Finite-element analysis of hyperelastic thin shells with large strains

The objective of this contribution is the development of theoretical and numerical models applicable to large strain analysis of hyperelastic shells confining particular attention to incompressible materials. The theoretical model is developed on the basis of a quadratic displacement approximation in thickness coordinate by neglecting transverse shear strains. In the case of incompressible materials this leads to a three-parametric theory governed solely by mid-surface displacements. The material incompressiblity is expressed by two equivalent equation sets considered at the element level as subsidiary conditions. For the simulation of nonlinear material behaviour the Mooney-Rivlin model is adopted including neo-Hookean materials as a special case. After transformation of nonlinear relations into incremental formulation doubly curved triangular and quadrilateral elements are developed via the displacement method. Finally, examples are given to demonstrate the ability of these models in dealing with large strain as well as finite rotation shell problems.The present study is supported by a research grant of the German National Science Foundation (DFG) under Ba 969/3-1.dedicated to Prof. Dr. Dr. Erwin Stein for his 65th birthday anniversary     

(+)-CC-1065 as a structural probe of Mu transposase-induced bending of DNA: overcoming limitations of hydroxyl-radical footprinting

Phage Mu transposase (A-protein) is primarily responsible for transposition of the Mu genome. The protein binds to six att sites, three at each end of Mu DNA. At most att sites interaction of a protein monomer with DNA is seen to occur over three minor and two consecutive major grooves and to result in bending up to about 90 degrees. To probe the directionality and locus of these A-protein-induced bends, we have used the antitumor antibiotic (+)-CC-1065 as a structural probe. As a consequence of binding within the minor groove, (+)-CC-1065 is able to alkylate N3 of adenine in a sequence selective manner. This selectivity is partially determined by conformational flexibility of the DNA sequence, and the covalent adduct has a bent DNA structure in which narrowing of the minor groove has occurred. Using this drug in experiments in which either gel retardation or DNA strand breakage are used to monitor the stability of the A-protein--DNA complex or the (+)-CC-1065 alkylation sites on DNA (att site L3), we have demonstrated that of the three minor grooves implicated in the interaction with A-protein, the peripheral two are 'open' or accessible to drug bonding following protein binding. These drug-bonding sites very likely represent binding at at least two A-protein-induced bending sites. Significantly, the locus of bending at these sites is spaced approximately two helical turns apart, and the bending is proposed to occur by narrowing of the minor groove of DNA. The intervening minor groove between these two peripheral sites is protected from (+)-CC-1065 alkylation. The results are discussed in reference to a proposed model for overall DNA bending in the A-protein att L3 site complex. This study illustrates the utility of (+)-CC-1065 as a probe for protein-induced bending of DNA, as well as for interactions of minor groove DNA bending proteins with DNA which may be masked in hydroxyl radical footprinting experiments.     

载体及反应条件对Pt/BaKL沸石催化剂芳构化性能的影响

研究了γ-Al_2O_3或SiO_2载体,以及反应条件对Pt/BaKL沸石催化剂芳构化性能的影响。发现经过碱化或负载Sn的γ-Al_2O_3作为载体,能够较好地保持该催化剂在正己烷芳构化反应中的高活性和高选择性,并有益于改善Pt/BaKL沸石催化剂的抗硫性能。     

PbO－Bi_2O_3－B_2O_3－SiO_2系重金属氧化物玻璃的结构与光学性

通过密度、可见光光谱、红外吸收光谱、Ｃｏ－６０辐照损伤试验及荧光光谱的测试，研究了ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３－ＳｉＯ２玻璃系的光学性能与结构．密度最高可达８．４６４ｇ／ｃｍ３其紫外吸收达截止波长随Ｐｂ２＋及Ｂｉ３＋含量升高而红移．玻璃熔化温度低达８５０℃．在ＰｂＯ－Ｂｉ２Ｏ３－Ｂ２Ｏ３系玻璃中加人ＳｉＯ２可使玻璃结构更致密．室温下该系统玻璃在３６０ｎｍ有一个宽的激发峰，能产生４１８ｕｍ及４３８ｕｍ两个弱的发射峰．该系统玻璃的结构是由［ＳｉＯ４］４－、［ＢＯ３］３－、［ＢＯ４］５－、［ＰｂＯ４］６－及［ＢｉＯ６］９－构成．其中部分Ｐｂ２＋及Ｂｉ３＋以网络外体进入玻璃．     

MIM隧道结的电子输运特性和发光研究

论述作为一种新型发光器件的ＭＩＭ隧道结的发光机理，报告了该器件的发光现象和Ｉ－Ｖ特性曲线中负阻现象的实验观察。数据显示，结中表面等离极化激元（ＳＰＰ）与粗糙度的耦合是引起光发射的主要方面，ＳＰＰ对隧穿电子的阻塞作用导致了电子输运中的负阻现象。此外，还观察到了直接辐射的紫外峰。     

正交试验法于优选白瓷坯料配方中的应用

对长石、石英、龙岩土、莱阳土４种因素各取４个水平，用正交表Ｌ１６（４５）安排１６个试验，分析了这１６个试验产品的吸水率、白度、热稳定性与每种因素各水平之间的关系．得出了白瓷坯料的最佳配方。其中，长石１９，石英２１，龙岩土２１．莱阳土０．     

Experimental studies of new ductile coupling beams and multi-storey shear walls

The span-depth ratios of coupling beams to interconnect shear walls are generally small, so that brittle shear failure may occur and lead to reduced ductility. In order to improve the ductility of coupling beams for earthquake loading, a new type of ductile coupling beam is proposed in this paper. Along the middle depth of this beam, a slit through the entire thickness (a narrow hole) near each end and two lateral keyways along the remaining middle part of the span are made. The reductions of the stiffness under service load and the ultimate carrying capacity of the beam due to the weakening mentioned above are small and the ductility is greatly increased. Tests of 4-storey walls interconnected by coupling beams in three different constructions (monolithic beams, beams with a through-slit and new-type beams) indicated that shear walls with the new coupling beams possess the best aseismic behaviours under cyclic loading. The proposed new coupling beam has been used in a high-rise building.     

正庚烷-甲苯-三甘醇三元体系液-液相平衡数据的测定与关联

利用气相色谱法测定了常压下２５℃、４０℃和５０℃时正庚烷－甲苯－三甘醇体系的液－液相平衡数据，采用峰面积归一化法定量，所得数据准确、可靠。用ＮＲＴＬ模型对所测数据进行了热力学关联，求出了相应的模型参数。用该模型对本三元体系进行了预测，结果令人满意。     

过滤技术在煤炭工业中的应用

一．前言 我国现有的洗煤厂，绝大部分都是采用湿法（以水或重悬浮液作为分选介质）选煤技术进行煤炭的分选。产品脱水就成为洗煤生产中的一个突出问题，对于洗煤厂来说，产品脱水也是一项保证产品质量，节约用水，节约运力，节省动力和减少污染的至关重要的工作。