AgBr-Ag3PO4-CSs三元复合光催化剂的制备及性能

以AgNO_3、KBr、Na_2HPO_4和碳球(CSs)为原料,通过共沉淀法制备了高活性的AgBr-Ag_3PO_4-CSs三元复合光催化剂。利用X射线衍射、场发射扫描电子显微镜、紫外-可见漫反射光谱和X射线光电子能谱等对复合催化剂的结构、形貌、光吸收范围及价态进行了表征,通过可见光下降解罗丹明B(RhB)和苯酚对复合催化剂的性能进行了考察。结果表明:以CSs为载体,将AgBr和Ag_3PO_4负载在CSs上,当n(AgBr):n(Ag_3PO_4)=4:100时,所得的4%AgBr-Ag_3PO_4-CSs复合催化剂光催化效果最佳,可见光照50 min时,对RhB的降解率达到99.3%;光照60 min时,降解率达到99.5%,几乎降解完全。对苯酚也具有超强的降解能力,捕获剂实验表明空穴为主要活性物种,并且所制备的复合光催化剂循环使用5次后时仍具有较高的光催化活性。     

不同晶相结构ZrO2负载铜基催化剂用于二乙醇胺脱氢反应

通过制备不同晶相结构〔单斜相(m-ZrO_2)、四方相(t-ZrO_2)和无定型(a-ZrO_2)〕ZrO_2载体,再通过沉积沉淀法制得Cu/m-ZrO_2、Cu/t-ZrO_2和Cu/a-ZrO_2催化剂,分别用于催化二乙醇胺脱氢合成亚氨基二乙酸反应。采用XRD、氮气物理吸附脱附、XPS、H_2-TPR、CO_2-TPD对催化剂的结构进行了表征。结果表明,Cu/m-ZrO_2催化剂界面更加有利于Cu~+/Cu~0稳定存在,具有更多的碱性位点,且抗氧化性较好。在二乙醇胺脱氢反应中,Cu/m-ZrO_2催化剂性能最好,反应时间为2.5 h,亚氨基二乙酸收率为97.64%。     

移动式含油污泥处理装置管道设计——离心处理装置

本文主要介绍了移动式含油污泥处理装置——离心处理装置的管道设计工作。     

Toward Energy-Efficient and Trustworthy eHealth Monitoring System

The rapid technological convergence between Internet of Things(IoT),Wireless Body Area Networks(WBANs)and cloud computing has made e-healthcare emerge as a promising application domain,which has significant potential to improve the quality of medical care.In particular,patient-centric health monitoring plays a vital role in e-healthcare service,involving a set of important operations ranging from medical data collection and aggregation,data transmission and segregation,to data analytics.This survey paper firstly presents an architectural framework to describe the entire monitoring life cycle and highlight the essential service components.More detailed discussions are then devoted to {\em data collection} at patient side,which we argue that it serves as fundamental basis in achieving robust,efficient,and secure health monitoring.Subsequently,a profound discussion of the security threats targeting eHealth monitoring systems is presented,and the major limitations of the existing solutions are analyzed and extensively discussed.Finally,a set of design challenges is identified in order to achieve high quality and secure patient-centric monitoring schemes,along with some potential solutions.     

NH_3-OH体系中共沉淀法同时回收钕铁硼废料中Nd-Pr-Co-Fe

为了避免回收单一钕铁硼废料中有价元素带来的操作复杂和资源浪费等问题,本研究采用共沉淀法共沉淀出钕铁硼废料中的有价元素Me(Nd,Pr,Co,Fe),制备可用于生产再生钕铁硼的原料;根据质量守恒和同时平衡原理,采用MATLAB软件建立Me(Nd,Pr,Co,Fe)-OH--NH3热力学模型,绘制lg[Me]-p H曲线模拟共沉淀工艺,并根据模拟结果确立了共沉淀工艺;模拟和实验的结果表明:根据lg[Me]-p H模拟结果可以确立一步共沉淀法的p H:6~10,Fe3+比Fe2+更易于沉淀完全;在上述条件下获得的共沉淀粉末主相均为Nd,Pr,Co,Fe的化合物,且有价元素的百分比含量均大于99.4%;其中,当p H值在8左右时回收率最高,在该条件下金属元素Me(Nd,Pr,Co,Fe)的沉淀效率分别为:98.7%,99.9%,93.6%,99.9%。该结果也表明共沉淀法工艺不仅高效,而且所制备的共沉淀粉末可以满足制备二次钕铁硼的需要。     

大型复杂工程管理的方法论

本文首先对大型工程系统中的复杂性展开详细分析,然后结合复杂性管理中的各种概念和理论,进一步探讨大型复杂工程管理上的综合集成管理方法论,以供参考。     

Health Monitoring of Long-Haul Fiber Communication System Using Chaotic OTDR

A novel chaotic optical time-domain reflectometry(OTDR)-based approach was proposed for monitoring long-haul fiber communication systems with multiple fiber segments. The self-phase modulation and group velocity dispersion effects of the optical cable was considered in demonstrating the proof-of-concept experiment and simulation. In experiments, the correlation peaks are clearly obtained from the correlation trace between the reference and reflected(or scattered) light signals propagating in three optical-fiber segments. The technique affords a high spatial resolution of 2 m, and further long-haul fiber simulations indicate that the sensing distance can be more than 3300 km. Thus, the new proposed technique can be effectively applied for health monitoring of long-haul fiber communication systems.     

基于教学中单片机系统的可靠性分析

在高职院校中,单片机系统是一项不可缺少的技术。但是单片机系统在运行过程中会受到外界的干扰而出现问题,所以需要提高单片机控制系统的可靠性,才能够提高高职院校各科目的教学质量。     

基于嵌入式系统的智能购物车的开发研究

智能超市购物车主要解决超市购物过程中寻找商品困难,付款排队时间久,购物体验差,效率低下等问题。文章主要介绍智能购物车的硬件组成、工作原理、使用意义等。智能购物车具有室内导航、条码扫描、管理购物列表、生成付款码等功能。当我们推着购物车在超市购物时,可以通过触摸屏输入寻找所需商品名称获取导航路线;可以通过扫描商品条码查看商品基本信息;可以随时查看已购物品的单价和总价钱等。在付款时也可以通过选择扫码支付或者现金支付的方式。智能超市购物车的使用,能够大大提高购物效率,提升购物体验,达到超市和顾客双赢的目的。