Experimental and first-principles studies of BiVO4/BiV1-xMnxO4-y n-n+ homojunction for efficient charge carrier separation in sunlight induced water splitting

Though bismuth vanadate (BiVO₄) is extensively used as a photoactive material, its performance in harnessing solar energy is limited by ineffective separation of photo-excited charge carriers. We demonstrate here a concept of n-n⁺ homojunction of BiVO₄/BiV_1-xMn_xO_4-y, which improves its charge separation efficiency. Using first-principles theoretical calculations, we determine the effect of Mn substitution on oxygen vacancy formation energies and associated changes in the electronic structure of BiVO₄. Showing that Mn substitution pushes the Fermi level of BiVO₄ towards its conduction band, we predict that the associated enhanced bending of bands at the homojunction (BiVO₄/BiV_1-xMn_xO_4-y) facilitates efficient separation of charge carriers. With Mott-Schottky experiments, we verify the increased band bending at the n-n⁺ homojunction, and show that the maximum photocurrent density measured in a sample with n-n⁺ homojunction is ten times higher than that obtained of the pristine sample. Secondly, Mn substitution in BiVO₄ also reduces the oxygen vacancy formation energy, promoting higher concentration of O-vacancies, further enhancing the photoelectrochemical response.     

Optimization of Digital Growth of Thick N-Polar InGaN by MOCVD

Smooth 200 nm thick N-polar InGaN films were grown by metal–organic chemical vapor deposition (MOCVD) on sapphire using a digital approach consisting of a constant In, Ga, and N precursor flow with pulsed injection of H2 into the N2 carrier gas. Using this growth scheme, the H2 injection time was altered and the effect on the morphology and indium incorporation in the films observed. The effect of periodic insertion of additional GaN inter-layers on the surface morphology of the InGaN layers was also studied.     

µBIGMSA-Microservice-Based Model for Big Data Knowledge Discovery: Thinking Beyond the Monoliths

Wireless Personal Communications - Enterprise thrives on software applications that are built to fulfil the core business requirements. A single business application can offer a cluster of...     

An efficient tool for genetic experiments: agarose gel image analysis

Repeatability of many genetic analysis experiments can be improved by the application of signal processing and image-processing tools. Most of the experiments in genetics result in some sort of digital signal or image patterns that are subjectively analyzed by the geneticists. This paper presents an example project where image-processing techniques are applied for automation of most of the routine processes of agarose gel image analysis. Result of applying this program has shown that the time taken for the analysis has been reduced by about 70% and the result is reproducible.     

Segmentation of volumetric tissue images using constrained active contour models

In this article we describe an application of active contour model for the segmentation of 3D histo-pathological images. The 3D images of a thick tissue specimen are obtained as a stack of optical sections using confocal laser beam scanning microscope (CLSM). We have applied noise reduction and feature enhancement methods so that a smooth and slowly varying potential surface is obtained for proper convergence. To increase the capture range of the potential surface, we use a combination of distance potential and the diffused gradient potential as external forces. It has been shown that the region-based information obtained from low-level segmentation can be applied to reduce the adverse influence of the neighbouring nucleus having a strong boundary feature. We have also shown that, by increasing the axial resolution of the image stack, we can automatically propagate the optimum active contour of one image slice to its neighbouring image slices as an appropriate initial model. Results on images of prostate tissue section are presented.     

Rehabilitating oustees in the Narmada basin,India

The plan for 3155 water projects is absolutely necessary for the socioeconomic development of the neglected Narmada basin. However, neither the 45‐year development target nor its cost (Rs 200 billion) is realistic. The environmental cost associated with the rehabilitation of 1.31 million oustees within the valley should be fully internalized in the development plan. In this article, submergence effects are estimated by extrapolation, and a socioeconomic and cultural profile of the oustees is presented. The feasibility of four possible resettlement alternatives is examined, keeping in view the objectives of rehabilitation and the performance of completed and ongoing projects. Guidelines are suggested for the preparation of a rehabilitation plan.     

Analysis of competition and market power in the wholesale electricity market in India

The electricity reforms were initiated in India with the objective of promoting competition in the electricity market. In order to promote competition, the Electricity Act 2003 was enacted and various policy initiatives were taken by the Government of India. Central Electricity Regulatory Commission (CERC) also facilitated competition through the regulatory framework of availability based tariff, Indian Electricity Grid Code, open access in inter-state transmission, inter-state trading and power exchanges. Despite these initiatives, electricity prices increased in the Wholesale Electricity Market in India (WEMI). This paper analyses the market structure and competitiveness in the WEMI. There are, of course, various potential reasons for the rise in the electricity price. This paper seeks to investigate, if market power was one of the reasons for increase in market prices. Concentration ratio, Herfindahl–Hirschman index, Supply Margin Assessment, and Residual Supply Index have been used to measure market power. This paper also uses the price–cost mark-up to examine, if exercise of market power led to higher margins. The analysis suggests that market power of firms may be part of the reason for the increase in electricity prices in WEMI. The study suggests various measures to increase competition in the WEMI.