-pixel array (FP-SPA) is a smart-pixel array capable of having its electronic functionality dynamically programmed in the field. Such devices could be used in a diverse range of applications, including optical switching, optical digital signal processing, and optical image processing. We describe the design, VLSI implementation, and applications of a first-generation FP-SPA implemented with the 0.8-microm complementary metal-oxide semiconductor-self-electro-optic effect device technology made available through the Lucent Technologies-Advanced Research Projects Agency Cooperative (Lucent/ARPA/COOP) program. We report spice simulations and experimental results of two sample applications: In the first application, we configure this FP-SPA as an array of free-space optical binary switches that can be used in optical multistage networks. In the second, we configure the device as an optoelectronic transceiver for a dynamically reconfigurable free-space intelligent optical backplane called the hyperplane. We also describe the testing setup and the electrical and the optical tests that demonstrate the correct functionality of the fabricated device. Such devices have the potential to reduce significantly the need for custom design and fabrication of application-specific optoelectronic devices in the same manner that field-programmable gate arrays have largely eliminated the need for custom design and fabrication of application-specific gate arrays, except in the most demanding applications.     

Interferometric chromatic dispersion measurements of long, gradient-index rod lenses in the visible and the near infrared

A new procedure is presented for testing long, radial-gradient-index rod lenses in a phase-stepping Twyman-Green interferometer. In addition, a method for converting the measured optical phase data to the rod's index of refraction profile is reviewed. This procedure was used to measure refractive-index profile dispersions over the wavelength range of 441 to 1064 nm. These measurements provide the first data for refractive-index profiles of rod lenses in the infrared and show the existence of positive dispersion, negative dispersion, and near-infrared dispersion reversal in some samples. The dispersion results suggest the need for modifications to the current glass model.     

Unidirectional single-mode Nd:YAG laser with a planar semimonolithic ring cavity

Unidirectional single-mode operation of a diode-pumped Nd:YAG laser with a planar semimonolithic ring cavity has been demonstrated at 1064 nm. The semimonolithic cavity consists of a laser active medium placed in a magnetic field, a crystal quartz plate, and an output coupling mirror, which form an optical diode by acting as a Faraday rotator, a reciprocal polarization rotator, and a partial polarizer, respectively. A single-mode output power of 155 mW and a slope efficiency of 17% were obtained with a 1.2-W diode laser at 809 nm. A laser linewidth of less than 100 kHz is inferred from a beat note frequency spectrum between two identical laser systems and continuous tuning to greater than 2 GHz was observed.