Preparation of Lead Zirconate by Homogeneous Precipitation and Calcination

Antiferroelectric PbZrO₃ has been synthesized by homogeneous precipitation from aqueous solutions in the presence of urea (NH₂CONH₂) and calcination for 6 h at 700°C. SEM studies displayed the presence of submicrometer powder, with a significant degree of agglomeration.     

A Benchmark for Some Physical Properties of Zinc-Blende ZnS

Somephysical properties of zinc-blende polytype of ZnS were investigated via geometry optimization calculations. After employing a shell model interatomic potential to our computations, some physical parameters such as typical cubic elastic constants, young modulus, shear modulus, bulk modulus, poisson ratio, elastic wave velocities, static and high frequency dielectric constants, and static refractive index zinc-blende ZnS were deduced. Later, previous theoretical results and our current results with each other as well as with former experimental findings were evaluated. Present results exhibit a fair consistency with experiments and better than those of several recent density functional theory results for the considered parameters of related material.     

Optimal regulation of homogeneous systems

We present an offline numerical algorithm to generate a discontinuous feedback law to robustly regulate the origin of a continuous-time homogeneous system through sample and hold. The proposed feedback comes out of the solution of an infinite horizon optimization problem in discrete time and is in the form of a look-up table. We show that when applied to either chained systems or systems in power form the algorithm results in a closed loop whose origin is globally exponentially stable.     

Stochastic Priority Model for Aggregate Blending

Aggregate blending models that incorporate the optimization of two objectives with their priority levels are presented. The two objectives include the minimization of the mean deviation (or mean absolute deviation) from the midpoint of specification limits and the minimization of the unit cost of the blend. The models are applicable to any number of aggregates and can be used to provide the optimum proportions corresponding to a given priority level or to establish trade‐off curves between mean deviation and cost. The stochastic elements of aggregate gradations are formulated and incorporated into the models. Both the deterministic and stochastic models are applied to a numerical aggregate blending problem, and extensions of the models to accommodate some practical cases are presented.     

Application of the prins reaction on oleic acid

The probable structure of the various components of oleic acid-formaldehyde adducts is discussed. The adducts are reduced to alcohols by high pressure hydrogenation with copper chromite as a catalyst. The new alcohols are distilled, analyzed and used for the preparation of various esters with carboxylic acids. The esters were evaluated as low temperature lubricant base stocks and low temperature plasticizers.     

A comparison of the functional characteristics of wheat stored as grain with wheat stored in spike form

In this study, wheat grain and wheat spike with 12%, 14% and 16% moisture content were stored at 10, 20 and 30 °C for 0, 3, 6 and 9 months. After storage, wheat samples were investigated for hectolitre weight, gluten content, Zeleny sedimentation volume, enzyme activity, acidity, phytic acid and L colour value. Storage of wheat at different storage forms (spike and grain) and storage conditions showed considerable changes in grain quality. In general, the storage period of 3 months positively affected wheat quality. However, hectolitre weight, gluten, Zeleny sedimentation, enzyme activity, acidity and colour of wheat got worse at storage periods beyond 3 months. Hectolitre weight, wet and dry gluten, Zeleny sedimentation, phytic acid content and L Colour value of wheat stored in both spike and grain form significantly decreased during storage. However, the increase in grain moisture content, storage time and temperature resulted in significant increase in total titratable acidity and falling number values of wheat. Falling Number and phytic acid values of wheat stored in spike form were generally lower than wheat stored in grain form. Storage in spike form had a positive effect on especially wet gluten content of wheat stored at non-optimal storage conditions such as high grain moisture content and high temperature. Wet gluten of wheat stored in spike form was higher than that of wheat stored grain form after storage at 30 °C for 6 and 9 months. Wheat stored in spike form is more resistant than wheat stored in grain form against adverse storage conditions such as high moisture content and temperature and longer storage time.     

Pb(II) biosorption using anaerobically digested sludge

Removal of Pb(II) by using resting cells of anaerobically digested sludge (ADS) obtained from a nearby wastewater treatment plant was examined. Firstly, sorption kinetic and equilibrium experiments were conducted using agitated, thermostated (25 degrees C) batch reactors. The maximum Pb(II) sorption capacity was found to be very high (1,750 mg/g dry ADS or 8.45 mmol/g dry ADS). At all initial Pb(II) concentrations tested, sorption resulted in neutralization with an increase in the solution pH from an initial value of 4.0-5.5 to an equilibrium value of 7.0-8.0, at which Pb(II) can precipitate as hydroxide. The removal of Pb(II) by ADS was found to involve bioprecipitation as well as biosorption. FTIR spectrometry highlighted carboxyl groups present on the surface of ADS as the major functional groups responsible for biosorption. Secondly, a three-stage semi-continuous pseudo-counter current reactor system was tested to reduce ADS requirement in comparison to a conventional single-stage batch reactor. At an initial Pb(II) concentration of about 200 mg/L, an effluent Pb(II) concentration of 1.3 mg/L was achieved in the three stage reactor, corresponding to a metal removal capacity of 682.7 mg/g dry ADS (3.30 mmol/g), in comparison to 1.9 mg/L and 644.0 mg/g dry ADS (3.10 mmol/g) for the single-stage batch reactor.     

Microbiological,chemical and sensory assessment of mussels (<Emphasis Type="Italic">Mytilus galloprovincialis</Emphasis>) stored under modified atmosphere packaging

Wild mussels (Mytilus galloprovincialis), were packaged aerobically under vaccum packaging(VP) and modified atmosphere packaging (MAP (50%/50% CO₂/N₂: M1, 80%/20% CO₂/N₂: M2, 65%/35% CO₂/N₂: M3), and stored at 2 ± 1 °C. Quality evaluation was carried out using microbiological, chemical and sensory analyses. Microbiological results revealed that M2 and M3 delayed microbial growth compared to M1. Of the chemical indices determined, the TVB-N and TMA-N values of M2 remained lower than the proposed acceptability limits of 35 mg N/100 g and 8 mg N/100 g, respectively, up to 8 days of storage. All of the MAP and VP mussel samples exceeded these limits after 12 days of storage. All samples retained desirable sensory characteristics during the first 8 days of storage. Based on microbiological and chemical analyses along with sensory evaluation, M2 and M3 gave a longer shelf-life compared with VP and M1. M2 gas mixture was the most effective for mussel preservation.