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111.
The quasiparticle density of states is calculated in the vortex state of an orthorhombic d-wave superconductor as a function of the orientation of the external magnetic field (H ) in the CuO 2 -plane. Because of the existence of chains oriented along the y-axis in YBCO, its in-plane properties are highly anisotropic and in the superconducting state a predominantly order parameter will also contain a subdominant s-wave admixture allowed by the orthorhombic crystal space group. In a simple anisotropic effective mass model for the band structure and a d + s gap we compute the quasiparticle density of states as a function of the orientation () of H with respect to the a-axis in the CuO 2 plane. As a function of we find a two fold pattern of behavior with minima at the angles where the Fermi velocity at the nodal momentum is in the direction of the external field. For an untwinned single crystal the resulting anisotropy of the specific heat at low temperatures should be measurable. It is greatly reduced in twinned samples  相似文献   
112.
A study of the influence of the local environment on the light-induced luminescence enhancement of CdSe/ZnS quantum dots (QD) embedded in silica colloids that are dispersed in various solvents is presented. The photoluminescence of the embedded QD is enhanced up to a factor of ten upon photoactivation by ultraviolet or visible light. This enhancement is strongly dependent on the local environment. The thickness-dependent permeability of the silica shell covering the QD controls the influence of the solvent on the QD. If foreign ions are present the activation state is stabilized after termination of the activation, whereas in their absence the process is partially reversible. A new qualitative model for the photoactivation of QD in various environments is developed. It comprises light-induced passivation and subsequent oxidation processes. The embedded QD also retain their fluorescence quantum yield inside living cells. Moreover, they can be activated for many hours in living cells by laser radiation in the visible regime.  相似文献   
113.
Decomposition (“plateau”) pressures of H2, D2, and T2 over Li-LiH, Li-LiD, and Li-LiT alloys were determined between 600 and 850°C, for pressures ranging from 3 to 460 Torr, and for alloy compositions falling within the (α + β) miscibility gaps. The measurements were carried out separately for each hydrogen isotope using the same lithium sample and experimental procedures. For each system the ln P vs. 1/T data form a pair of linear segments, the intersection of which represents the monotectic temperature (694°C for Li-LiH, 690°C for Li-LiD, and 688°C for Li-LiT). For a given temperature plateau pressures were in the order PT2 >PD2 >PH2. The DH and TH isotope effects in pressures varied from 1.48 and 1.74 at 600°C to 1.34 and 1.45 at 850°C. The results were used to calculate the standard free energies of formation of solid LiH, LiD, and LiT. The tritium gas used in this study had significant amounts of hydrogen and deuterium. A method for correcting the plateau pressures of this mixture to those of pure tritium is presented.  相似文献   
114.
115.
In this study we present a solution method for the compressible Navier-Stokes equations as well as the Reynolds-averaged Navier-Stokes equations (RANS) based on a discontinuous Galerkin (DG) space discretisation. For the turbulent computations we use the standard Wilcox k-ω or the Spalart-Allmaras model in order to close the RANS system. We currently apply either a local discontinuous Galerkin (LDG) or one of the Bassi-Rebay formulations (BR2) for the discretisation of second-order viscous terms. Both approaches (LDG and BR2) can be advanced explicitly as well as implicitly in time by classical integration methods. The boundary is approximated in a continously differentiable fashion by curved elements not to spoil the high-order of accuracy in the interior of the flow field.Computations are performed for the circular cylinder, the flat plate and classical airfoil sections like NACA0012. We compare our obtained results with experimental and computational data as well as analytical (boundary layer) predictions for the flat plate. The excellent parallelisation characteristics of the scheme are demonstrated, achieved by hiding communication latency behind computation.  相似文献   
116.
T cell therapies require the removal and culture of T cells ex vivo to expand several thousand‐fold. However, these cells often lose the phenotype and cytotoxic functionality for mediating effective therapeutic responses. The extracellular matrix (ECM) has been used to preserve and augment cell phenotype; however, it has not been applied to cellular immunotherapies. Here, a hyaluronic acid (HA)‐based hydrogel is engineered to present the two stimulatory signals required for T‐cell activation—termed an artificial T‐cell stimulating matrix (aTM). It is found that biophysical properties of the aTM—stimulatory ligand density, stiffness, and ECM proteins—potentiate T cell signaling and skew phenotype of both murine and human T cells. Importantly, the combination of the ECM environment and mechanically sensitive TCR signaling from the aTM results in a rapid and robust expansion of rare, antigen‐specific CD8+ T cells. Adoptive transfer of these tumor‐specific cells significantly suppresses tumor growth and improves animal survival compared with T cells stimulated by traditional methods. Beyond immediate immunotherapeutic applications, demonstrating the environment influences the cellular therapeutic product delineates the importance of the ECM and provides a case study of how to engineer ECM‐mimetic materials for therapeutic immune stimulation in the future.  相似文献   
117.
Handling of various oil-bearing materials and special problems of loading, cleaning, drying, and storage are discussed, along with considerations for preventing quality deterioration during storage.  相似文献   
118.
W. B. Lyons  H. Ewald  C. Flanagan  E. Lewis   《Measurement》2003,34(4):301-312
Preliminary results are presented for a multi-point optical fibre sensor designed to detect the presence of chemical species in water at spatial intervals of greater than 20 m. The sensor is addressed using optical time domain reflectometry (OTDR) with a spatial resolution of 10 m. The optical signals arising from the OTDR are highly complex due to interfering effects from external parameters such as localised fibre straining and temperature changes. Because of this level of complexity it has been found advantageous to use artificial neural networks (ANNs) as classifiers on the OTDR signals. The preliminary system has been trained initially to recognise only the presence of water, although it is planned to extend this capability to recognise the presence of contaminants in the water such as bacteria and chemical pollutants. Initial investigations show that different contaminants and interfering parameters (cross-sensitivities) may give rise to characteristic signatures on the OTDR signal which may be identified by the pattern recognition software.  相似文献   
119.
2000年10月1日EG2037/2000开始生效,届时1994年12月15日颁布的EG3093/94失效。新规定基本上是根据1995年“蒙特利尔议定书”缔约国会议,并在欧洲范围内已经承担的义务上进行修订的,同时还引入了一个许可体系,该体系不仅仅是引入,而且要消除破坏臭氧层物质材料。1 法规的适用范围 在条款1中,对法规的适用范围作了简要说明,包括:生产、进口和出口、使用、回收、再生加工、处理和消毁,以及对破坏臭氧层的CFC、HCFC和该物质的衍生物的规定。该法规条款、章节内容的说明主要集中在制冷技术方面。 新的欧盟法规针对CFC和HCFC主…  相似文献   
120.
Investigations on the Ultimate Strength of Damaged Post‐Tensioned Tendons In order to assess the influence of bond action between strands, injection grout and surrounding concrete on the ultimate strength of damaged post‐tensioning tendons more accurately, a series of tensile tests on tendons which were built using post‐tensioning strands and wires from demolished bridges were carried out. Wire and strand breakage was included in the tendons at specified patterns. Furthermore, the influence of the quality of the injection grout on the load carrying‐capacity of the tendon was studied. The results of the test series show that tendons with damaged or broken wires or strands are able to carry a high percentage of the ultimate load of an undamaged tendon.  相似文献   
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