Symmetry Breaking in Monometallic Nanocrystals toward Broadband and Direct Electron Transfer Enhanced Plasmonic Photocatalysis

Metallic nanocrystals manifest themselves as fascinating light absorbers for applications in plasmon-enhanced photocatalysis and solar energy harvesting. The essential challenges lie in harvesting the full-spectrum solar light and harnessing the plasmon-induced hot carriers at the metal–acceptor interface. To this end, a cooperative overpotential and underpotential deposition strategy is proposed to mitigate both the challenges. Specifically, by utilizing both ionic additive and thiol passivator to introduce symmetry-breaking growth over gold icosahedral nanocrystals, the microscopic origin can be attributed to the site-specific nucleation of stacking faults and dislocations. By adopting asymmetric crystal shape and unique surface facets, such nanocrystals attain high activity toward photocatalytic ammonia borane hydrolysis, arising from combined broadband plasmonic properties and enhanced direct transfer of hot electrons across the metal–adsorbate interface.     

Flexible Asymmetric Supercapacitor Based on Structure‐Optimized Mn3O4/Reduced Graphene Oxide Nanohybrid Paper with High Energy and Power Density

A highly flexible Mn₃O₄/reduced graphene oxide (rGO) nanohybrid paper with high electrical conductivity and high mass loading of Mn₃O₄ nanofibers (0.71 g cm^?3) is developed via a facile gel formation and electrochemical reduction process, which is low‐cost, environmental friendly, and easy to scale up. Confined Mn₃O₄ nanofibers are well dispersed within the rGO sheets, which demonstrate to be a promising cathode material for flexible asymmetric supercapacitors (ASCs). When coupled with an electrochemically reduced rGO paper as the anode, a flexible ASC device, based on the Mn₃O₄/rGO nanohybrid paper as the cathode, is assembled; and it demonstrates remarkable electrochemical performance: a high volumetric capacitance of 54.6 F cm^?3 (546.05 mF cm^?2), and remarkable volumetric energy and power density (0.0055 Wh cm^?3 and 10.95 W cm^?3) being achieved with excellent cycling ability. The nanohybrid paper shows great improvement for flexible energy devices in terms of electrochemical properties.     

Adaptive sparse system identification using normalized least mean fourth algorithm

Normalized least mean square (NLMS) was considered as one of the classical adaptive system identification algorithms. Because most of systems are often modeled as sparse, sparse NLMS algorithm was also applied to improve identification performance by taking the advantage of system sparsity. However, identification performances of NLMS type algorithms cannot achieve high‐identification performance, especially in low signal‐to‐noise ratio regime. It was well known that least mean fourth (LMF) can achieve high‐identification performance by utilizing fourth‐order identification error updating rather than second‐order. However, the main drawback of LMF is its instability and it cannot be applied to adaptive sparse system identifications. In this paper, we propose a stable sparse normalized LMF algorithm to exploit the sparse structure information to improve identification performance. Its stability is shown to be equivalent to sparse NLMS type algorithm. Simulation results show that the proposed normalized LMF algorithm can achieve better identification performance than sparse NLMS one. Copyright © 2013 John Wiley & Sons, Ltd.     

浅谈建设综合自动化站应考虑的几个主要问题

随着计算机技术的飞速发展,综合自动化变电站已在国内得到广泛应用,根据近几年的运行经验,针对设计、管理、设备等诸方面存在的问题,提出当前和今后努力的方向。     

大中型防爆电机振动测试与分析

采用丹麦BK公司振动测量及分析仪器,对典型的大中型防爆电机振动故障进行测量分析研究,为准确判断振源特性提供依据。     

启发式电力系统暂态稳定裕度在线评估方法研究

本文定义了一个能综合反映电力系统特定结构和运行方式下整体暂态稳定水平的连续指标：综合临界切除时间。结合知识库,模糊逻辑推理和综合技术,本文提出了一种能以较高精度在线估计ＧＣＣＴ值的暂态稳定估计方法。     

Analysis of demand‐priority access using a priority queue with server vacations and message dependent switchover times

In this paper, we analyse the message waiting times in a local area network (LAN) that uses the demand‐priority access method. This is a priority‐based round‐robin arbitration method where the central controller (the repeater) polls its connected ports to determine which have transmission requests pending and the requests' priority classes. We model it as a 2‐priority M/G/1 queue with multiple server vacations and switchover time between service periods. The service discipline is nonpreemptive and the length of the switchover time is dependent upon the priority class of the preceding message served as well as that of the message to be served next. We provide an approximate analysis for the waiting times of both message classes and derive expressions for the Laplace–Stieltjes transforms (LST) of the stationary distributions and the mean waiting times. We conclude with numerical and simulation results to show the applicability and accuracy of the analytical model. This revised version was published online in June 2006 with corrections to the Cover Date.     

气敏薄膜的光学机理研究

本文根据光传输理论导出介导消光系数，折射率与介质电磁参数，光波频率，电偶极子浓度及迁移率等的关系，分析了光激发与增加气敏介质的氧吸附的规律，结合实验说明气敏薄膜的光学变化机制。     

数字微镜器件及其应用

数字微镜器件是一种新型的全数字化的平板显示器件，以其为主要组件的大屏幕投影显示技术获得了良好的市场反映。本文将具体介绍数字微镜器件的工作原理、像素结构、制作工艺及图像显示原理等。     

基于双DSP结构的实时视频压缩编码器

本文讨论了实时视频压缩编码器的设计与实现，提出了一种DSP加运动协处理器的系统结构，给出了用单象素精度运动估计器实现1／2精度运动估计的方法，并列出了系统可实现的性能指标。