Effect of acetylation and succinylation on solubility profile, water absorption capacity, oil absorption capacity and emulsifying properties of mucuna bean (Mucuna pruriens) protein concentrate

Mucuna protein concentrate was acylated with succinic and acetic anhydride. The effects of acylation on solubility, water absorption capacity, oil absorption capacity and emulsifying properties were investigated. The pH-dependent solubility profile of unmodified mucuna protein concentrate (U-mpc) showed a decrease in solubility with decrease in pH and resolubilisation at pH values acidic to isoelectric pH (pH 4). Apart from pH 2, both acetylated mucuna protein concentrates (A-mpc) and succinylated mucuna protein concentrate (S-mpc) had improved solubility over the unmodified derivative. Acylation increased the water absorption capacity (WAC) at all levels of ionic strength (0.1-1.0 M). WAC of the protein samples increased with increase in ionic strength up to 0.2 M after which a decline occurred with increase in ionic strength from 0.4-1.0 M. When protein solutions were prepared in salts of various ions, increase in WAC followed the Hofmeister series in the order: NaSCN < NaClO4 < NaI < NaBr < NaCl < Na2SO. Acetylation improved the oil absorption capacity while the lipophilic tendency reduced the following succinylation. Emulsifying capacity increased with increase in concentration up to 2, 4 and 5% w/v for U-mpc, A-mpc and S-mpc, respectively, after which an increase in concentration reduced the emulsifying capacity. Both acetylation and succinylation significantly (P < 0.05) improved the emulsifying capacity at pH 4-10. Initial increase in ionic strength up to 0.4 M for U-mpc and 0.4 M for A-mpc and S-mpc increased the emulsion capacity progressively. Further increase in ionic strength reduced emulsion capacity (EC). Contrary to the effect of various salts on WAC, increase in EC generally follows the series Na2SO4 < NaCl < NaBr < NaI < NaClO4 < NaSCN. At all levels of ionic strength studied, S-mpc had a better emulsifying activity (EA) than both A-mpc and U-mpc. EA and emulsifying stability (ES) were pH-dependent. Maximum EA and ES were recorded at pH 10. ES of protein derivatives were higher than those of U-mpc in the range of pH 4-10 but lower at pH 2. Studies revealed that both A-mpc and S-mpc had better ES and EA than the unmodified derivative when protein solutions were prepared in salts of various anions.     

Failure Analysis of an Effluent Treatment Plant in an Oral Care Industry

Reports of environmental pollution by industries worldwide call for an urgent need to assess wastewater treatment facilities in various industries. This study presents an assessment of a wastewater treatment plant in an oral care (toothpaste) industry. The industry was visited, facilities for wastewater treatment were assessed (based only on efficacy to remove selected environmental and human’s health-related pollutants) and measurement of essential design parameters and facility characteristics were conducted. The study revealed that the averages of flow rate, biochemical oxygen demand at 5 days (BOD₅), chemical oxygen demand (COD), suspended solids (SS), iron concentration, and total solids (TS) in the influent wastewater into the plant were 4.96 ± 0.6 m³/d; 90 ± 5 mg/L; 224 ± 8 mg/L; 1266.78 ± 10.24 mg/L; 0.31 ± 0.11 mg/L, and 2198.65 ± 20.44 mg/L, respectively. Individual efficacies were as follows: 0.49, 0.28, and 0.38% for SS, TS, and calcium, respectively. The overall efficacy of the wastewater treatment facility was found to be 0.020% which was significantly lower than expected. This indicates that no treatment was conducted on the wastewater and that the wastewater is being discharged into the environment essentially untreated. Equalization time (t _eq) was found to be 2.0 h with equivalent equalized BOD₅ concentration of 90 ± 5 mg/L, while expected volume for the equalization tank is 1.5 m³. It was concluded that failure (lower overall efficacy) of the system can be attributed to lack of an equalization tank, inadequate treatment processes, and refusal to apply standardized engineering code and practices. Although such conditions are rare in developed nations, these results demonstrate the problems in pollution control in developing communities.     

Evaluating mobile app usage by service sector micro and small enterprises in Nigeria: an abductive approach

ABSTRACT

This research investigated how mobile apps influence the dynamic capabilities of service sector micro and small enterprises (MSEs) in Lagos, Nigeria. Using an abductive method, data from 388 service sector MSEs was examined through exploratory factor analysis. The resultant model suggests that mobile app usage barely increases the absorptive capability (integrating new learning into the organization) of MSEs; rather, it strongly influences the ability to seize opportunities. The result implies that mobile app usage by service sector MSEs in Lagos deviates from the conventional views on the micro foundations of the dynamic capability framework, which argues that sensed opportunities are first analysed (shaped) before resources are deployed towards their maximization. These findings suggest that the service sector MSEs in Lagos seldom scrutinize opportunities before deploying resources to seize them. This study extends IS literature on how mobile apps help MSEs to exploit business opportunities in resource-constrained contexts.     

The effect of some operating variables on the adsorption of lead and cadmium ions on kaolinite clay

Modification of kaolinite clay mineral with orthophosphate (p-modified sample) enhanced adsorption of Pb and Cd ions from aqueous solutions of the metal ions. Increasing pH of solutions of metal ions, increasing adsorbent dose and increasing concentration of metal ion, increased the adsorption of metal ions. Adsorption of both metal ions simultaneously on both unmodified and p-modified samples indicates that adsorption of one metal ion is suppressed to some degree by the other. The presence of electrolyte and their increasing concentration reduced the adsorption capacities of both unmodified and p-modified samples for the metal ions. Ca-electrolytes had more negative effect on the adsorption capacities of the adsorbents than Na-electrolytes. Ca-electrolytes reduced adsorption capacities of the adsorbents for Pb and Cd ions. From Langmuir plots it was observed that these electrolytes increased the binding energy constant of the metal ions unto the adsorbents especially on the p-modified samples. The rate of adsorption of Pb and Cd ions on p-modified adsorbent were increased and equilibrium of metal ion solution were more quickly reached (8min for Pb ions and 12min for Cd ions) with p-modified adsorbent as against 20min for adsorption of both metal ions on unmodified adsorbent when 200mg/L of metal ion solutions were used during the kinetic studies. When adsorption data were fitted against Langmuir, Freundlich, Toth and Langmuir-Freundlich isotherms, satisfactory fits were found with the Freundlich isotherm. However, at low concentration of metal ions, data also showed satisfactory fits to Langmuir isotherm.     

Predicting the dynamics and performance of a polymer–clay based composite in a fixed bed system for the removal of lead (II) ion

A polymer–clay based composite adsorbent was prepared from locally obtained kaolinite clay and polyvinyl alcohol. The composite adsorbent was used to remove lead (II) ions from aqueous solution in a fixed bed mode. The increase in bed height and initial metal ion concentration increased the adsorption capacity of lead (II) and the volume of aqueous solution treated at 50% breakthrough. However, the adsorption capacity was reduced by almost 16.5% with the simultaneous presence of Ca²⁺/Pb²⁺ and Na⁺/Pb²⁺ in the aqueous solution. Regeneration of the adsorbent with 0.1 M of HCl also reduced its adsorption capacity to 75.1%. Adsorption of lead (II) ions onto the polymer–clay composite adsorbent in the presence of Na⁺ and Ca²⁺ electrolyte increased the rate of mass transfer, probably due to competition between cationic species in solution for adsorption sites. Regeneration further increased the rate of mass transfer as a result of reduced adsorption sites after the regeneration process. The length of the mass transfer zone was found to increase with increasing bed height but did not change with increasing the initial metal ion concentration. The models of Yoon–Nelson, Thomas, and Clark were found to give good fit to adsorption data. On the other hand, Bohart–Adams model was found to be a poor predictor for the column operation. The polymer–clay composite adsorbent has a good potential for the removal of lead (II) ions from highly polluted aqueous solutions.