Preparation and characterization of cyclodextrin microencapsulated ammonium polyphosphate and its application in flame retardant polypropylene

A novel microencapsulated ammonium polyphosphate (MAPP) with shell of crosslinked β-cyclodextrin (HDI-CD) was prepared. The HDI-CD shell had a fibrous structure and covered with good completeness on the APP core, and a solid chemical bonding was found between the APP core and HDI-CD shell. The microcapsules were more hydrophobic than the pristine APP. When compounded within polypropylene (PP), the MAPP exhibited good compatibility and dispersibility. The combustion testing results showed that the novel all-in-one intumescent flame retardant had efficient flame retardancy for PP materials.     

热处理对铝-钢爆炸复合板交界区的影响

研究了铝-钢爆炸复合板交界区经热处理(300℃,350℃,400℃,450℃)×20min后的组织和性能.结果表明,爆炸状态下,Fe-Cu-Al界面发生合金元素的扩散,形成了合金元素的成分过渡区.其中,Cu-Al交界处的扩散较为明显,合金元素扩散的距离较长,Al元素的扩散能力较强,但未见析出物.450℃×20 min热处理后,Cu-Al交界区有明显的析出物;爆炸使Cu-Al界面产生了明显的硬化效应,随着热处理温度的提高,硬度峰值增加,350℃后的热处理,硬度峰值变化不明显;爆炸状态下,Cu-Al界面的剪切强度满足了使用性能的要求.     

基于液相掺杂的低损耗近等厚芯层掺稀土光纤

过高的纤芯损耗和纤芯折射率非均匀性严重制约了掺稀土光纤在高功率光纤激光器中的应用,提出一种基于液相掺杂的低损耗近等厚芯层掺稀土光纤的工艺方法.结合改良的化学气相沉积(MCVD)溶液掺杂法制备了含有多层疏松层的掺稀土光纤预制棒,理论分析了光纤预制棒缩棒前、后芯层差的变化原理,采用流量递减沉积工艺降低了缩棒后不同芯层之间的...     

镁合金板材挤压工艺的有限元模拟

采用有限元模拟方法对AZ31B镁合金板材挤压过程中的应力场、应变场和挤压力随工艺参数的变化规律进行研究.所研究的挤压工艺参数包括:挤压温度、挤压比和挤压速度等。结果表明:随着坯料挤压温度的升高,最大等效应变值从17. 6逐渐增大至26. 4;最大等效应力值由133. 2 MPa减小至43. 4 MPa;挤压温度高于350℃后,挤压力变化不大.随着挤压比的增加,挤压力由7. 328 MN增大至8. 808 MN;最大等效应变值先减小后增大;最大等效应力值由87 MPa增加至119 MPa.随着挤压速度的增加,挤压力从2. 14 MN增加至3. 42 MN;最大等效应变值先增大后减小;最大等效应力值由72. 3 MPa逐渐增大至104. 2MPa.     

不通气的沸腾汽-液-固三相搅拌槽中的汽液分散和固体悬浮

在直径为0.476 m的椭圆底搅拌槽中,采用直径为0.238 m的单层六叶深凹叶盘式涡轮桨(HEDT),在液位为0.5 m的全挡板条件下研究了沸腾状态下,蒸汽、去离子水和玻璃珠组成的汽-液-固体系中搅拌功率、气含率及固体颗粒完全离底悬浮特性,并与常温通空气三相体系进行对比.研究结果表明,沸腾条件下的流体动力学性能与常温通气体系相比存在较大差异.在沸腾条件下,搅拌功率消耗随着搅拌转速的增加有所下降,但HEDT桨具有较高的载气能力,即使在高叶端线速度下,相对功率消耗(RPD)仍能保持在较高的水平;沸腾体系的气含率随单位质量流体输入功率的增加表现出先增后减的规律,即存在气含率的极大值,蒸汽成核位置和固体颗粒悬浮特性随搅拌功率增加而改变是造成上述行为的主要原因;沸腾体系中的气含率远远低于常温通空气体系.临界悬浮搅拌转速(NJSG)随固相体积分率的增加略有增加;沸腾体系中蒸汽量的变化对NJSG影响远小于常温通气体系.研究结果对于工业沸腾态三相搅拌反应器的设计和操作具有一定的参考价值.     

污染土壤/底泥电动修复研究进展

修复污染土壤/底泥对改善生态环境质量极为重要,通过对污染土壤/底泥施加电场,可使污染物定向迁移、富集并去除.综述了电动修复的发展历程,比较了重金属、有机污染物及复合污染物的电动修复机理及其限制因素,分析了土壤预处理(加入酸、氧化剂、共溶剂、表面活性剂,搅拌,升温等)、电极优化(交换电极、阳极逼近、电极矩阵等)、多技术(...     

现场仪表质量管理

针对仪表质量管理的薄弱环节和盲区,确定持续改进对策。仪表以最低成本、高质量、更高效益的工作,为产品质量上档次提供了必要的保证。     

A Novel Family of Winged-Helix Single-Stranded DNA-Binding Proteins from Archaea

The winged helix superfamily comprises a large number of structurally related nucleic acid-binding proteins. While these proteins are often shown to bind dsDNA, few are known to bind ssDNA. Here, we report the identification and characterization of Sul7s, a novel winged-helix single-stranded DNA binding protein family highly conserved in Sulfolobaceae. Sul7s from Sulfolobus islandicus binds ssDNA with an affinity approximately 15-fold higher than that for dsDNA in vitro. It prefers binding oligo(dT)₃₀ over oligo(dC)₃₀ or a dG-rich 30-nt oligonucleotide, and barely binds oligo(dA)₃₀. Further, binding by Sul7s inhibits DNA strand annealing, but shows little effect on the melting temperature of DNA duplexes. The solution structure of Sul7s determined by NMR shows a winged helix-turn-helix fold, consisting of three α-helices, three β-strands, and two short wings. It interacts with ssDNA via a large positively charged binding surface, presumably resulting in ssDNA deformation. Our results shed significant light on not only non-OB fold single-stranded DNA binding proteins in Archaea, but also the divergence of the winged-helix proteins in both function and structure during evolution.     

微乳液体系制备Fe2B包覆纳米α-Fe及其性能研究

采用油包水(W/O)的微乳液体系制备纳米α-Fe.XRD、TEM分析表明,纳米α-Fe被Fe2B所包覆,其粒度在20～100 nm;激光粒度分析表明,纳米α-Fe存在团聚现象,但粒度分布窄;TG-DSC分析表明,纳米α-Fe在＞1100K时发生吸热的α-γ相变;磁强计检测表明,粉体具有铁磁性,其饱和磁化强度为1.14emu/g,剩余磁化强度为0.08emu/g,矫顽力为280Oe.