Synthesis of graphene oxide/Ag<Subscript>3</Subscript>PO<Subscript>4</Subscript> composite with enhanced visible-light photocatalytic activity

The nano-scale Ag₃PO₄ was successfully synthesized by the silver ammonia complexing precipitation method at room temperature. And the Graphene oxide (GO)/Ag₃PO₄ nanocomposites with different contents of GO were successfully synthesized using the electrostatic driving method. The as-prepared GO/Ag₃PO₄ nanocomposites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and UV–visible diffuse reflectance spectroscopy (UV–Vis DRS), confirming that Ag₃PO₄ were highly dispersed to GO sheet. The photocatalytic properties of GO/Ag₃PO₄ were evaluated by the degradation of Methyl Orange (MO) under visible light irradiation and solar irradiation respectively. The results showed that the photocatalytic efficiencies of GO/Ag₃PO₄ nanocomposites had enhanced largely and the kinetics reaction models were followed first-order. Furthermore, 5% GO/Ag₃PO₄ exhibited the highest photocatalytic activity on degradation of MO under visible-light irradiation. The improved photocatalytic performances of the GO/Ag₃PO₄ nanocomposites mainly attributed to the introducing of GO, which benefit for electron transfer and inhibit the recombination of electron–hole pairs, promoting the practical application of Ag₃PO₄ in water purification.     

Tribological performance of filled PTFE‐based friction material for ultrasonic motor under different temperature and vacuum degrees

In this work, a glass fiber reinforced polytetrafluoroethylene (PTFE)‐based friction material with good properties for ultrasonic motor was fabricated. The effects of temperature and vacuum degree on the tribological behavior of the PTFE‐based friction material were investigated; the evolutions of friction‐wear modes and mechanisms were also discussed as function of temperature and vacuum degree. The results show that the delamination and fatigue wear are predominant under the effects of repeated shearing and dynamic contact under atmospheric environment. While wear mechanisms change from adhesive to abrasive and fatigue wear as it is cooled from 30 to ?60 °C at vacuum environment. Under high vacuum, adhesive wear was prone to taking place at room temperature for high frictional heat which increased the wear rate and extended the running‐in period. Experiment shows that the highest no‐load speed, output power, and holding torque of ultrasonic motor at room temperature under atmospheric environment are 220 rpm, 9.9 W, and 1.21 N m, respectively. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45358.     

Effect of initial gas pressure on the reaction of Al with water

The effect of initial gas pressure on Al–water reaction was investigated systematically. It was found that there is a non-monotonic relationship between the initial pressure and the induction time for the beginning of Al–water reaction. The induction time decreases with decreasing the initial pressure at the first stage from atmospheric pressure, then reaches a minimum, and finally increases with further decreasing the initial pressure. The mechanism analyses revealed that the special vacuum pressure corresponding to the minimum induction time is close to the saturated vapor pressure, below which probably there are some vapor bubbles passing or adsorbing on Al particle surfaces due to boiling, retarding the hydration process of Al surface oxide film and increasing the reaction induction time. The present results imply that a suitable initial gas pressure should be chosen for Al–water reaction to generate hydrogen.     

影响自洁玻璃光催化性能的热处理工艺研究

通过介绍自清洁玻璃产生的背景,阐述自洁玻璃的自清洁原理。从TiO_2薄膜的微观结构入手分析了TiO_2晶型对光催化性能的影响,从而找到相对应晶型的热处理工艺。     

一种评价油水井生产能力的新方法及其应用研究

准确认识和评价油水井生产能力,是油田进行合理配产配注和开发调整的基本依据。在综合分析油水井基本产能公式和实际生产动态变化的基础上,建立了累积产液量、注入量与生产压差积分的关系,并用综合产液指数、综合吸水指数,来反映油水井的实际生产能力;而在实际生产过程中,开采条件变化产生的影响可以直观地反映在不同阶段油水井的生产能力变化上,通过计算不同阶段的综合产液指数、综合吸水指数,可以准确分析和评价不同开发阶段、不同条件下,油水井综合生产能力和变化趋势。实例应用表明,利用本文建立的方法,计算过程简捷、分析结果准确,可以为油藏开发调整和油井措施的实施奠定基础。     

铝合金激光-MIG复合焊接头性能研究

探讨了激光与电弧相互作用后,焊缝中心上部和下部晶粒大小不同的原因,在此基础上研究了焊接速度的改变对6009铝合金接头的微观组织、拉伸性能、显微硬度的影响。结果表明：6009铝合金激光-MIG焊焊接接头的抗拉强度和延伸率随着焊接速度的增加而增加,拉伸试样的断裂位置由焊缝区转移到热影响区,断口呈现均匀分布的韧窝形貌,断裂机制为微孔聚集形断裂;焊缝中心上部晶粒小于焊缝中心下部,而且尺寸分布均匀。焊缝中心上部的显微硬度则高于焊缝下部。接头热影响区存在软化区,宽度为4～6 mm。     

High Brightness 2.2–12 μm Mid‐Infrared Supercontinuum Generation in a Nontoxic Chalcogenide Step‐Index Fiber

An environment friendly nonlinear chalcogenide glass fiber with a Ge‐Sb‐Se core and a Ge‐Se cladding is fabricated for bright broadband mid‐infrared (MIR) supercontinuum (SC) generation. The fabricated Ge‐Sb‐Se/Ge‐Se fiber with a core diameter of 6 μm shows zero group velocity dispersion at ~4.2 μm and ~7.3 μm. By pumping the fiber with a length of 11 cm at 4.485 μm with 330 fs pulses, we achieve a SC covering the 2.2–12 μm spectral range and with an output average power of ~17 mW. This bright broadband SC source is promising for high‐resolution MIR spectroscopy.     

富CoCr含量CoCrNiAlTi中熵合金的高温强韧化行为及微观机制

本工作研究了富CoCr含量的CoCrNi基中熵合金的高温力学性能及其变形机制。研究发现,经过热锻以及时效热处理,成分为Co_33.3Cr_30.6Ni_26.1Al₅Ti₅ (at%)中熵合金在600～800℃的温度范围内具有优异的瞬时拉伸性能。特别是,在700℃条件下出现反常屈服,屈服强度高达为944 MPa,拉伸塑性为16%,优于大多数镍基以及钴基高温合金。通过X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)和三维原子探针(3D-APT)等手段,发现高体积分数的多主元γ′[(Ni,Co,Cr)₃(Al,Ti)]相的有序强化以及晶界处生成的多主元富(Co,Cr)面心立方相(fcc)结构相引起的晶界强化是该合金在高温条件下实现强韧化的主要因素。     

沸石去除废水中氨氮的研究进展

沸石是一种天然的廉价矿物,对水中的氨氮具有较强的吸附作用,本文介绍了天然及改性沸石在去除水中氨氮的应用现状及进展,在此基础上提出了加强沸石在水处理领域研究力度、加大对资源开发的资金投入和加速成果转化的建议。