EILog-05成套测井装备在长庆油田的应用

EILog-05成套测井装备是中国石油集团测井有限公司研发的具有完全自主知识产权的集成测井系统。集成化设计提高了测井仪器性能,综合化设计实现了地面系统网络化,成像测井仪器的配接成功丰富了测井项目,配套使用的一体化LEAD处理解释软件能更好地实现测井资料的现场综合解释。20井次现场试验、与ECLIPS-5700测井系统5口井的对比试验以及累计300多井次的现场应用表明,EILog-05成套测井装备的可靠性、稳定性、重复性以及与国外同类仪器测井结果的一致性均满足油田生产需要,能很好地判断长庆油田的“三低一高”复杂地层,对认识岩石三性关系和评价油气显示具有重要的作用。     

Mass transfer kinetics of neodymium(III) extraction by calix[4]arene carboxylic acid using a constant interfacial area cell with laminar flow

BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (K_ao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (E_a) was calculated to be 21·41 kJ mol^?1 or 88·17 kJ mol^?1 (dependent on temperature) from the slope of log K_ao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (C_min) is lower than 4·19 × 10^?4 mol L^?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd³⁺]_(a)/dt = k_f[Nd³⁺]_(a)[H₄A]_(o)^0·727[H⁺]_(a)^?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry     

宣钢1260 m3高炉扩容大修改造设计

宣钢l260m^3高炉大修改造时将炉容扩大到l350m^3，对高炉本体系统设备及冷却系统、自动控制及检测系统进行了全面的改造更新，在炉腹、炉腰及炉身下部高热负荷区域采用铜冷却壁，取消炉身中上部铸铁冷却壁凸台，并采用薄内衬等先进、适用、可靠、成熟的技术。     

微型构造表征技术在八面河油田的应用

通过对八面河油田井网密集区及井网稀疏的欠开发区的微构造研究,探讨了微构造表征技术。首先在储层多层次逐级对比的基础上,建立主力油层对比关系;密集井网条件下,则利用钻井资料编制油层顶底微型构造图;对于欠开发地区,通过人机联作自动追踪成图技术,输出2m等值线间隔构造图,建立微构造模型。以微构造模型为基础进行潜力评价,部署关键井寻找优质储量或进行开发动态调整。应用该项技术在八面河油田滚动发现了角15块等断鼻翼部局部高点,增加石油地质储量488×10~4t。     

Facile synthesis of nanocrystalline zinc ferrite via a self-propagating combustion method

Macroporous nanocrystalline zinc ferrite with single spinel-phase was prepared by a facile self-propagating combustion method using zinc nitrate, iron nitrate and glycine. The as-prepared ZnFe₂O₄ were characterized by X-ray diffraction (XRD) analysis, N₂ adsorption, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and energy dispersive X-ray spectrum (EDS). The magnetic properties of the prepared ZnFe₂O₄ were also studied.     

单壁碳纳米管的制备及生长特性研究

采用Fe/MgO作为催化剂 ,催化裂解CH4制备了较纯的单壁碳纳米管 ,用TEM和Raman对碳纳米管进行了表征 ,对不同生长温度下制备的碳纳米管Raman径向呼吸振动峰 (RBM)进行了分析 ,研究了生长温度对单壁碳纳米管生长特性和结构特性的影响     

自蔓延高温合成TiNi多孔体合金

为了开发新型的生体材料，本文对自蔓延高温合成TiNi多孔体合金——人造骨材料进行了研究。以单质钛粉和镍粉作原料，在氩气保护条件下，采用预热点燃模式和热爆模式制得了不同形态的多孔TiNi形状记忆合金。采用SEM和XRD分析了样品的孔洞特征和相组成，测试了其力学性能，并研究了合成条件参数与样品表面形貌和孔隙状态之间的关系。结果表明，用SHS法制备TiNi多孔体合金是可行的。     

钼酸铵溶液深度净化工艺探索

对传统的钼酸铵溶液净化工艺及文献介绍工艺进行了较为详细的分析 ,并与实验数据对比分析 ,找到了较为合理的工艺方案     

针刺机针板及刺针对产品的影响

通过对针刺机针板不同布针形式及刺针规格和型号选用的对比分析，介绍和说明了其对针刺非织造布产品的影响，提出了相应的选择依据。     

掺Yb相移光纤光栅形成过程的分析

研究了用二次曝光法制作掺Yb相移光纤光栅的实验过程 ,并对相移光纤光栅制作过程中出现次峰的情况进行了理论分析。合理地解释了该现象