Dithiocarbamate as an efficient intermediate for the synthesis of 2-(alkylthio)thiazol-4(5H)-ones

An effective approach for the synthesis of 2-(alkylthio)thiazol-4(5H)-ones from alkyl dithiocarbamates and chloroacetyl chloride in the presence of NaHCO₃ has been developed. Good to excellent yields of products, simple reaction conditions and general applicability are the most important advantages of this protocol.     

A novel ratiometric fluorescent Yb3+ sensor based on a N′-(1-oxoacenaphthylen-2(1H)-ylidene)furan-2-carbohydrazide as a suitable fluorophore

N′-(1-oxoacenaphthylen-2(1H)-ylidene)furan-2-carbohydrazide (L) was synthesized for the first time and used as a ratiometric fluorescent chemosensor for high selective recognition of Yb³⁺ ions in acetonitrile (MeCN) solution. The L–Yb³⁺ complexation quench the fluorescence of L at 420 nm and induces new fluorescent enhancement at 516 nm. Due to the formation of a 2:1 metal ligand complex in acetonitrile solution, the red shift of fluorescent emission spectrum occurred. The sensor shows a linear response toward Yb³⁺ ion concentration in the range of 3.3 × 10^? 7 M to 1.0 × 10^? 4 M with detection limit of 1.2 × 10^? 7 M. The fluorescent probe exhibits high selectivity for Yb³⁺ ion over the other common mono-, di-, and trivalent cations.     

Synthesis and properties of fluorescent light‐emitting polyamide hybrids with reactive nanosilica by epoxide functionalization

A series of poly(carbazole‐quinoxaline‐amide)s (PCQAs) containing phenyl and long alkyl chain as pendants was synthesized from polycondensation between a new diamine with a synthesized and several commercial dicarboxylic acids using Yamazaki's method. PCQAs had inherent viscosities and weight average molecular weights ( ) in the range of 0.48–0.62 dL g^?1 and 51,600–58,500 g mol^?1, respectively. These luminescent polymers are readily soluble in a variety of organic solvents and formed low‐colored and tough thin films. In this study, silane modified SiO₂ (mSiO₂) nanoparticles were prepared, characterized and used with PCQAs in preparation of nanocomposites via solution blending method. The interfacial interaction strength between mSiO₂ and the polymer–matrix enhanced thermal stability (T_10%, from 463°C to 500°C) and mechanical strength (from 100 MPa to 150 MPa) for composite containing 30 wt % mSiO₂ in comparison with the pure polyamide. These materials showed good ability for extraction–elimination of metal ions such as Cr⁶⁺, Cr³⁺, Co²⁺, Zn²⁺, Pb²⁺, Cd²⁺, and Hg²⁺ from aqueous solutions either individually or in the mixture at various pH. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40219.     

MgB2 under pressure and plane strain: a DFT study

Full potential density functional theory (DFT) calculations have been performed for the MgB₂ superconductor. Results show that applying positive (negative) pressure leads to a decrement (increment) in the DOS at the Fermi level that this calculations suggest a decrement in Tc under application of positive pressure. In the Γ-A path of momentum space, the band which has the dominant role in conduction properties, moves upward when c increases or a decreases, and moves downward when c decreases or a increases. By relaxation of the system under the plane strain, we have studied the behavior of axial lattice parameter c. Our results show that changes in the axial lattice constant c is one third of the changes of planar lattice constant a. It has been seen that by applying small in-plane strain (tensile), DOS at the Fermi level increases, but it decreases for higher applied strain. For the negative in-plane strain (compression), DOS decreases monotonically at the Fermi level. It can be seen that tension makes the electronic bands to move downward in the Γ-A direction of the reciprocal lattice, but by compression, they move upward. Based on these results, it can be concluded that by applying small tension, one can enhance Tc in MgB₂ compound.     

Studies on the Dynamics of D–T Fusion Reaction Based on the Relativistic Equilibrium Velocity Distribution

The Coulomb barrier is in general much higher than thermal energy. Nuclear fusion reactions occur only among few protons and nuclei (i.e., deuterium and tritium) with higher relative energies than Coulomb barrier. It is the equilibrium velocity distribution of these high-energy protons and nuclei that participates in determining the rate of nuclear fusion reactions. In the circumstance it is inappropriate to use the Maxwellian velocity distribution for calculating the nuclear fusion reaction rate. We use the relativistic equilibrium has a reduction factor with respect to that based on the Maxwellian distribution, which factor depends on the temperature, reduced mass and atomic numbers of the studied nuclear fusion reactions. In this paper, we concluded at energy range 10⁵ (keV) ≤ E ≤ 10⁶ (keV), that is smaller than reduced mass energy of deuterium–tritium, m _r c ², the numerical values of R and R _M are not different from each other very much, but by increasing energy near the region of m _r c ² the difference between them are visible, also by increasing energy for example 9 × 10⁶ (keV) ≤ E ≤ 10 × 10⁶ (keV) the difference is obviously more visible. Therefore, we have to use relativistic equilibrium velocity distribution instead of Maxwellian velocity distribution.     

Distribution system compensation using a new binary multilevelvoltage source inverter

A new binary multilevel voltage source inverter with separate DC sources is proposed. This n-level voltage source inverter produces a (2 ⁿ⁺¹-1)-steps AC voltage output with n full bridge inverters connected in series. The use of selective harmonic elimination modulation technique to either completely eliminate or minimize harmonics is studied. A closed-loop controller to control the capacitor voltages and adjust the inverter reactive power output is developed. Application of such a compensator for dynamic compensation of 13.8 kV distribution system is examined through transient studies using a PSCAD/EMTDC program. The proposed inverter configuration not only reduces the system complexity and its size, but also improves the harmonic profile significantly     

Critical moisture content for microbial growth in dried food‐processing residues

BACKGROUND: Food‐processing residues are good feedstocks for biofuel and biochemical production because they have high energy content and are abundant. Year‐round biofuel and biochemical production requires proper storage to prevent microbial decomposition and thermal runaway. In this study, microbial activity of tomato pomace (TP), grape pomace (GP), fermented grape pomace (FGP) and sugar beet pulp (SBP) was monitored at nine different moisture contents. RESULTS: Maximum and cumulative respirations for each feedstock with respect to moisture content followed a sigmoidal relationship. The critical moisture content below which no microbial activity was detected for SBP, TP, FGP and GP was 24–31, 16–21, 23–33 and 43–46% (dry basis) respectively. A logarithmic relationship was observed (R² = 0.94) between critical moisture content and initial water‐soluble carbohydrate (WSC) content of the processing residues. CONCLUSION: The critical moisture content below which no microbial activity was detected and the relationship between critical moisture content and initial WSC content were determined in this study for four food‐processing residues. Both parameters permit evaluation of the potential for deterioration of food‐processing residues during storage based on moisture content and WSC content. Copyright © 2010 Society of Chemical Industry     

Minimization of exceptional elements and voids in the cell formation problem using a multi-objective genetic algorithm

Cell formation problem is the main issue in designing cellular manufacturing systems. The most important objective in the cell formation problem is to minimize the number of exceptional elements which helps to reduce the number of intercellular movements. Another important but rarely used objective function is to minimize the number of voids inside of the machine cells. This objective function is considered in order to increase the utilization of the machines. We present a bi-objective mathematical model to simultaneously minimize the number of exceptional elements and the number of voids in the part machine incidence matrix. An ε-constraint method is then applied to solve the model and to generate the efficient solutions. Because of the NP-hardness of the model, the optimal algorithms can not be used in large-scale problems and therefore, we have also developed a bi-objective genetic algorithm. Some numerical examples are considered to illustrate the performance of the model and the effectiveness of the solution algorithms. The results demonstrate that in comparison with the ε-constraint method, the proposed genetic algorithm can obtain efficient solution in a reasonable run time.     

Study of electrospinning of sodium alginate,blended solutions of sodium alginate/poly(vinyl alcohol) and sodium alginate/poly(ethylene oxide)

Alginate is an interesting natural biopolymer for many of its merits and good biological properties. This paper investigates the electrospinning of sodium alginate (NaAlg), NaAlg/PVA‐ and NaAlg/PEO‐ blended systems. It was found in this research that although NaAlg can easily be dissolved in water, the aqueous NaAlg solution could not be electrospun into ultrafine nanofibers. To overcome the poor electrospinnability of NaAlg solution, synthetic polymers such as PEO and PVA solutions were blended with NaAlg solution to improve its spinnability. The SEM images of electrospun nanofibers showed that the alginate (2%, w/v)–PVA (8%, w/v) blended system in the volume ratio of 70 : 30 and the alginate (2%, w/v)–PEO (8% w/v) blended system in the volume ratio of 50 : 50 could be electrospun into finest and uniform nanofibers with average diameters of 118.3 nm (diameter distribution, 75.8–204 nm) and 99.1 nm (diameter distribution, 71–122 nm), respectively. Rheological studies showed a strong dependence of spinnability and fiber morphology on solution viscosity and thus on the alginate‐to‐synthetic polymer (PVA or PEO) blend ratios. FTIR studies indicate that there are the hydrogen bonding interactions due to the ether oxygen of PEO (or the hydroxyl groups of PVA) and the hydroxyl groups of NaAlg. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007