Characterization of vanadyl phthalocyanine based surface-type capacitive humidity sensors

This study presents the fabrication and characterization of novel surface-type capacitive humidity sensors using vanadyl phthalocyanine (VOPc) as the active material. The devices, which comprise three different thicknesses,have been fabricated using the thermal evaporation technique. A thin film of VOPc is deposited on thoroughly cleaned glass substrates with pre-pattemed Ag electrodes. The capacitive effect of the samples under humidity has been in-vestigated. Comparison of the samples with different thicknesses shows that the thinnest device seems more sensitive towards humidity. The humidity dependent capacitance properties of the sensor make it beneficial for use in commercial hygrometers.     

Engineering Iron Oxide Hollow Nanospheres to Enhance Antimicrobial Property: Understanding the Cytotoxic Origin in Organic Rich Environment

Engineered magnetic iron oxide nanoparticles with surprisingly high antimicrobial activity and excellent safety profiles to mammalian cell lines have been developed. Hematite hollow nanospheres (HNSs) are prepared by a facile hard templating method; reduction of hematite HNSs by H₂ leads to magnetite HNSs. The antimicrobial activity of magnetite HNSs towards Gram negative (Escherichia coli) and Gram positive (Staphylococcus epidermidis) bacteria is evaluated against hematite HNSs and conventional magnetite (C‐magnetite; diameter <50 nm). Superior antibacterial performance is observed for magnetite HNSs towards both E. coli and S. epidermidis over hematite HNSs and C‐magnetite. The origin of the antimicrobial activity of magnetite HNSs is the high leaching of iron ions in the presence of microorganisms, which leads to high generation of reactive oxygen species. Magnetite HNSs allow multiple‐fold increase in the generation of soluble iron ions over hematite HNSs and C‐magnetite, showing that control over both the composition and nanostructure is crucial to tune the antimicrobial activity of iron oxides. Based on the current findings, magnetic HNSs show promising potential antimicrobial applications.     

Effect of Newtonian Heating and Thermal Radiation on Heat and Mass Transfer of Nanofluids over a Stretching Sheet in Porous Media

Laminar boundary layer slip flow from a stretching surface in a nanofluid‐saturated homogenous, isotropic porous medium is studied numerically. A Newtonian heating boundary condition in the presence of thermal radiation is incorporated and a Darcy model utilized for the porous medium. The model used for the nanofluids include the effects of Brownian motion and thermophoresis. A group theoretical analysis is conducted to generate similarity transformations. The governing transport equations are nondimensionalized and rendered into a set of coupled similarity ordinary differential equations using similarity transformations. The transformed equations are then solved using the Runge–Kutta–Fehlberg fourth‐fifth order numerical method with shooting technique. It is shown that the physical quantities of interest depend on a number of parameters. The results are presented in tabular and graphical forms. Comparison of the present numerical solutions with published work shows very good agreement. The study finds applications in high‐temperature nanotechnological materials processing.     

Optimized photovoltiac system for hydrogen production

Hydrogen, which can be produced by water electrolysis, can play an important role as an alternative to conventional fuels. It is regarded as a potential future energy carrier. Photovoltaic arrays can be used in supplying the water electrolysis systems by their energy requirements. The use of photovoltaic energy in such systems is very suitable where the solar hydrogen energy systems are considered one of the cleanest hydrogen production technologies, where the hydrogen is obtained from sunlight by directly connecting the photovoltaic arrays and the hydrogen generator. This paper presents a small PV power system for hydrogen production using the photovoltaic module connected to the hydrogen electrolyzer with and without maximum power point tracker. The experimental results developed good results for hydrogen production flow rates, in the case of using maximum power point tracker with respect to the directly connected electrolyzer to the photovoltaic modules.     

Prospects and challenges of using hydropower for electricity generation in Lebanon

In a region characterized by low water resources, Lebanon stands as an exceptional country in the Middle East. Several waterways present ample opportunity for utilization of hydropower. Before the civil war, several projects were undertaken to generate electricity through hydropower. A total installed capacity of 283 MW has aided Lebanon in supplementing its need of electricity from local renewable sources, thus reducing the overall bill of imported energy. The available hydropower generation constitutes currently 4–7% of the electricity generation depending on rainfall, with future plans expected to install another 205 MW of capacity. This use is in competition with water diversion for irrigation. Four different scenarios were analyzed to indicate the share of hydropower in the total production of electricity, with and without future irrigation and power projects, indicating that, by 2020, hydropower's share of electricity generation will vary between a maximum of 6.9% and a minimum of 1.2% depending on government plans regarding water use. Current value of potential energy available when water from the Litani river is used for hydropower is estimated to be around 20 cents per m³. Water uses planned should take this value into account.     

Second harmonic generation from LB superlattices containing two active components

Second harmonic generation has been observed from Langmuir-Blodgett multilayer arrays containing two active components. Both materials were based on long chain donor-acceptor dye compounds, but were designed with the donor-acceptor groups in opposite senses with respect to the hydrocarbon chain. Preliminary results indicate a significant enhancement of the second-order polarisability for this type of supermolecular array.     

Quantitative preparation of long chain thioethers from an oxo-trans-2-enoic ester and a 9,12-dioxo-trans-10-enoic acid

Branched-chain thioethers have been prepared from methyl 4-oxo-trans-2-hexadecenoate and 9,12-dioxo-trans-10-octadecenoic acid. The reagents involved in these preparations were mercaptoacetic and mercaptopropionic acids. The yields of these thioethers are almost quantitative.     

Plasma Internal Inductance in the Presence of External Resonant Fields in IR-T1 Tokamak

In this paper we presented experimental investigation of effects of local limiter biasing (V_biasing = +200 v, V_biasing = +320 v) on the plasma parameters as plasma current, loop voltage, poloidal beta, plasma pressure, plasma energy, plasma resistance, plasma temperature, plasma displacement, Shafranov parameter and plasma internal inductance in IR-T1 tokamak. For these purposes, array of magnetic probes and also a diamagnetic loop have been used. The results show that applied biased voltage V_biasing = +200 v causes to decrease of about 40 % in plasma internal inductance. The plasma resistance and the plasma displacement have been decreased by V_biasing = +200 v. The main result of the application of V_biasing = +200 v is flatting the plasma parameters profiles. In other words, the addition of biasing voltage V_biasing = +200 v to plasma could be effective for improving the quality of tokamak plasma discharge by creating the steady state plasma. The plasma current, plasma pressure, plasma energy, plasma temperature and shift parameter have increased after the application of limiter biasing with V_biasing = +320 v but they decrease rapidly.