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排序方式: 共有424条查询结果,搜索用时 15 毫秒
11.
Marginean I Kelly RT Prior DC LaMarche BL Tang K Smith RD 《Analytical chemistry》2008,80(17):6573-6579
A detailed characterization of a conventional low-flow electrospray ionization (ESI) source for mass spectrometry (MS) using solution compositions typical of reversed-phase liquid chromatography is reported. Contrary to conventional wisdom, the pulsating regime consistently provided better ESI-MS performance than the cone-jet regime for the interface and experimental conditions studied. This observation is supported by additional measurements showing that a conventional heated capillary interface affords more efficient sampling and transmission for the charged aerosol generated by a pulsating electrospray. The pulsating electrospray provided relatively constant MS signal intensities over a wide range of voltages, while the signal decreased slightly with increasing voltage for the cone-jet electrospray. The MS signal also decreased with increasing emitter-interface distance for both pulsating and cone-jet electrosprays due to the expansion of the charged aerosol plume. At flow rates below 100 nL/min, the MS signal increased with increasing flow rate due to increased number of gas-phase ions produced. At flow rates greater than 100 nL/min, the signal reached a plateau due to decreasing ionization efficiency at larger flow rates. These results suggest approaches for improving MS interface performance for low-flow (nano- to micro-) electrosprays. 相似文献
12.
Francisco Lara-Ochoa Juan Antonio Cogordan Ioan Silaghi-Dumitrescu 《Fullerenes, Nanotubes and Carbon Nanostructures》2013,21(5):887-896
Abstract The interaction of tBu-calix[8]arene with C60 and C70 in the 1:1 and 1:2 models have been investigated by means of molecular dynamics and molecular mechanics (CVFF91 force field) calculations. The results reveal that one C60 molecule can be encapsulated in the cavity of the calixarene which adopts a conformation with six phenyl groups oriented upward and the other two (1 and 5) outward. The relatively weak bonded 1:1 C60-calixarene system is a result of attractive π…H(C-tBu. C-methylene) and repulsive π…π interactions. C70, more voluminous than C60 can not be accommodated in the cavity of the calixarcnc and forces it to a relatively opened conformation where the number of atractive interactions is less than in the C60-calixarene system. This conformation allows however the interaction with a second molecule and thus 1:2 adducts are formed. Thus, if proper substituents are on the calixarene and the fullerene size permite the encapsulation, 1:1 complexes are obtainable while if the fullerene size is larger than the cavity of the calixarene can cope with, only the 1:2 adducts can be separated. 相似文献
13.
Fabienne Delaunois Victor Ioan Stanciu Mario Sinnaeve 《Metallurgical and Materials Transactions A》2018,49(3):822-835
Various materials are commonly used to manufacture work rolls for hot rolling mills, such as ICDP (Indefinite Chill Double Pour) cast irons, high-chromium white cast irons, and high speed steels (HSS). Various chemical compositions and microstructures are studied in order to optimize the in-use behavior of those grades of rolls. In this paper, six grades of ferrous alloys (an ICDP cast iron; an ICDP cast iron enriched in vanadium, niobium, and molybdenum; a HSS; a graphitic HSS; a high-chromium white cast iron (Hi-Cr); and a niobium-molybdenum-doped high-chromium white cast iron) were investigated. High-temperature oxidation tests with gravimetric means at 575 °C in water vapor atmosphere and sliding wear tests were carried out. The oxidation kinetics was followed during oxidation test. The microstructure was observed by optical and scanning electron microscopies. The oxides formed on the surface of the samples were analyzed by XRD and EDS. The thickness of the oxide scales and the mass gain were measured after oxidation test. The results showed that the behavior of all the grades differed. The oxide scale of HSS and HSS-G grades was fine and their friction coefficient was low. The weight gain after oxidation test of HSS was high. Hi-Cr and M-Hi-Cr grades presented highly porous oxide layer and an important increase of the friction coefficient during wear test. ICDP and M-ICDP had intermediate behavior. 相似文献
14.
Marcela-Corina Rosu Ramona-Crina Suciu Maria Mihet Ioan Bratu 《Materials Science in Semiconductor Processing》2013,16(6):1551-1557
The titanium dioxide (TiO2)-based layers sensitized with carmine and morin dyes were prepared using commercial P25 TiO2 powder as starting material. The influence of natural colorants as natural photosensitizers on TiO2 photoactivity was discussed from the point of view of UV–VIS and Fourier transform infra-red (FTIR) spectroscopy, fluorescence analysis, microscopy, X-ray diffraction and nitrogen adsorption-desorption isotherms determination. A shift to visible region of the sensitized TiO2 layers is observed. The decrease of sensitized TiO2 band gap improves its photoactivity in the visible domain. The fluorescence quenching of TiO2 sensitized with carmine is correlated with better adsorption of the dye molecules to the TiO2 surface and with electron injection process, also. The FTIR absorption spectra of samples proved the presence of dye molecules on TiO2 nanoparticles surface. Thus, the investigated sensitized TiO2-based layers could have potential in photoelectrochemical applications. 相似文献
15.
Sergiu Coseri Alina Spatareanu Liviu Sacarescu Vlad Socoliuc Ioan Sorin Stratulat Valeria Harabagiu 《应用聚合物科学杂志》2016,133(5)
Ultrasmall superparamagnetic iron oxide (Fe3O4) nanoparticles coated by biocompatible pullulan (Pu‐USPIO) with sizes below 10 nm and having a magnetite core and a hydrophilic outer shell of pullulan were prepared. The formed Pu‐USPIOs were thoroughly characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, atomic force microscopy, and small‐angle X‐ray scattering experiments. The content of magnetic nanoparticles embedded into the pullulan matrix was determined by thermogravimetric analysis. Vibrating sample magnetometry analysis was used to evaluate the magnetic properties of the Pu‐USPIO samples. Because of the presence of pullulan, these nanoparticles could be conditioned in many versatile forms, from a clear solution to magnetic films, for potential applications, including magnetic hyperthermia mediators. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42926. 相似文献
16.
In recent years, vegetable oils, as renewable raw materials, became a promising feedstock for chemicals and biodiesel production. The main products derived from oils are esters of fatty acids, especially methyl esters, obtained by their transesterification with methanol, in presence of acid or alkaline catalysts. The use of such catalysts implies the need for washing operations, which leads to environmental pollution. In the present paper, the response surface methodology based on a central composite design, has been developed to optimize the process of transesterification of corn oil. Ba(OH)2 in presence of diethyl ether was used as catalyst. A quadratic polynomial equation was obtained. It correlates the reaction parameters [methanol/oil molar ratio (x r), reaction time (x t) and catalyst concentration (x c)] with methyl esters yield. Analysis of variance analysis showed that only methanol/oil molar ratio and catalyst concentration have had the most significant influences on the conversion. The maximum methyl esters yield was obtained using the following optimum parameters: methanol/corn oil ratio of 11.32, reaction time of 118 min and catalyst concentration of 3.6 wt%. 相似文献
17.
Luiza G?in? Castelia Cristea Claudia Moldovan Dan Porumb Emanoil Surducan C?lin Deleanu Abdalah Mahamoud Jacques Barbe Ioan A. Silberg 《International journal of molecular sciences》2007,8(2):70-80
Application of a dynamic microwave power system in the chemical synthesis of some phenothiazine and quinoline derivatives is described. Heterocyclic ring formation, aromatic nucleophilic substitution and heterocyclic aldehydes/ketones condensation reactions were performed on solid support, or under solvent free reaction conditions. The microwave-assisted Duff formylation of phenothiazine was achieved. Comparison of microwave-assisted synthesis with the conventional synthetic methods demonstrates advantages related to shorter reaction times and in some cases better reaction yields. 相似文献
18.
In Part I of the paper ((1999), Trib. Trans., 42, pp. 851–859) we investigated the effect of the polyethylene concentration on the film forming properties in a rolling bearing. This second part presents the influence of the polymer additive concentration on the traction behavior experienced using a two-disk machine at different temperatures and contact pressures. By using the traction data, a semi-empirical approach for determining the effective lubricant theological parameters in EHL contacts was performed. Using this approach, the effect of polymer concentration upon rheological parameters that appear in the Johnson and Tevaarwerk model with Eyring stress was quantified. 相似文献
19.
The magnetoresistor achieved and presented in this paper is based on magnetorheological elastomer (MRE) with graphite microparticles. It is shown that the resistance R of the magnetoresistor decreases with an increase of the strength H of the transverse magnetic field and of the compression force F, respectively The sum θ of the principal deformations as well as the compresibility module K is determined and the results obtained are discussed. 相似文献
20.