U(Ⅳ)-U(Ⅵ)同位素交换反应动力学研究 Ⅰ.Fe~(2+)对U(Ⅳ)-U(Ⅵ)同位素交换反应的催化作用

一、前言由于U(IV)-U(VI)同位素交换体系具有相当大的同位素效应和很好的稳定性,并且容易实现两相回流,这对于分离U同位素的工业应用都是十分有利的。但是,U(IV)-U(VI)同位素交换反应速度非常慢,常温下H~+浓度为1.0—4.0 mol/l时,速度常数为1.0×10~(-4)l~2/mol·s。因此要用U(IV)-U(VI)交换体系浓缩铀同位素,必须研究U(IV)-U(VI)交换反应动力学,找到加快交换反应的方法。     

高放废液中^147Pm的测定

建立了高放废液中~(147)Pm的测定方法。用HDEHP萃取稀土,再用HDEHP萃淋树脂柱分离AM和稀土。然后用高效液相色谱法将~(147)Pm从Eu、Ce等其它稀土中分离出来,用液体闪烁法测量~(147)Pm的放射性活度。     

一类解析Toeplitz算子的换位子

作者用Hardy空间H2 上的再生核方法刻画了一类解析Toeplitz算子的换位子 ,同时也导出了“ThecommutantofanalyticToeplitzOperatars”的结果。     

Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

Application of artificial neural networks to the analysis of two‐dimensional fluorescence spectra in recombinant E coli fermentation processes

A two‐dimensional (2D) spectrofluorometer was used to monitor various fermentation processes with recombinant E coli for the production of 5‐aminolevulinic acid (ALA). The whole fluorescence spectral data obtained during a process were analyzed using artificial neural networks, ie self‐organizing map (SOM) and feedforward backpropagation neural network (BPNN). The SOM‐based classification of the whole spectral data has made it possible to qualitatively associate some process parameters with the normalized weights and variances, and to select some useful combinations of excitation and emission wavelengths. Based on the classified fluorescence spectra a supervised BPNN algorithm was used to predict some of the process parameters. It was also shown that the BPNN models could elucidate some sections of the process's performance, eg forecasting the process's performance. Copyright © 2005 Society of Chemical Industry     

人类HLA-DRB1基因型与民族和人群的神经网络无监督模式分类

HLA-DRB1等位基因主要参与人类的抗原免疫功能,对其进行比较研究,有助于追溯人类的进化迁移史,开发类群特异性药物.本研究以Matlab为平台,用自组织竞争网络(Self-Organizing Competitive Neural Network),对世界54个民族和人群、14个HLA-DRB1等位基因,进行了无监督模式分类.结果表明,各民族之间存在差异性,同民族的各人群之间有相似性.西伯利亚各人群,澳洲各土著人群,黑人各人群,南美印第安各人群,犹太族各人群,日本各人群,及欧美白人各人群有相对独立性:南美印第安人与西伯利亚人有高度相似性;中国民族在南方人群和北方人群间存在较大差异;中国汉族中,广东汉族地位特殊,与少数民族如拉祜族、瑶族关系密切.     

种分Δα_k与精液Al_2O_3浓度的关系

对烧结法和拜尔法种分槽的Δαk 变化进行了概述 ,阐述了精液Al2 O3 浓度关系到晶种分解的产出率、分解率、氢氧化铝粒度及系统的液量平衡、能耗等 ,生产中要把握这些影响因素 ,确保氢氧化铝晶体的长大速度为正值。     

江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.