Solubility Limit of MgO in Al2O3 at 1600°C

The solubility of Mg in alumina was measured using wavelength-dispersive spectroscopy mounted on a scanning electron microscope. Careful calibration of the microscope's working conditions was performed in order to optimize the detection limit and accuracy. Measurements were conducted on water-quenched and furnace-cooled samples, without any thermal or chemical etching to avoid alteration of the bulk concentration. The results indicate the solubility limit of Mg in alumina to be 132±11 ppm at 1600°C.     

Transient detection in COTS processors using software approach

This paper presents a software-based error detection scheme called enhanced committed instructions counting (ECIC) for embedded and real-time systems using commercial off-the-shelf (COTS) processors. The scheme uses the internal performance monitoring features of a processor, which provides the ability to count the number of committed instructions in a program. To evaluate the ECIC scheme, 6000 software induced faults are injected into a 32-bit Pentium® processor. The results show that the error detection coverage varies between 90.52% and 98.18%, for different workloads.     

Phospholipids and oxophospholipids in atherosclerotic plaques at different stages of plaque development

We identified and quantified the hydroperoxides, hydroxides, epoxides, isoprostanes, and core aldehydes of the major phospholipids as the main components of the oxophospholipids (a total of 5–25 pmol/μmol phosphatidylcholine) in a comparative study of human atheroma from selected stages of lesion development. The developmental stages examined included fatty streak, fibrous plaque, necrotic core, and calcified tissue. The lipid analyses were performed by normal-phase HPLC with on-line electrospray MS using conventional total lipid extracts. There was great variability in the proportions of the various oxidation products and a lack of a general trend. Specifically, the early oxidation products (hydroperoxides and epoxides) of the glycerophosphocholines were found at the advanced stages of the plaques in nearly the same relative abundance as the more advanced oxidation products (core aldehydes and acids). The anticipated linear accumulation of the more stable oxidation products with progressive development of the atherosclerotic plaque was not apparent. It is therefore suggested that lipid infiltration and/or local peroxidation is a continuous process characterized by the formation and destruction of both early and advanced products of lipid oxidation at all times. The process of lipid deposition appears to have been subject to both enzymatic and chemical modification of the normal tissue lipids. Clearly, the appearance of new and disproportionate old lipid species excludes randomness in any accumulation of oxidized LDL lipids in atheroma.     

Ozone formation potential of organic compounds in the Eastern United States: a comparison of episodes, inventories, and domains

Direct sensitivity analysis is applied for 3-D assessment of ozone reactivity (or ozone formation potential) in the Eastern United States. A detailed chemical mechanism (SAPRC-99) is implemented in a multiscale air quality model to calculate the reactivity of 32 explicit and 9 lumped compounds. Simulations are carried out for two different episodes and two different emission scenarios. While absolute reactivities of VOCs show a great deal of spatial variability, relative reactivities (normalized to the reactivity of a base mixture) produce a significantly more homogeneous field. Three types of domain-wide relative reactivity metrics are formed for 1-h and 8-h averaging intervals. In general, ozone reactivity metrics (with the exception of those based on daily peak ozone) are fairly robust and consistent between different episodes or emission scenarios. The 3-D metrics also show fairly similar rankings for VOC reactivity when compared to the box model scales. However, the 3-D metrics have a noticeably narrower range for species reactivities, as they result in lower reactivity for some of the more reactive, radical-producing VOCs (especially aldehydes). As expected, episodes and emission scenarios with less radical availability have higher absolute reactivities for all species and higher relative reactivities for the more radical-producing species. Finally, comparing the results with those from a different domain (central California) shows that relative reactivity metrics are comparable over these two significantly different domains.     

Element distinctness on one-tape Turing machines: a complete solution

We give a complete characterization of the complexity of the element distinctness problem for n elements of bits each on deterministic and nondeterministic one-tape Turing machines. We present an algorithm running in time for deterministic machines and nondeterministic solutions that are of time complexity . For elements of logarithmic size , on nondeterministic machines, these results close the gap between the known lower bound and the previous upper bound . Additional lower bounds are given to show that the upper bounds are optimal for all other possible relations between m and n. The upper bounds employ hashing techniques, while the lower bounds make use of the communication complexity of set disjointness.Received: 23 April 2001, Published online: 2 September 2003Holger Petersen: Supported by Deutsche Akademie der Naturforscher Leopoldina, grant number BMBF-LPD 9901/8-1 of Bundesministerium für Bildung und Forschung.     

In vivo quantitative three-dimensional localization of tumor labeled with exogenous specific fluorescence markers

We introduce a diffused optical detection system based on the administration of a fluorophore-antibody conjugate to diseased tissue. The conjugate interacts with the antigens expressed by the diseased tissue, resulting in fluorescent labeling of the antigen. By combining an optical detection system with a reconstruction algorithm developed on the basis of the random-walk model, we were able to determine the position of the fluorophore (and, thus, of the diseased cells) in the tissue. We present three-dimensional reconstructions of the location of a fluorophore (FITC-fluorescein isothiocyanate) in the tongues of mice. Measurements were performed with the fluorophore embedded at various simulated depths. The simulations were performed with agarose-based gel slabs applied to the tongue as tissuelike phantoms. Reconstructed fluorophore locations agree well with the actual values.     

Sensitivity analysis of narrowband photonic crystal filters and waveguides to structure variations and inaccuracy

Photonic crystal microcavities, formed by local defects within an otherwise perfectly periodic structure, can be used as narrowband optical resonators and filters. The coupled-cavity waveguide (CCW) is a linear array of equally spaced identical microcavities. Tunneling of light between microcavities forms a guiding effect, with a central frequency and bandwidth controlled by the local defects' parameters and spacing, respectively. We employ cavity perturbation theory to investigate the sensitivity of microcavities and CCWs to random structure inaccuracies. For the microcavity, we predict a frequency shift that is due to random changes in the lattice structure and show an approximate linear dependence between the standard deviation of the structure inaccuracy and that of the resonant frequency. The effect of structural inaccuracy on the CCW devices, however, is different; it has practically no effect on the CCW performance if it is below a certain threshold but may destroy the CCW if this threshold is exceeded.     

The hardness of the Expected Decision Depth problem

Given a function f over n binary variables, and an ordering of the n variables, we consider the Expected Decision Depth problem. Namely, what is the expected number of bits that need to be observed until the value of the function is determined, when bits of the input are observed according to the given order. Our main finding is that this problem is (essentially) #P-complete. Moreover, the hardness holds even when the function f is represented as a decision tree.     

Georeferenced Registration of Construction Graphics in Mobile Outdoor Augmented Reality

This paper describes research that investigated the application of the global positioning system and 3 degree-of-freedom (3-DOF) angular tracking to address the registration problem during interactive visualization of construction graphics in outdoor augmented reality (AR) environments. The global position and the three-dimensional (3D) orientation of a user’s viewpoint are tracked, and this information is reconciled with the known global position and orientation of superimposed computer-aided design (CAD) objects. Based on this computation, the relative translation and axial rotations between the user’s viewpoint and the CAD objects are continually calculated. The relative geometric transformations are then applied to the CAD objects inside a virtual viewing frustum that is coincided with the real world space that is in the user’s view. The result is an augmented outdoor environment where superimposed graphical objects stay fixed to their real world locations as the user navigates. The algorithms are implemented in a software tool called UM-AR-GPS-ROVER that is capable of interactively placing static and dynamic 3D models at any location in outdoor augmented space. The concept and prototype are demonstrated with an example in which scheduled construction activities for the erection of a structural steel frame are graphically simulated in outdoor AR.     

Hydrothermally Oxidized Single‐Walled Carbon Nanotube Networks for High Volumetric Electrochemical Energy Storage

Improving volumetric energy density is one of the major challenges in nanostructured carbon electrodes for electrochemical energy storage device applications. Herein, a simple hydrothermal oxidation process of single‐walled carbon nanotube (SWNT) networks in dilute nitric acid is reported, enabling simultaneous physical densification and chemical functionalization of the as‐assembled randomly‐packed SWNT films. After the hydrothermal oxidation process, the density of the SWNT films increases from 0.63 to 1.02 g cm^?3 and a considerable amount of redox‐active oxygen functional groups are introduced on the surface of the SWNTs. The functionalized SWNT films are used as positive electrodes against Li metal negative electrodes for potential Li‐ion capacitors or Li‐ion battery applications. The functionalized SWNT electrodes deliver high volumetric as well as gravimetric capacities, 154 Ah L^?1 and 152 mAh g^?1, respectively, owing to the surface redox reactions between the introduced oxygen functional groups and Li ions. In addition, these electrodes exhibit a remarkable rate‐capability by retaining its high capacity of 94 Ah L^?1 (92 mAh g^?1) at a high discharge rate of 10 A g^?1. These results demonstrate the simple hydrothermal oxidation process as an attractive strategy for improving the volumetric performance of nanostructured carbon electrodes.