Cholesterol‐imprinted polymer receptor prepared by a hybrid imprinting method

A novel cholesterol‐imprinted polymer (CMIP‐H) was prepared by a hybrid method of covalent imprinting and non‐covalent imprinting. This approach involves the copolymerization of a template‐containing monomer, cholesteryl 2‐hydroxyethyl methacrylate carbonate, and a cross‐linker, followed by hydrolysis to afford a flexible guest‐binding site accompanied with the easy and efficient removal of a ‘sacrificial spacer’. The effect of solvent on the binding capacity of CMIP‐H towards cholesterol was studied, indicating that a good binding capacity towards cholesterol could be achieved in a less‐polar solvent. The binding experiments of CMIP‐H towards a series of structural analogues of cholesterol, including cholesterol acetate, progesterone and stigmasterol, were carried out in hexane. The results showed that CMIP‐H almost did not bind cholesterol acetate at all because the hydrogen‐bonding site is blocked. It exhibited a similar binding towards both cholesterol and stigmasterol, but much higher binding towards progesterone. Copyright © 2005 Society of Chemical Industry     

Flammability and thermal stability studies of ABS/Montmorillonite nanocomposite

Acrylonitrile–butadiene–styrene (ABS)/montmorillonite nanocomposites have been prepared using a direct melt intercalation technique by blending ABS and organophilic clay of two different particle sizes: OMTa (5 µm) and OMTb (38 µm). Their structure and flammability properties were characterized by X‐ray diffraction, high resolution electronic microscopy (HREM), thermogravimetric analysis (TGA) and cone calorimeter experiments. The results of HREM showed that ABS/5 wt% OMTa nanocomposite was a kind of intercalated–delaminated structure, while ABS/5 wt% OMTb nanocomposite was mainly an intercalated structure. The nanocomposites showed a lower heat release rate peak and higher thermal stability than the original ABS by TGA and cone calorimeter experiments. Also, the intercalated nanocomposite was more effective than an exfoliated–intercalated nanocomposite in fire retardancy. Copyright © 2003 Society of Chemical Industry     

纸张用有机硅抗水剂的制备

采用氨基硅油、十二烷基三甲氧基硅烷、甲基三乙氧基硅烷配成11种抗水剂,用于纸张的抗水处理.通过渗透法和接触角法测试发现,有机硅抗水剂对实验选择的9种纸张均有明显的抗水效果;其中采用氨基硅油配制的抗水剂效果最好,经其处理的生宣纸与空白样相比,接触角由完全润湿提高到125°,渗透时间由0提高到18 s.最佳应用工艺为:将氨基硅油配制成质量分数为2.041%的甲苯溶液,按照10g/m2的涂布量喷涂于纸张表面,自然晾干3～5天至恒定质量.     

凤滩水电厂自动发电控制策略

介绍了凤滩水电厂自动发电控制(AGC)策略的实现方法,重点介绍了修正等容量比例有功分配方法及相应措施.程序设计的原则是,机组紧跟目标负荷的情况下,在最佳效率下运行,同时减少机组开/停机次数、有功调节频率和跨越振动区次数,从而减少机组磨损,兼顾运行效率和机组运行安全.     

纤维艺术的另一种诠释（Ⅱ）：从室内空间中领悟现代纤维艺术

现代纤维艺术与室内空间及人 空间属人的感知。在求美于视、听、触等诸种感知中，视觉感智是首要的。视觉是人们认识空间的一种主要手段，而现代纤维艺术的根本职能，就是建立更适合人的室内空间环境，即为了使人的视觉、触觉等感知得到更多的美愉悦。     

一种基于时间分层决策矩阵的综合评价算法

综合评价系统用四元总体（A，Z，X^(k)，D）表示，其中决策矩阵X^(k)是具有对象维i,指标维j,时间维k的三维矩阵，将三维矩阵X（k)按时间划分形成m个二维矩阵，每个二维矩阵分别代表每个年度n个评价对象对应于p个指标的属性集，讨论了按时间分层决策矩阵的多指标综合评价问题，描述了按时间分层的决策矩阵的求解算法，并采用Visual Foxpro数据库语言编程实现。     

NaI多道脉冲幅度分析系统在燃料元件破损监测中的应用研究

介绍了船用堆燃料元件破损监测中较常用的两种方法.通过分析其缺陷,提出了用NaI多道脉冲幅度分析系统测量特征核素(131I、137Cs)的方法,有效避免了监测中的干扰因素的影响,降低了定量监测中的误报率,提高了燃料元件破损监测的效率和置信度.