论十八世纪纹章瓷纹章装饰对珐琅彩瓷的影响

一般认为，珐琅彩瓷是铜胎掐丝珐琅工艺影响之下的产物，而事实上，珐琅彩瓷的出现与兴盛，除了铜胎掐丝珐琅工艺的影响之外，还受一种外销瓷——纹章瓷的影响。本文通过对纹章瓷和珐琅彩瓷的构图形式、装饰形态、装饰色彩，以及创烧的时间等方面的分析与比较，论证了纹章瓷对珐琅彩瓷具有一定的影响。     

移动混合开发框架

针对现有混合开发框架在开发便利性和应用性能方面的不足,研究了以HTML5开发为基础的移动混合开发框架的问题.结合HTML5跨平台特性、打包机制、多窗口管理机制、原生插件开发技术等,实现了一套自有的混合开发框架.本混合开发框架为开发带来了便利,提升了开发效率,同时,混合引擎中独特实现的Widget应用管理以及窗口管理模式也改善了混合应用的性能,提升了用户体验.我公司实现的企业级移动解决方案表明该框架性能较好,易于使用,具有较好的商业价值.     

电解法处理利福霉素SV钠废渣分离液的研究

根据电化学原理，采用电解法，利用铁屑与炭粒作电极，处理利福霉素SV钠药渣分离液，讨论各种因素对分离液污染物作效果的影响，COD去除率可达91．8％左右，脱色率可达95％左右。     

GoAhead Web Server在嵌入式远程监控系统中的应用

文章对Go Ahead Web Server的基本特点和运行环境进行了介绍,结合嵌入式远程监控系统的现状,将嵌入式开发平台、Linux操作系统、Go Ahead Web Server和I n t e r n e t融合在一起,设计了一个控制电压转换的嵌入式远程监控系统。应用结果表明,Go Ahead Web Server反应迅速,可靠稳定,在实际应用中具有可行性,对嵌入式产品的管理和控制可以得到满意的效果。     

时间戳服务在信息系统审计的研究应用

联网审计后,审计的审计线索由原来纸质的资料转为为计算机的电子数据,电子数据存在被篡改或伪造的可能,不能确保其真实性和可靠性,本文研究的是在被审计单位原始数据生成时,采用时间戳服务对其实时签名,来保证电子数据的真实性和可靠性。     

基于路由标记的分布式信息检索

文章对分布式信息检索中通常采用的洪泛策略进行分析,发现其容易重复转发相同消息,导致产生大量冗余通信,造成网络拥塞等问题。提出采用基于路由标记的分布式信息检索策略,以减少冗余消息的产生并避免网络拥塞,最后以实例进行两种策略的对比分析,并通过理论推导证明了后者的有效性。     

高纯竹叶碳苷黄酮复合纳米生物材料的制备及其结构表征（急）

采用离子交联法，以高纯竹叶碳苷黄酮制剂（碳苷总质量分数﹥90%，记为H-BLF）和芫根阴离子多糖（TP）为原料，通过ε-聚赖氨酸（ε-PL）的阳离子桥键合而成竹叶碳苷黄酮纳米混悬液（H-BLFnd），进一步在混悬液中添加8%（w/v）的γ-环糊精、经真空冷冻干燥得到纳米冻干粉（H-BLFnp），采用粒径分析、TEM、UV、FTIR、TG和DSC对其外观、性能、结构进行表征。结果表明： H-BLFnp外观为白色粉状，表面光洁平整，色泽均匀，平均粒径为（679±10.2）nm，分散系数为（0.349±0.004），包埋率为（92.39±0.34）%。     

Effects of the reinforcement and toughening of acrylate resin/CaCO3 nanoparticles on rigid poly(vinyl chloride)

Novel composite particles based on nanoscale calcium carbonate (nano‐CaCO₃) as the core and polyacrylates as the shell were first synthesized by in situ encapsulating emulsion polymerization in the presence of the fresh slush pulp of calcium carbonate (CaCO₃) nanoparticles. Subsequently, these modified nanoparticles were compounded with rigid poly(vinyl chloride) (RPVC) to prepare RPVC/CaCO₃ nanocomposites. At the same time, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were investigated, and the synergistic effect of modified nanoparticles with chlorinated polyethylene (CPE) was also studied. The results showed that in the presence of nano‐CaCO₃ particles, the in situ emulsion polymerization of acrylates was carried out smoothly, and polyacrylates successfully encapsulated on the surface of nano‐CaCO₃ to prepare the modified nanoparticles, breaking down nano‐CaCO₃ particle agglomerates, improving their dispersion in the matrix, and also increasing the particle–matrix interfacial adhesion. Thus, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were very significant, and the cooperative effect of the nanoparticles with CPE occurred in the united modification system. Scanning electron microscopy analyses indicated that large‐fiber drawing and network morphologies coexisted in the system of joint modification of nanoparticles with CPE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3940–3949, 2007     

NURBS曲线C~1连续参数优化算法

曲线的参数特性直接决定基于自由曲线的路径规划、运动控制等算法的质量.为了生成满足C1连续的近似弧长参数化,提出一种基于分段三次重新参数化的参数优化算法.首先利用Simpson方法离散积分能量,然后使用极值求解法求得初始解,最后通过LM(Levenberg-Marquardt)优化算法计算出曲线的最优参数表示.与C1连续的分段有理重新参数化方法相比,该算法能够在分段数量很少的情况下达到局部最优.最后通过实例说明了文中算法的有效性.     

Controllable Fabrication of Co3−xMnxO4 with Tunable External Co3+/Co2+ Ratio for Promoted Oxygen Reduction Reaction

Co_3?xMn_xO₄ is a bimetal oxide with excellent electrochemical activity in alkaline solution, has been regarded as a promising alternative in the field of ion-air batteries and proton exchange membrane fuel cell (PEMFC). Herein, we report a simple solvothermal-calcination method to fabricate Co_3?xMn_xO₄ with tunable external Co³⁺/Co²⁺ and Mn³⁺/Mn²⁺ ratio. The tunable ratio of element valence in the bimetal results in a higher exposure of active center for oxygen redox reaction (ORR), and thus lead to a better ORR activity, which was confirmed by X-ray photoelectron spectroscopy characterizations and electrochemical measurements. Specially, Co_1.8Mn_1.2O₄ with a Co³⁺/Co²⁺ ratio of 2.08 showed an overpotential of 0.37 V at benchmark ORR current density of 3 mA/cm² in 0.1 M KOH, which is lower than that of pure oxide (Mn₃O₄ 0.53 V and Co3O4 0.56 V). In addition, the as prepared Co_1.8Mn_1.2O₄ exhibited a positive half-wave potential (0.83 V vs RHE) due to their more active sites, promotes charge transfer, adsorption and desorption of oxygen species. This work provides a strategy for the design and fabrication of earth-abundant, low-cost electrocatalysts for PEMFC in practical applications.

Graphic Abstract

Co_3?xMn_xO₄ was fabricated by tuning external Co³⁺/Co²⁺ and Mn³⁺/Mn²⁺ ratio, and the activity initially shows a positive correlation with the ration of Co³⁺/Co²⁺ in Co_3?xMn_xO₄.