2A12铝合金化学铣切加工工艺探讨

为了精确加工2Al2铝合金,探讨了化铣时间和温度对其化铣速率及表面粗糙度的影响,采用现代技术对化铣工件的力学性能进行了测试与分析.结果表明:延长非化铣部位保护胶固化时间并使保护部位向非加工面位移3～5 mm可很好地解决未化铣区域的腐蚀问题;随化铣时间的延长,化铣速率降低,且化铣温度与化铣速率呈现正相关性;化铣表面的粗糙度随化铣时间的延长而增加,随化铣温度的升高呈先减小后增加的趋势;化铣后材料的抗拉强度和屈服强度均有所提高.     

A dense and compact laser cladding layer with solid metallurgical bonding significantly improved corrosion resistance of Mg alloy for engineering applications

Although Mg alloy attracts great attention for engineering applications because of high specific strength and low density, low corrosion resistance limits its extensive use. In this study, Mg–Al–Zn–Mn alloy was treated via a laser cladding process to generate a dense and compact laser cladding layer with solid metallurgical bonding on the substrate for improving corrosion resistance, effectively hindering the corrosion pervasion into Mg alloy. The corrosion current density declined from 103 μA/cm² for Mg alloy to 13 μA/cm² for the laser cladding layer in NaCl aqueous solution. Moreover, the laser cladding layer was slightly corroded in comparison with Mg alloy in NaCl aqueous solution. Besides, the microhardness of the cladding layer reached a mean value of 170.5 HV, 3.1 times of Mg alloy (56.8 HV) due to the in situ formation of hardening intermetallic phases. Wear resistance of laser cladding layer was also obviously improved. These results demonstrated that the laser cladding layer obviously enhanced anticorrosion property of Mg alloy for engineering applications.     

Improving storability,physiological disorders,and antioxidant properties of ‘Bartlett’ and ‘d’Anjou’ pears (Pyrus communis L.) by pre-harvest 1-methylcyclopropene spraying

Ethylene continues to be a major factor influencing quality of European pears during storage. Although research has been done on the effect of pre-harvest 1-methylcyclopropene (1-MCP) on physiological characteristics in pears, a full understanding of cultivar response and antioxidant metabolism remains elusive. Spraying 1-MCP on ‘Bartlett’ and ‘d’Anjou’ pears was studied with respect to physiology, storage and eating quality, disorders, and antioxidant properties at two harvest date (H1 and H2) during storage and ripening. Treatment with 1-MCP extended the harvest window of ‘Bartlett’ and ‘d’Anjou’ pears 3 and 4 days, respectively, without reducing storage or eating quality. Treatment with 1-MCP reduced ethylene production (EPR) and respiration rates (RR), maintained fruit firmness and green colour during storage and retarded development of desirable melting texture in both cultivars. Additionally, 1-MCP lowered the incidence of disorders by alleviating membrane lipid peroxidation, retaining high total flavonoids (TF) and antioxidant capacity, and enhancing superoxide dismutase (SOD), catalase (CAT) and ascorbate peroxidase (APX) activity in both cultivars. Overall, pre-harvest 1-MCP applications could extend storage time of ‘Bartlett’ and ‘d’Anjou’ pears to 5 and 6 months, respectively, at −1.1 ± 0.5 °C, by reducing ethylene synthesis and enhancing antioxidant metabolism.     

Reoptimization framework and policy analysis for maritime inventory routing under uncertainty

We study a maritime inventory routing problem, in which shipments between production and consumption nodes are carried out by a fleet of vessels. The vessels have specific capacities and can be chartered under different agreements. The inventory levels of all consumption nodes and some production nodes should be maintained within specified bounds; for the remaining production nodes, orders should be picked up within pre-defined time windows. We propose a discrete-time mixed-integer programming model. In the face of new information and uncertainty, this optimization model has to be re-solved, as the horizon is rolled forward. We discuss how to account for different sources of uncertainty. We present a rolling-horizon reoptimization framework that allows us to study different policies that impact the quality of the implemented solution, so we can identify the optimal set of policies.     

脱硫活性焦水洗再生过程实验研究

对5种活性焦水洗再生前后的脱硫性能进行实验研究，通过比表面积（BET）、X射线光电子能谱（XPS）方法表征水洗再生工艺对活性焦孔隙结构和表面化学性质的影响，揭示影响活性焦水洗再生性能的关键因素。结果表明:活性焦脱硫硫容的大小和水洗再生率的高低没有直接关系；微孔比表面积较大的活性焦脱硫性能较好，中大孔孔容较大的活性焦水洗再生率较高，同时具备较大的微孔比表面积和中大孔孔容结构的活性焦适宜水洗再生工艺；活性焦表面极性含氧官能团含量越高水洗再生效果越好；活性焦AC5经过6次水洗再生循环，微孔中的硫酸经过多次累积后可以被水洗出，稳定再生率保持在45%~50%，最适用于活性焦水洗再生工艺。     

High-Tg porous polyimide films with low dielectric constant derived from spiro-(adamantane-2,9′(2′,7′-diamino)-fluorene)

Porous polyimide (PI) films with low dielectric constants and excellent thermal properties have been a pressing demand for the next generation of high-performance, miniature, and ultrathin microelectronic devices. A series of novel porous PI films containing fluorenyl-adamantane groups were prepared successfully via thermolysis of poly(ethylene glycol) (PEG) added in the PI matrix. The cross-sectional morphologies of porous PI films showed closed pores with diameters ranging from 135 to 158 nm, which were uniform and regular in shape without interconnectivity. These porous PI films exhibited excellent thermal properties with a glass-transition temperature at 376 °C whereas the 5% weight loss temperature in air excess of 405 °C due to enhanced rigidity afforded by fluorenyl-adamantane groups. Accompanied by thermolysis content of PEG increasing from 0 to 20 wt %, the density of porous PI films decreased, and the corresponding porosity grew significantly from 0 to 11.48%. Depending on porosity, the dielectric constant and dielectric loss of porous PI films significantly declined from 2.89 to 2.37 and from 0.050 to 0.021, respectively. These excellent properties benefit the as-prepared porous PI films for application as interlayer dielectrics, integrated circuit chips, or multichip modules in microelectronic fields. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47313.     

Small‐Sized High‐Power PIN Diode Switch with Defected Ground Structure for Wireless Broadband Internet

This letter presents a small‐sized, high‐power single‐pole double‐throw (SPDT) switch with defected ground structure (DGS) for wireless broadband Internet application. To reduce the circuit size by using a slow‐wave characteristic, the DGS is used for the quarter‐wave (°/4) transmission line of the switch. To secure a high degree of isolation, the switch with DGS is composed of shunt‐connected PIN diodes. It shows an insertion loss of 0.8 dB, an isolation of 50 dB or more, and power capability of at least 50 W at 2.3 GHz. The switch shows very similar performance to the conventional shunt‐type switch, but the circuit size is reduced by about 50% simply with the use of DGS patterns.     

大庆长垣以东地区深层天然气输导特征及成藏

大庆长垣以东地区深层天然气输导通道主要由断裂、不整合面和砂体构成。该区砂体横向分布不稳定，物性差，不是天然气侧向长距离运移的输导通道，但可以起到衔接输导作用。输导通道时该区天然气成藏与分布起到了重要控制作用，主要表现在断裂将天然气输导致上覆不同储集层中聚集成藏。不整合面和砂体将天然气输导到四周古隆起上聚集成藏。沿断裂输导的天然气形成以断层为主的构造气藏。沿不整合面和砂体输导的天然气形成以地层及岩性为主的气藏。沿断裂输导运移聚集的天然气在剖面上呈串多层分布，沿不整合面和砂体输导运移聚集的天然气在平面上呈环状分布。     

Study on Hydrocracking of VGO Derived from Kazakhstan-Russian Mixed Crude

1 Introduction With the successful completion of the construction of the China-Kazakhstan oil pipeline the refinery at Dushanzi Pet- rochemical Company will process the Kazakhstan-Russian mixed crude at full steam starting 2007. The high sulfur, nitro- gen and heavy metals contents in the Kazakhstan-Russian mixed crude would have a serious impact on the secondary processing units of the Dushanzi refinery, in particular on the distillate hydrocracking unit, which mainly operates on vacuum g…