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Xiaohui Lin Long Chen Chenglin He Yiliu Wang Xu Li Weiqi Dang Kun He Ying Huangfu Dan Wu Bei Zhao Bo Li Jia Li Xidong Duan 《Advanced functional materials》2023,33(1):2210278
Single crystal metal halide perovskites thin films are considered to be a promising optical, optoelectronic materials with extraordinary performance due to their low defect densities. However, it is still difficult to achieve large-scale perovskite single-crystal thin films (SCTFs) with tunable bandgap by vapor-phase deposition method. Herein, the synthesis of CsPbCl3(1–x)Br3x SCTFs with centimeter size (1 cm × 1 cm) via vapor-phase deposition is reported. The Br composition of CsPbCl3(1–x)Br3x SCTFs can be gradually tuned from x = 0 to x = 1, leading the corresponding bandgap to change from 2.29 to 2.91 eV. Additionally, an low-threshold (≈23.9 µJ cm−2) amplified spontaneous emission is achieved based on CsPbCl3(1–x)Br3x SCTFs at room temperature, and the wavelength is tuned from 432 to 547 nm by varying the Cl/Br ratio. Importantly, the high-quality CsPbCl3(1–x)Br3x SCTFs are ideal optical gain medium with high gain up to 1369.8 ± 101.2 cm−1. This study not only provides a versatile method to fabricate high quality CsPbCl3(1–x)Br3x SCTFs with different Cl/Br ratio, but also paves the way for further research of color-tunable perovskite lasing. 相似文献
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Ben-Xin Wang Chongyang Xu Guiyuan Duan Wei Xu Fuwei Pi 《Advanced functional materials》2023,33(14):2213818
Metamaterial absorbers have been widely studied and continuously concerned owing to their excellent resonance features of ultra-thin thickness, light-weight, and high absorbance. Their applications, however, are typically restricted by the intrinsic dispersion of materials and strong resonant features of patterned arrays (mainly referring to narrow absorption bandwidth). It is, therefore essential to reassert the principles of building broadband metamaterial absorbers (BMAs). Herein, the research progress of BMAs from principles, design strategies, tunable properties to functional applications are comprehensively and deeply summarized. Physical principles behind broadband absorption are briefly discussed, typical design strategies in realizing broadband absorption are further emphasized, such as top-down lithography, bottom-up self-assembly, and emerging 3D printing technology. Diversified active components choices, including optical response, temperature response, electrical response, magnetic response, mechanical response, and multi-parameter responses, are reviewed in achieving dynamically tuned broadband absorption. Following this, the achievements of various interdisciplinary applications for BMAs in energy-harvesting, photodetectors, radar-IR dual stealth, bolometers, noise absorbing, imaging, and fabric wearable are summarized. Finally, the challenges and perspectives for future development of BMAs are discussed. 相似文献
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在离子束抛光工艺中,为了提高驻留时间求解算法在工件边缘处的求解精度,需要对原始面形误差数据进行有界光滑延展。推导并提出了一种基于高斯曲线的曲面延展算法,该算法利用了高斯函数的有界性、光滑性和参数连续性。将该曲面延展算法应用于带有高频噪声的面形误差工件的驻留时间求解过程中,驻留时间算法在光学元件边缘处的残余误差得到了抑制,使得驻留时间算法在整个通光口径内的收敛率达到了97%(RMS)。这表明基于高斯曲线的曲面光滑延展算法能实现光学元件面形误差的光滑延展,并具有良好的抗噪声干扰能力,改善了驻留时间算法的求解精度。 相似文献
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In order to prevent and eliminate the asphaltene precipitation during gas flooding, the rules of the changes of the pressure under different conditions are systematically studied by the laser solid detection system, the light transmission method, and the P–T phase diagram when the asphaltene precipitation occurs. When the pressure is reducing to a certain value, the penetrating light intensity of the crude oil is markedly decreased, which shows that the pressure at this point is the pressure of the onset of asphaltene precipitation (AOPP). The AOPP value decreases with an increase in the temperature. During gas flooding, the AOPP value increases with an increase in the content of gas in the crude oil, and these two nearly do have a linear relationship. According to the P–T phase behaviors of the gas–crude oil system, with an increase in the content of gas in the crude oil, the asphaltene precipitation envelope curve (APE) is gradually moved up, which shows that the possibility of asphaltene precipitation is much higher. During oil production, for the oil reservoirs with rich asphaltene, the production pressure drop should be kept a small value to ensure that the flowing bottom-hole pressure is higher than AOPP and it is necessary to help complement producing energy timely by using water injection, gas injection, etc. Besides, according to the intersection of T–P curve and APE curve in the P–T phase diagram, the location where the asphaltene precipitation occurs in the wellbore can be roughly predicted. The experimental results can provide the theoretical foundation for taking measures to prevent and eliminate the asphaltene precipitation. 相似文献
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二叠系是叶城_和田凹陷最为重要的烃源岩层系之一。通过和田凹陷杜瓦地区野外露头剖面及最新钻井分析,并结合有机地球化学测试数据,对二叠系普司格组烃源岩沉积特征、古环境及有机地球化学特征进行研究。结果表明:普司格组烃源岩发育在滨湖、浅湖及半深湖亚相中,乌鲁吾斯塘地区和杜瓦地区为烃源岩沉降中心,以低Pr/Ph值、较高伽马蜡烷指数等为特征,表现出较强还原性、较高盐度下具有一定水体分层的湖相沉积产物。普司格组烃源岩有机碳(TOC)值为0.12%~5.68%,为“差-中等”烃源岩,有机质类型以Ⅱ型、Ⅲ型为主,镜质体反射率RO值为0.72%~1.385%,主体已进入成熟-高成熟阶段。结合地震资料、生储盖条件分析认为,杜瓦地区普司格组烃源岩生烃潜力较好,逆冲推覆体为油气勘探的可能有利区域,准原地质体为塔西南坳陷山前带最为有利的油气勘探区域,原地质体埋深很大,是目前勘探工作面临的主要挑战之一。 相似文献