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排序方式: 共有5461条查询结果,搜索用时 15 毫秒
41.
Byeongdu Lee Jin Won Lee Seung Woo Lee Jinhwan Yoon Moonhor Ree 《Polymer Engineering and Science》2004,44(9):1682-1691
A series of poly(ethylene phthalate‐co‐terephthalate)s were synthesized by melt polycondensation of ethylene glycol (EG) with dimethyl phthalate (DMP) and dimethyl terephthalate (DMT) in various proportions. The DMT‐rich polymers were obtained with reasonably high molecular weights, whereas the DMP‐rich polymers were synthesized with relatively low molecular weights due to steric effects associated with the highly kinked DMP monomer. The compositions and thermal properties of the polymers were determined. The copolymers containing DMP in amounts of ≤ 21 mol% were crystallizable, whereas the other polymers were not. All the polymers exhibited a single glass transition temperature. Analysis of the measured glass transition temperatures and crystal melting temperatures confirmed that the DMT‐rich copolymers are random copolymers. The non‐isothermal crystallization behaviors of the DMT‐rich copolymers were investigated by calorimetry and modified Avrami analysis. The Avrami exponents n were found to range from 2.7 to 3.8, suggesting that the copolymers crystallize via a heterogeneous nucleation and spherulitic growth mechanism; that is, the incorporation of DMP units as the minor component does not change the growth mechanism of the copolymers. In addition, the activation energies of the crystallizations of the copolymers were determined; the copolymers were found to have higher activation energies than the PET homopolymer. Polym. Eng. Sci. 44:1682–1691, 2004. © 2004 Society of Plastics Engineers. 相似文献
42.
N‐(2‐hydroxy)propyl‐3‐trimethylammonium chitosan chloride (HTCC), a water‐soluble chitosan quaternary ammonium derivative, was used as an antimicrobial agent for cotton fabrics. HTCC has a lower minimum inhibition concentration (MIC) against Staphylococcus aureus, Klebsiella pneumoniae, and Escherichia coli compared to that of chitosan; however, the imparted antimicrobial activity is lost on laundering. Thus crosslinking agents were utilized to obtain a durable antimicrobial treatment by immobilizing HTCC. Several crosslinkers such as dimethyloldihydroxyethylene urea (DMDHEU), butanetetracarboxylic acid (BTCA), and citric acid (CA) were used with HTCC to improve the laundering durability of HTCC treatment by covalent bond formation between the crosslinker, HTCC and cellulose. The polycarboxylic acid treatment was superior to the DMDHEU treatment in terms of prolonged antimicrobial activity of the treated cotton after successive laundering. Also, the cotton treated with HTCC and BTCA showed improved durable press properties without excessive deterioration in mechanical strength or whiteness when compared to the citric acid treatment. With the addition of only 0.1% HTCC to BTCA solutions, the treated fabrics showed durable antimicrobial activity up to 20 laundering cycles. The wrinkle recovery angle and strength retention of the treated fabrics were not adversely affected with the addition of HTCC. Therefore, BTCA can be used with HTCC in one bath to impart durability of antimicrobial activity along with durable press properties to cotton fabric. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1567–1572, 2003 相似文献
43.
Four oil absorbents based on styrene–butadiene (SBR)—pure SBR (PS), 4‐tert‐butylstyrene–SBR (PBS), EPDM–SBR network (PES), and 4‐tert‐butylstyrene‐EPDM‐SBR (PBES)—were produced from crosslinking polymerization of uncured styrene–butadiene rubber (SBR), 4‐tert‐butylstyrene (tBS), and ethylene–propylene–diene terpolymer (EPDM). The reaction took place in toluene using benzoyl peroxide (BPO) as an initiator. Uncured SBR was used as both a prepolymer and a crosslink agent in this work, and the crosslinked polymer was identified by IR spectroscopy. The oil absorbency of the crosslinked polymer was evaluated with ASTM method F726‐81. The order of maximum oil absorbency was PBES > PBS > PES > PS. The maximum values of oil absorbency of PBES and PBS were 74.0 and 69.5 g/g, respectively. Gel fractions and swelling kinetic constants, however, had opposite sequences. The swelling kinetic constant of PS evaluated by an experimental equation was 49.97 × 10?2 h?1. The gel strength parameter, S, the relaxation exponent, n, and the fractal dimension, df, of the crosslinked polymer at the pseudo‐critical gel state were determined from oscillatory shear measurements by a dynamic rheometer. The morphologies and light resistance properties of the crosslinked polymers were observed, respectively, with a scanning electron microscope (SEM) and a color difference meter. 相似文献
44.
The infrared reflectance and transmission spectra of amorphous CdGe
x
As2 were investigated to study the amorphous structure with varying Ge content. The mid-infrared optical absorption edges of amorphous CdGe
x
As2 with 0<x<1.2, were observed in the range 1.6–1.7 m, indicating a structural similarity in short-range order throughout. Comparing the reflectance and transmission spectra of amorphous and devitrified crystalline phases established that the structures of amorphous CdGe
x
As2 transformed from the CdAs2 basic structure to the chalcopyrite (CdGeAs2) structure, as one progressed fromx=0 tox=1.2. The infrared spectra were interpreted interactively with radial distribution function, magnetic susceptibility, density measurements, and crystallization studies. The crystallization behaviour of amorphous CdGe
x
As2 that was heat treated at different temperatures was investigated using far-infrared transmission spectra. 相似文献
45.
Cloud computing is becoming a key factor in the market day by day. Therefore, many companies are investing or going to invest in this sector for development of large data centers. These data centers not only consume more energy but also produce greenhouse gases. Because of large amount of power consumption, data center providers go for different types of power generator to increase the profit margin which indirectly affects the environment. Several studies are carried out to reduce the power consumption of a data center. One of the techniques to reduce power consumption is virtualization. After several studies, it is stated that hardware plays a very important role. As the load increases, the power consumption of the CPU is also increased. Therefore, by extending the study of virtualization to reduce the power consumption, a hardware-based algorithm for virtual machine provisioning in a private cloud can significantly improve the performance by considering hardware as one of the important factors. 相似文献
46.
Chan-Geun Song Jonghan Won Inhoon Jang Hyeunseok Choi 《Journal of the American Ceramic Society》2021,104(9):4398-4407
In metal oxide nanofiber fabrication using the electrospinning method, heat treatment is performed at temperatures of 500°C or higher for crystallization and polymer desorption. Therefore, it is difficult to fabricate low-temperature phase metal oxides that crystallize at low temperatures. TiO2, a representative metal oxide often used as photocatalysts, is known to have higher photocatalytic activity in the low-temperature phase (anatase structure) than in the high-temperature phase (rutile structure). Studies on the fabrication of TiO2 anatase nanofibers using conventional electrospinning have reported disadvantages such as the partial expression of rutile structures and low crystallinity. This study developed an anatase TiO2 nanofiber as a high-efficiency catalyst based on the electrospinning method and a residual organic matter cleaning method that employs ultra-violet (UV) light. We fabricated nanofibers using the electrospinning method and implemented TiO2 nanofibers with the anatase structure through heat treatment at 260°C. Residual organics remaining after heat treatment of the fabricated crystalized TiO2 nanofibers were removed by exposing them to UV light, thereby improving photocatalytic efficiency. The photocatalytic efficiency of the fabricated TiO2 nanofibers was confirmed through a methylene blue (MB) decomposition experiment under visible light irradiation. The photocatalytic efficiency (time taken for the concentration of the MB solution to reach 50%) of the UV-treated TiO2 nanofibers was approximately six times higher than of P25 and the heat-treated nanofibers. 相似文献
47.
The superplastic deformation behavior of quasi-single phase Zn-0.3 wt. %Al was investigated. A series of load relaxation and
tensile tests was conducted at various temperatures ranging from RT (20 °C) to 200 °C. The recently proposed internal variable
theory of structural superplasticity was applied. The flow curves obtained from load relaxation tests were shown to consist
of contributions from interface sliding (IS) and accommodating plastic deformation. In the case of quasi-single phase Zn-0.3
wt.% Al alloy with an average agrain size of 1 μm, the IS behavior could be described as a viscous flow process characterized
by a power index of Mg=0.5. A large elongation of about 1400% was obtained at room temperature and the strain rate sensitivity parameter was about
0.4. Although relatively large-grained (10 μm) single phase alloy showed a high value of strain rate sensitivity comparable
to that of fine-grained alloy at very low strain rate range, IS was not expected from the analysis based on the internal variable
theory of structural superplasticity at room temperature. As the temperature increased above 100 °C, however, the contribution
from IS was observed at a very low strain rate range. A high elongation of ∼400% was obtained in a specimen of 10-μm-grain-size
at 200 °C under a strain rate of 2×10−4/sec.
Jointly appointed at Center for Advanced Aerospace Materials (CAAM) 相似文献
48.
Il Song Park Tae Gyu Woo Min Ho Lee Seung Geun Ahn Myung Sik Park Tae Sung Bae Kyeong Won Seol 《Metals and Materials International》2006,12(6):505-511
Anodic oxidation is the process of creating a titanium oxide layer with various defects more dense and stable. In this study,
a dense, stable and porous oxide layer was formed using anodic spark oxidation on pure titanium surface and hydroxyapatite
crystals were formed on its surface via a hydrothermal treatment. A mixture of 0.02M−GP (Glycerolphosphate disodium salt)
and 0.2M-CA (Calcium acetate) was used as an electrolyte. By increasing the anodizing voltage to 220, 260, 300, and 360 V,
the effects of the anodizing voltage were examined by evaluating the film properties after anodization and a hydrothermal
treatment. Breakdown occurred around 230 V. As the voltage increased after breakdown, the pore size increased. After the hydrothermal
treatment, the amount of HA crystal precipitation was also increased as the voltage increased. The mean surface roughness
(Ra) of the anodizing surface was also increased as the voltage increased. The Ra value was larger in the hydrothermally treated
group compared with the group treated with anodization as a result of the HA crystals present on the surface after the hydrothermal
treatment. Corrosion resistance of the surface modified by anodization was significantly increased in a saline solution compared
to that for the non-treated group; this increased further after the hydrothermal treatment. These increases were most likely
due to a thick stable oxide layer formed through anodization. Thus, it is believed that titanium with its surface modified
through anodic spark oxidation would be a suitable biomaterial due to its corrosion resistance and biocompatibility. 相似文献
49.
Jae Woong Choi Gil Ho Hwang Won Kyu Han Sung Goon Kang 《Metals and Materials International》2006,12(1):75-80
Ni−B film of 1 μm thickness was electrolessly deposited on an electroplated Cu bus electrode. The film, which encapsulates
the Cu bus electrodes, prevents Cu oxidation and serves as a diffusion barrier against Cu contamination of the transparent
dielectric layer in a plasma display during the firing process at 580 °C. The microstructure of theas-deposited barrier film was amorphous phase and crystallized to Ni and Ni3B after annealing at 300 °C. The good barrier properties observed here can be explained by Ni3B precipitates at the grain boundaries acting as a fast diffusion path via pre-annealing at 300 °C before the firing process
at 580 °C. 相似文献
50.
Recently, Kim and Bell ( 2011 ) developed a revenue managemnent pricing model with price‐driven substitution. The authors considered production decisions under unlimited production capacity and investigated the impact of price‐driven substitution on a firm's pricing and production decisions. The authors modeled the consumer demands for each market segment as linear additive demand function based on exogenous variables, where demand substitution occurred as a function of price differences between the two products. In this article, we extend this work to examine the impact of a production capacity constraint on the firm's joint pricing and inventory decisions. Based on this extended model, we investigate the impact of price‐driven substitution on a firm's pricing and production decisions where there is a limit on total capacity. We show how revenue managers should adjust prices and production levels to take into account price‐driven substitution under a capacity constraint setting. Both deterministic and stochastic models are developed, and the impact of price‐driven substitution and a capacity constraint on the optimal prices, production levels, and revenues is illustrated. 相似文献