Behavior,distribution and environmental influence of arsenic in a typical lead smelter

A field study was conducted to determine the behavior and distribution of arsenic during the pyrometallurgy process in a typical SKS(Shuikoushan) lead smelter in Hunan province, China. Environmental influences of arsenic in selected samples were evaluated. Arsenic contents in all input and output samples vary from 0.11% in raw lead to 6.66% in collected dust-2. More arsenic is volatilized in blast furnace and fuming furnace(73.02% of arsenic input) than bottom blowing furnace(10.29% of arsenic input).There are 78.97%, 13.69%, 7.31% of total arsenic distributed in intermediate materials, stockpiled materials and unorganized emissions, respectively. Matte slag-2, collected dust-1 and secondary zinc oxide are hazardous based on the arsenic concentrations of toxicity characteristic leaching procedure. According to risk assessment code(RAC) guideline, arsenic in collected dust-1 poses a very serious risk to the surrounding environment, arsenic in speiss, matte slag-2, water-quenched slag and secondary zinc oxide show low risk, while arsenic in matte slag-1, collected dust-2 and post dust has no risk to the environment.     

基于能量平衡的无线传感器网络非随机分簇算法（英文）

无线传感器网络(WSNs)路由协议的设计受到传感器的节点特征、网络行为和应用需求等的影响,网络拓扑结构的变化对节点之间通信路径的影响非常关键。分簇是减少能量消耗和增强网络可扩展性的一种有效的拓扑控制技术。为了节约能耗,提出了能量平衡的非随机分簇算法。该算法采用最小能量分簇技术形成簇群,利用最小的通信距离来选择最优的簇头(CH)。仿真结果表明该算法延长了网络寿命,与集中式的LEACH-C算法相比,提高了能量利用效率。     

关于加强高校思想政治理论课防范和抵御校园传教渗透作用的思考

近年来,高校大学生信教人数呈较快增长趋势。敌对势力利用新兴媒体加紧对校园进行传教渗透,部分大学生对宗教的暧昧态度,高校思想政治工作的弱化特别是思想政治理论课功能的缺失,是导致这一状况的重要原因。有针对性地完善思想政治理论课相关内容、加强教师队伍建设,充分发挥思想政治理论课的主渠道作用与思想政治教育工作的协调联动作用,是新媒体环境下防范和抵御校园传教渗透的有效途径。     

网络公共资源防护技术研究

提出了一种网络公共资源防护系统,用于有效阻止对网络公共资源的恶意破坏、提高网络资源的末端防护能力、保证信息服务的安全可靠。首先,根据网络公共资源自身的特点和防护需求,为了使整个防护系统能够灵活、高效地运转,设计了一种“监测-处理-恢复-监测”闭环反馈运转机制;然后,介绍了系统中的体系化联动机制和主动防御方法。实验结果表明：平均资源修复速率为本地31.95KB/毫秒,网络16.10KB/毫秒。系统部署后,访问测试网站的平均响应时间仅降低了1.93%,不会影响资源的可用性。     

柴达木盆地涩北气田疏松砂岩气藏水气体积比及水侵预警

柴达木盆地涩北气田属于弱边水驱动的背斜型浅层疏松砂岩气田,采用衰竭式开采。根据水气体积比,其气藏生产过程可分为4个阶段,即低含水稳产阶段、初期水侵阶段、边水突破阶段和强水侵阶段。依照水气体积比变化,可以准确监测水侵的发生,水侵突破阶段可以作为预判边水大规模水侵的时间窗口,以调整开采方案,延长稳产期;高含水的强水侵阶段,生产周期较长,是带水开采提高采收率的重要阶段。     

Dual-responsive shape memory hydrogels with self-healing and dual-responsive swelling behaviors

Shape memory hydrogels (SMHs) can fix the hydrogels in a provisional shape and restore the initial shape under external stimulation. Herein, a dual-responsive shape memory hydrogel with dual-responsive swelling and self-healing properties is presented in this work. The SMHs were fabricated by one-step emulsion copolymerization of acrylic acid (AAc), acrylamide (AAm) and stearyl methacrylate (SMA). Sodium alginate (SA) was introduced as an interpenetrating polymer in the network. With ionic cross-linking between -COO⁻ and Fe³⁺ or saline-reinforced hydrophobic association, the hydrogels can be fixed in a provisional shape, which can be restored by immersing the hydrogels in vitamin C solution or pure water, respectively. When the as-prepared hydrogels were immersed in FeCl₃ solutions, additional ionic cross-linking between Fe³⁺ and -COO⁻ could be formed, thus constructing the dual physically cross-linked (DPC) network, which endows the hydrogels with excellent fracture stress (2.6 MPa) and toughness (5.47 MJ/m³). Besides, the reversible physical cross-linkings endowed the hydrogel with outstanding self-healing capability. Furthermore, the pH and saline responsive swelling properties of the SMHs are additional fantastic properties. Therefore, we believe that this simple strategy provides a great opportunity for the preparation of SMHs with multiple intellectual performances.     

生物原油炼制： 副产物内循环及水热自催化

利用高温高压条件模拟石油生成的生物质水热液化技术可用于制备生物原油,以替代日益枯竭的石油资源,然而副产物处置问题制约了其可持续发展。解决该问题的方法首先是通过水热定向催化调控减少副产物,然后集成各种技术将副产物尽可能原位资源化。基于此并依据生物炼制的思想,本文对一种集成几种水热技术炼制生物原油的模式进行了讨论。依据生物质水热液化副产物的特性,通过对固体产物水热合成制备催化剂、水相产物回用产生有机酸、气体产物分离或彻底氧化后水热还原生产有机酸等,可实现副产物内循环并强化自催化生成生物原油。指出该模式符合绿色化工的理念,对于加快规模化生产可替代石油的生物原油、缓解能源危机具有重要的参考意义。     

一例1000kV单相自耦变压器局部放电故障的诊断与分析

分析了一台1000kV单相自耦变压器局放试验图谱与数据,通过吊罩解体检查发现了故障部位,并对后续此类产品试验过程中的注意事项提出建议.     

填料粒子成型对泡沫铝合金孔结构的影响

在实验的基础上 ,绘制出填料粒子成型时的体积与泡沫铝合金的孔隙率相对应的变化曲线 ,并应用力学的基本原理对泡沫铝合金孔结构的成形机理进行了研究。确定填料粒子成型时的体积变化应在 0 %～ 12 %之间 (此时泡沫铝合金的孔隙率应在 41.6 %～ 47.6 %之间 ) ,才能稳定填料粒子尺寸 ,从而更好地控制泡沫铝合金的孔径尺寸 ,提高成型质量 ,稳定泡沫铝合金的使用性能。     

Cd2+-H2O系羟合配离子配位平衡

根据配位化学热力学平衡原理,绘制了Cd^2＋-H2O系配合离子浓度pc-pH图、镉羟合配离子分率αn-pH图及Cd（OH）2条件溶度积pKS-pH图。pc-pH图描述了Cd（OH）2（s）溶解平衡时,镉的总离子平衡浓度与pH的关系。当pH为9.84～13.31时,Cd（OH）2的溶解度最小;αn-pH图指出了各种羟合配离子分率与pH关系,每种羟合配离子都对应有其存在的最佳pH范围。Cd（OH）2（s）的条件溶度积pKS-pH图表明：当pH值在9.5～10.5范围内,Cd（OH）2（s）的条件溶度积最小。研究结果可为中和水解法去除废水中镉等技术提供理论依据。