Seeded Crystallization of Leucite

The leucite crystallization kinetics from a hydrothermally derived precursor seeded with nano-crystalline leucite was investigated by X-ray diffraction and non-isothermal differential thermal analysis. The nano-crystalline leucite was prepared by high-energy milling of high-purity leucite powder and the leucite precursor was prepared by the hydrothermal method of silica sol, aluminum nitrate, and potassium nitrate. After the seeds were introduced, the crystallization temperature of the precursor was lowered by 100°C and the transition phase kalsilite did not appear during the crystallization process. When the seeded precursor was heat treated at 700°C, a small amount of cubic leucite was stabilized to room temperature. The seeded precursor showed an exothermic peak between 800° and 920°C under different heating rates. The activation energy for the growth of leucite from the seeded precursor was 256(SD9) kJ/mol.     

Synthesis and characterization of copolythiophene

Copolythiophenes (Co‐PTs), poly(3‐hexylthiophene‐co‐3‐thiophene carboxylic acid) (P3HT‐TCa), poly(3‐hexyloxylthiophene‐co‐3‐thiophene carboxylic acid) (P3HOT‐TCa), and poly(3‐phenylthiophene‐co‐3‐thiophene carboxylic acid) (P3PhT‐TCa), were synthesized by chemical oxidized polymerization to investigate the effect of copolymerization on the properties of polythiophenes (PTs). Gel permeation chromatography showed that the molecular weight (MW) of Co‐PT was lower than that of homopolythiophene. Fourier transform infrared (FTIR) spectra indicated that the copolymerization was successful between the monomers. The λ_max of Co‐PTs gave a “blue shift” in ultraviolet‐visible (UV‐VIS) spectra. Photoluminescence (PL) spectra showed that the PL intensity of Co‐PT became weaker than that of homopolythiophene and the disappearance of PL had been observed in P3HOT‐TCa. The thermal stability of Co‐PT was influenced by the carboxyl for its low decomposition temperature. Furthermore, the copolymerization between multi‐wall carbon nanotube containing thiophene ring (MWNT‐Th) and 3‐hexyloxylthiphene could also take place successfully. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

CaO-SiO2系玻璃的析晶动力学研究

利用溶胶-凝胶法制得CaO-SiO2系基础玻璃,通过差热分析曲线分析质量比为CaO-SiO2玻璃的析晶能力。经分析,其析晶活化能E=457.1kJ·mol-1,而晶化生长指数是随升温速率的不同而不同,速率越大,晶化生长指数越小。     

Alekseevskii-Tate revisited:An extension to the modified hydrodynamic theory of long rod penetration

The modified hydrodynamic theory of long rod penetration into semi-infinite targets was established independently by Alek-seevskii and Tate over forty years ago and since then many investigators contributed much to the development of the high speed penetration mechanics.However,in all the models proposed so far,the target resistance Rt is not well defined and usually determined by adjusting it until the predicted depth of penetration comes to an agreement with experimental data.In this paper,assumptions are...     

Deformation and failure study of surrounding rocks of dynamic pressure roadways in deep mines

In order to understand the change rules of stress-displacement in surrounding rocks of dynamic pressure roadways in deep mines and to obtain a theoretical basis for analyses of roadway stability and designs of support,we established a coupling equation of adjacent rock strength,mining stress and supporting resistance on the basis of an elastic-plastic theory of mechanics.We obtained an analytical solution for stress and displacement distribution of elastic and plastic regions in surrounding rock of dynamic pressure roadway..Based on this theory,we have analyzed the changes in stress-displacement in elastic and plastic regions of surrounding rocks of dynamic pressure roadways in the Haizi Coal Mine.The results show that:1) radial and tangential stress change violently within the first 4 m from the inner surface of a roadway after excavation;radial stress increases while tangential stress decreases within a range of about 6 m from the inner surface of the roadway as a function of q3;2) radial and tangential stress increase with an increase in the mining pressure coefficient k;the increase in the rate of tangential stress is greater than that of radial stress;3) the radial displacement of the inner surface of roadways decreases with an increase in q3,provided that k remains unchanged.     

中国银行利率风险实证分析

随着中国融入世界的步伐加快,加入WTO中要求中国放开金融市场的开放程度,利率管制的放松也将逐步的实行,利率风险日益成为中国商业银行面临的重要风险之一。本文从理论和实践角度对中国商业银行的利率风险进行了分析和研究,剖析中国商业银行存在的诸多障碍,指出了商业银行风险管理中存在的问题,并提出中国商业银行利率风险管理建议。     

光谱法研究Ni[S2P（OCH2CH2Ph）2]2与α,α＇-联吡啶加合反应

利用紫外光谱法研究了Ni[S2P（OCH2CH2Ph）2]2与α,α-联吡啶的加合反应。研究发现Ni[S2P（OCH2CH2Ph）2]2与α,α-联吡啶形成1∶1型加合物,在25℃的苯溶剂中,加合物的离解度α=0.07,稳定常数K稳^θ=2.1×10^6。     

鄂尔多斯盆地靖安油田岩性地层油藏成藏分析

鄂尔多斯盆地靖安油田是我国典型的岩性地层油藏,其特点是构造简单、低孔、低渗、非均质性强.岩性油藏主要受构造沉积环境、烃源岩发育范围和区域盖层等因素控制.烃源岩是岩性油气藏形成的物质基础,沉积环境对岩性地层圈闭具有控制作用,盖层控制岩性油藏发育的规模.该区有3种成藏模式,构造-岩性油藏主要分布于洼陷带,砂岩透镜体、砂岩上...     

高性能电极接头栓的研制

研制了高粘结强度、低电阻率、高渗透性能接头栓,并说明了改进的目标和方向。研究了电极接头栓的使用性能、主要作用和选用接头栓补救电极和接头连接质量的优点;研究了电极接头栓的原料选择、原料配比、添加剂和发泡剂的选取;确定了电极接头栓的生产技术要求和生产工艺流程。试验证明,研制的高性能接头栓具有高粘结、强固结、有效补强的作用。     

ZrO2对CaO-SiO2系玻璃析晶的影响

通过DSC曲线研究了不同含量的ZrO2对CaO-SiO2系玻璃析晶的影响,根据JMA方程计算动力学参数(如析晶活化能E、频率因子ν、晶化指数n)。从计算结果可以看出,随着ZrO2含量的增加,析晶活化能E减少,而频率因子ν和晶化指数n增加。当ZrO2含量为7%时,E值最小:235.58kJ/mol;n值最大:4.70。说明ZrO2在CaO-SiO2玻璃体系是有效的晶核剂。