带多项偏差变元的非线性脉冲微分方程周期边值问题

发展了经典的上下解方法,建立了一些比较准则。通过运用这些结论和单调迭代技巧,得到了所考虑方程的周期边值问题的解的存在性。     

CO2-H2O和CO2-H2O-NaCl 体系的相平衡研究进展

To study the feasibility of CO2 geological sequestration,it is needed to understand the complicated mul- tiple-phase equilibrium and the densities of aqueous solution with CO2 and multi-ions under wide geological condi- tions（273.15—473.15K,0—60MPa）,which are also essential for designing separation equipments in chemical or oil-related industries.For this purpose,studies on the relevant phase equilibria and densities are reviewed and analyzed and the method to improve or modify the existing model is suggested in order to obtain more reliable predictions in a wide temperature and pressure range.Besides,three different models（the electrolyte non random two-liquid（ELECNRTL）,the electrolyte NRTL combining with Helgeson model（ENRTL-HG）,Pitzer activity coefficient model combining with Helgeson model（PITZ-HG））are used to calculate the vapor-liquid phase equilib- rium of CO2-H2O and CO2-H2O-NaCl systems.For CO2-H2O system,the calculation results agree with the experimental data very well at low and medium pressure（0—20MPa）,but there are great discrepancies above 20MPa.For the water content at 473.15K,the calculated results agree with the experimental data quite well.For the CO2-H2O-NaCl system,the PITZ-HG model show better results than ELECNRTL and ENRTL-HG models at the NaCl concentration of 0.52mol·L ^-1 .Bur for the NaCl concentration of 3.997mol·L ^-1 ,using the ELECNRTL and ENRTL-HG models gives better results than using the PITZ-HG model.It is shown that available experimental data and the thermodynamic calculations can satisfy the needs of the calculation of the sequestration capacity in the temperature and pressure range for disposal of CO2 in deep saline aquifers.More experimental data and more accurate thermodynamic calculations are needed in high temperature and pressure ranges（above 398.15K and 31.5MPa）.     

在硫酸化氧化物催化剂上二氯甲烷的低温催化降解

采用色谱微反联用技术研究了在硫酸化氧化物催化剂上二氯甲烷的低温催化降解。实验发现，硫酸化氧化物催化剂如ＴｉＯ２－（ＳＯ４）在较低反应温度（如２７５℃）时表现出较高的反应活性，转化率１００％，并且其催化活性次序为：ＴｉＯ２－（ＳＯ４）＞ＺｒＯ２－（ＳＯ４）＞ＣｅＯ２－（ＳＯ４）。实验结果还表明：催化剂的酸性关联降解二氯甲烷的催化活性。同时，水汽的存在明显降低了其催化活性。     

复合塔板的流体力学特性(Ⅱ) 操作变量和液体物性对塔板流体力学特性的影响

在前文工作的基础上进一步研究了同时具备大孔径和高开孔率条件的复合塔板 ,研究了操作变量和流体的物理性质对该复合塔板流体力学性能的影响 .结果表明 :液体的密度增加 ,塔板压降增加 ,漏液量增加 ;黏度增加 ,塔板压降降低 ;表面张力减小 ,漏液点速度上升 ,雾沫夹带增大 ,液泛速度下降.     

Effect of the Three Gorges Reservoir on vertical distribution of suspended sediment concentration and estimation accuracy of depth-average concentration in downstream reaches

The sediment regime in the middle Yangtze River has been significantly changed from quasi-equilibrium to nonequilibrium since the impoundment of the Three Georges Reservoir (TGR). To understand the effects of the TGR on vertical distribution of suspended sediment concentration (SSC) and estimation accuracy of mean concentration, vertical sediment concentration and flow velocity data at the Shashi and Jianli hydrological stations in the reach before and after the impoundment were collected. Comparisons and analysis of vertical profiles of SSC before and after the TGR impoundment show that after the impoundment of the TGR, due to the coarsening of sediment particle size, the reduction in sediment load, and the significant decrease in sediment saturation, the vertical distribution of SSC in the downstream reaches became more uneven under medium and low water flows, which was reflected in the vertical gradient and the fluctuation degree of SSC significantly increased. In addition, the depth-average sediment concentrations were calculated by the selected-point method and the mean values calculated by the “multi-point method” were regarded as the “true mean” to evaluate the accuracy of the mean value calculated by the “few-point method.” It was found that the relative errors for the selected-point method were mainly positive before impoundment but mainly negative after impoundment. Additionally, the correction factors of one-point, two-point, and three-point methods and the position of the near-bed substituted point for the five-point method were given to reduce the error when the point measurements were used to calculate the depth-average sediment concentration in the downstream reaches.     

基于格的非交互式密钥交换协议

当前网络中广泛使用的交互式密钥交换协议,如SSL协议和TLS协议,由于密钥建立过程的通信量较大,不适合物联网中传感器等资源有限的轻型网络设备使用,因此提出一种基于格的非交互式密钥交换协议.文章基于格理论的环上带误差学习困难性问题,使用Freire等人给出的非交互式密钥交换协议形式化定义和安全模型对协议的安全性进行分析,通过攻击者与挑战者之间的博弈证明了协议的安全性.该协议具有抗量子攻击安全性,能够有效地提升物联网的通信安全.     

高保真IP指挥调度系统关键技术应用

高保真IP指挥调度系统是在继承传统话音指挥调度系统的体系架构和业务应用模式的基础上,研制的新一代话音指挥调度系统.通过采用国产自主可控技术、宽频话音编码技术、大容量会议混音技术、回声消除技术及多级降噪等关键技术,系统功能、性能和安全性得到进一步提升,特别是话音质量在原来口令清晰的基础上达到了人员可辨,有效满足了未来话音指挥调度的业务需求.     

Design of a broadband dielectric resonator antenna and its application in low sensitivity frequency beam‐scanning array with wide scanning angle and suppressed sidelobes

In this paper, a broadband dielectric resonator antenna (DRA) with a simple H‐slot feeding structure is proposed. The broad bandwidth (~45%) and uni‐directional radiation enable this DRA suitable to work as a radiation element in the construction of a beam‐scanning array with not only low frequency sensitivity which is important for accurate angle estimation of in‐coming targets, but also a wide scanning range. Moreover, stable coupling coefficients are established around all the above three resonances with respect to its corresponding feeding line, ensuring a low sidelobe level (SLL) across the whole operating frequency range. In order to realize such a DRA, a latticed rectangular structure is utilized to generate the lower two resonances, while the upper resonance is generated by its H‐shaped feeding slot. The shape of the latticed dielectric resonator is also modified according to a 3‐D printed fixing structure for an accurate installation. A 20‐element beam‐scanning prototype is demonstrated and manufactured. The range of scanning angle is from ?36° to +13° within the bandwidth of 10 to 16 GHz, corresponding to a frequency sensitivity of only 122.5 MHz/^o. The achieved SLL are smaller than 19 dB for all scanning beams. The above performance indicates that, this array is very suitable for near‐range radar systems requiring an accurate angle estimation.     

形貌对ZnS微纳结构电化学电极特性影响及机制分析

在低能耗条件下以水热法实现了对ZnS材料的形貌调控,通过扫描电子显微镜及透射电子显微镜表征证明了所获得的ZnS材料为纳米颗粒、微米块和毛线球三种形貌。X射线衍射结果表明ZnS纳米颗粒及ZnS微米块为闪锌矿结构,ZnS毛线球为纤锌矿结构。以三种形貌的ZnS材料分别构建了电化学电极,以循环伏安法和交流阻抗谱对ZnS基电极的电化学特性进行了表征。结果表明,毛线球形貌的ZnS材料较大的比表面积使得以其构建的电极中电子传导速率最快,电化学特性最为优异。