电渗析处理化纤厂去酸水的研究

本文采用电渗析法对化纤厂粘胶单丝淋洗废水的处理进行了试验研究。     

Precision grinding and facing of copper-beryllium alloys

This paper investigates the machinability of Cu-Be alloys by ultraprecision grinding and facing. The material temper, tool geometry, and machining parameters are varied to assess their effects on surface finish. The study shows that microgrinding of Cu-Be with a diamond wheel generates a rougher surface finish as compared to that produced by microfacing with a single-point diamond tool. Similar chip formation mechanisms are observed when the depths of cut vary from few millimeters to submicron levels. A mathematical model is derived to compare the theoretical and experimental surface finish. Good agreement between predicted and measured data is obtained, providing grain boundaries are visible on a machined surface when being observed under a microscope. Feedrate and tool radius are the most influential parameters on surface finish. Flatness of 20 nm on the 9.5 mm diameter rod and roughness of 2 nm R_a and 8 nm R_t are achieved. Although the material’s micromachinability is the same for both the aged and unaged alloys, size and distribution of beryllides must be controlled for better tool life and surface finish.     

金刚石形状对成形砂轮修整精度的影响及其消除的方法

在用金刚石修整成形砂轮时,金刚石的形状对砂轮的成形修整精度有不容忽视的影响。为了提高修整精度,可以分别或综合采取下列措施：1）减小金刚石的形状误差,如挑选金刚石的形状或加以修整;2）减小修整机构的修整压力角v D;3）按金刚石的形状修磨修整机构的仿形触指。     

Structural load mitigation control for wind turbines: A new performance measure

Structural loads of wind turbines are becoming critical because of the growing size of wind turbines in combination with the required dynamic output demands. Wind turbine tower and blades are therefore affected by structural loads. To mitigate the loads while maintaining other desired conditions such as the optimization of power generated or the regulation of rotor speed, advanced control schemes have been developed during the last decade. However, conflict and trade‐off between structural load reduction capacity of the controllers and other goals arise; when trying to reduce the structural loads, the power production or regulation performance may be also reduced. Suitable measures are needed when designing controllers to evaluate the control performance with respect to the conflicting control goals. Existing measures for structural loads only consider the loads without referring to the relationship between loads and other control performance aspects. In this contribution, the conflicts are clearly defined and expressed to evaluate the effectiveness of control methods by introducing novel measures. New measures considering structural loads, power production, and regulation to prove the control performance and to formulate criteria for controller design are proposed. The proposed measures allow graphical illustration and numerical criteria describing conflicting control goals and the relationship between goals. Two control approaches for wind turbines, PI and observer‐based state feedback, are defined and used to illustrate and to compare the newly introduced measures. The results are obtained by simulation using Fatigue, Aerodynamics, Structures, and Turbulence (FAST) tool, developed by the National Renewable Energy Laboratory (NREL), USA.     

Production of GST–SOD fusion protein by recombinant E coli XL1 Blue

A recombinant plasmid was constructed by inserting a DNA fragment with the coding region of Cu/Zn–superoxide dismutase (Cu/Zn–SOD) cDNA from sweet potato, Ipomoea batatas (l) Lam cv Tainong 57, into the 3′ end of the open reading frame of the glutathione S‐transferase (GST) gene in an expression vector, pGEX‐2T. The constructed plasmid was transformed into E coli XL1 Blue. Fusion proteins of Cu/Zn–SOD and GST (GST–SOD) were produced from the recombinant E coli. About 6 mg of GST–SOD fusion proteins could be obtained from 1 dm³ of cultural broth after induction with 0.075 mmol dm⁻³ Isopropyl‐β‐D ‐thiogalactoside (IPTG). Lactose was not an efficient inducer. High cell density culture was performed by fed‐batch fermentation using a glucose analyzer to control glucose concentration at 1 g dm⁻³. The cell density of the fed‐batch culture reached an OD₆₀₀ of 30, the total amount of GST–SOD fusion protein was 100 mg dm⁻³ which is about 14 times more than that of the batch culture. Most of the fusion proteins were shown to be in an active monomeric form, and the molecular weight was estimated to be 45 kDa by SDS–PAGE and 47 kDa by gel filtration. The specific activity of the purified fusion proteins was about 1200 mg⁻¹ and equal to 3200 unit per mg of SOD domain only. © 2000 Society of Chemical Industry     

Highly concentrated aqueous SiC slurry containing fine SiC powder: A new approach for ultra-dense green body

SiC slurry with ultra-high concentration up to 70 vol% was prepared using oxidized fine and coarse SiC powder mixture, and dense SiC green body with a relative density of 76% was fabricated by drying the slurry at ambient condition. Three approaches were performed to prepare highly concentrated SiC slurry; preparation of SiC powder having good dispersion behavior, optimization of the oxidation condition, and optimization of bi-modal particle size distribution. An aqueous slurry with the solid loading up to 62 vol% could be prepared using fine (150 nm) SiC powder prepared by the mechanical alloying of Si and carbon. The surface property of the fine and coarse (10 μm) SiC powders was optimized using an oxidation treatment. The maximum solid loading of the fine SiC slurry prepared using oxidized powder was 66 vol%. By optimizing the mixing ratio of the oxidized fine and coarse SiC powder to 75:25, the solid loading of the SiC slurry could increase up to 70 vol%. The relative densities of the green bodies after drying 66, 68, and 70 vol% slurries were 69, 75.7, and 76.1%, respectively, which values were higher than those (58%) prepared by cold isostatic pressing under 200 MPa.     

Replacement of carcinogenic alkylating agent ethylene oxide in the synthesis of (Z)-3-dodecen-1-YL (E)-2-butenoate,sex pheromone of sweet-potato weevil,Cylas formicarius elegantulus (summers) andCylas formicarius formicarius (F.)

An alternative synthesis of (Z)-3-dodecen-1-y1 (E)-2-butenoate without use of carcinogenic ethylene oxide and HMPA is described. By coupling of the tetrahydropyranyl (THP) ether of 3-butyn-1-ol with 1-bromooctane with sodamide in liquid ammonia, 12-(2-tetrahydropyranyloxy)-9-dodecyne was obtained; subsequent hydrolysis and semihydrogenation afforded (Z)-3-dodecen-1-ol. The alcohol was then reacted with crotonyl chloride to give the desired crotonate with a total yield of 29.8%. Males of sweet-potato weevil,Cylas formicarius were strongly attracted to the synthetic sex pheromone. The attraction from the dispenser of polyethylene tube was better than the attraction from the dispenser of rubber septum in the field.     

Effects of a tert‐butylphenylene substituent on the structure and optical,fluorescent and thermal properties of the poly(p‐phenylenevinylene) derivatives

Two soluble fluorescent polymers, poly(2‐decyloxy‐5‐(4′‐tert‐butylphenyl)‐1,4‐phenylenevinylene) (DtBP‐PPV) and poly(2‐decyloxy‐1,4‐phenylenevinylene) (DO‐PPV), were prepared by a method similar to the Gilch procedure. The DtBP‐PPV and DO‐PPV have a same chemical structure except for the conjugated tert‐bytulphenyl substituents in the former. The polymers are characterized by using ¹H NMR, FTIR, UV–vis, photoluminescence (PL), and electroluminescence (EL) spectroscopies and thermogravimetric analysis (TGA). The ¹H NMR spectra show no tolane‐bis‐benzyl (TBB) structure defects in DtBP‐PPV but some in DO‐PPV. Both UV–vis absorption and PL emission peaks of the DtBP‐PPV exhibit a red‐shift phenomenon as compared with those of the DO‐PPV. Moreover, with the DtBP‐PPV and DO‐PPV acting as light‐emitting polymers separately, EL devices were fabricated with a sequential lamination of ITO/PEDOT/DtBP‐PPV (or DO‐PPV)/Ca/Ag. The DtBP‐PPV‐based device shows a lower turn‐on voltage, a longer EL emission wavelength, and a higher brightness than the DO‐PPV‐based device. The maximum brightness of DtBP‐PPV‐based device is 57 cd/m² at an applied voltage of 12 V. POLYM. ENG. SCI., 47:1380–1387, 2007. © 2007 Society of Plastics Engineers