Effect of ultrasound radiation on the size and size distribution of synthesized copper particles

The effect of ultrasound radiation on the size and size distribution of synthesized copper particles was investigated under various concentrations of ethylene glycol (E.G.) as a capping agent. Monodispersed copper particles were produced by the reduction of an aqueous copper (II) sulfate solution at the presence of hydrazine monohydrate. X-ray diffraction and scanning electron microscopy analysis revealed that the morphology, size, and size distribution of produced particles were influenced by the reducing agent injection rate, capping agent concentration, and sonication. Increasing the injection rate of reducing agent to an amount higher than a critical value decreases the size of copper particles and also converts the monodispersed particles to polydispersed particles. Results of using a sonifier at the reduction stage revealed that finer monodispersed copper particles can be achieved at higher injection rates related to the critical value. Increasing the concentration of E.G. as a capping agent decreases the size of copper particles, while applying ultrasound radiation along with increasing the concentration of E.G. increases the size of copper particles. Morphology of particles varies by the concentration and type of the capping agent. Higher reducing agent injection rates and the application of a sonifier at the instance of reduction result in smaller spherical particles at various capping agent concentrations.     

Comparison of Physical,Thermal, and Thermomechanical Properties of Cotton/Epoxy Composite and Cotton/Vinyl Ester Composite Inhibitors

The inhibition of a double‐base solid propellant is used to control and prevent the burning degree of the exposed area, which is due to longer burning time. In recent years, inhibition with cellulose derivatives has become popular, but these monolithic systems usually suffer from the drawback of a high erosion rate and demand high thickness and low burning time. In this research two composite inhibitors based on natural fibers were manufactured by filament winding technique and their physical, thermal, and thermomechanical properties were compared. In addition, a chlorinated flame retardant (CFR) as well as antimony trioxide were added in inhibitor compositions to control their burning processes. It was found that the cotton/epoxy composite inhibitor displays a compatible thermal expansion coefficient with the propellant and a high amount of residual char compared to cotton/vinyl ester composite. Also, it was understood that the moisture absorption resistance and thermal stability, i.e., initial decomposition temperature of cotton/vinyl ester specimen were better than cotton/epoxy specimen. Furthermore, density and the flame retardant performance of both composite inhibitors were similar. Additionally, the tan(δ) value obtained for cotton/epoxy composite was higher than that of cotton/vinyl ester composite indicating its good dissipation of vibrational energy.     

Influence of pH on the photocatalytic activity of ZnO nanoparticles

In this study, ZnO nanoparticles were fabricated by co-precipitation method. The synthesized nanoparticles possessed monodispersity with the average size 20–30 nm. Since the industrial effluents may not be at neutral pH, the effect of pH on the rate of degradation is important and need to be considered. In order to investigate the effect of pH on ZnO nanoparticles photocatalytic activity, the photocatalytic degradation of Rose Bengal, Methylene blue, and Bromocresol green dyes, was studied with different pH values. It was observed that the adsorption of the dyes onto ZnO nanoparticles surface is strongly dependent on the pH of the solution which plays an important role in photocatalytic degradation.     

Solidification of Lead Tin and Lead Telluride Eutectic Alloys in Microgravity

The Brazilian Microgravity Program is mainly based on experiments carried out on sounding rockets. A solidification furnace, capable of producing temperatures up to 900 °C, was developed to process metal and semiconductor alloys in microgravity environment. This paper describes a solidification experiment made in this furnace during a parabolic flight, with two eutectic alloys. The behavior of the eutectic alloys PbSn with 26.1 Pb at. % composition, and PbTe with 10.9 Pb at. % composition were presented and compared with laboratory solidifications carried out in the same furnace and thermal cycle. It was concluded that the formation of dendritic structures in PbSn alloy is related to the presence of sedimentation and convective flow during solidification, and the size of these structures is connected to the solidification time. Thus, in the microgravity alloy, there was no formation of dendritic structures and the profile of solute distribution remained constant throughout the sample. For the PbTe eutectic alloy the microgravity conditions have not caused significant changes compared to the earth solidified sample.     

Stabilisation of unstable FOPDT processes with a single zero by fractional-order controllers

In this article, stabilisation of unstable first-order-plus-dead-time (FOPDT) processes with a single zero by fractional-order (FO) controllers is investigated. A Nyquist stability criterion-based approach is adopted to derive the conditions for stability. Sufficient stabilisability conditions by FO [proportional integral] controllers and FO-lead–lag controllers are established. In addition, robust stability of the system with these FO controllers is investigated. To illustrate the results, some examples are provided.     

Applying simulated annealing for designing cellular manufacturing systems using MDmTSP

The design of cellular manufacturing systems involves many structural and operational issues. One of the important design steps is the formation of part families and machine cells (cell formation). Despite a large number of papers on cell formation published worldwide, only a handful incorporates operation sequence in layout design (intra-cell move calculations). We propose a solution to solve the part-family and machine-cell formation problem considering the within-cell layout problem, simultaneously. In this paper, the cellular manufacturing system is formulated as a multiple departures single destination multiple travelling salesman problem (MDmTSP) and a solution methodology based on simulated annealing is proposed to solve the formulated model. Numerical examples show that the proposed method is efficient and effective in finding optimal solutions. The results also indicate that the proposed approach performs well compared to some well-known cell formation methods.     

The Case for Quantitative Process Management

This article introduces a special section on "Embedding Statistical Methods into Software Engineering Practices." It provides a background on Quantitative Process Management and makes the case for why these methods are important. It presents an example of how a model can be developed to predict project outcomes by using data emerging from the performance of process tasks. It discusses how these methods can be used with different software development paradigms. It ends by summarizing develops needed in five different communities in order for these methods to be widely adopted.     

An optimization problem related to balancing loads on SONET rings

We provide a model and a set of solution techniques for an important problem arising in the design of survivable telecommunication networks utilizing fiber-optics-based technologies. The emergence of a synchronous standard for optical signaling called SONET allows for an economic implementation of ring designs that provides protection for high capacity services. An objective is to choose a loading of the demands onto a ring design that minimizes associated equipment and facility costs while providing capacity for alternative routing should some link or node fail. After the computational complexity of the problem has been determined, three approximation heuristics, including a mathematical programming dual-ascent solution technique, are described and compared. The heuristics are being successfully applied to actual network design problems arising in Bell operating companies and other telecommunication providers.     

A genetic algorithm for optimization problems with fuzzy relation constraints using max-product composition

We consider nonlinear optimization problems constrained by a system of fuzzy relation equations. The solution set of the fuzzy relation equations being nonconvex, in general, conventional nonlinear programming methods are not practical. Here, we propose a genetic algorithm with max-product composition to obtain a near optimal solution for convex or nonconvex solution set. Test problems are constructed to evaluate the performance of the proposed algorithm showing alternative solutions obtained by our proposed model.     

Thermophysical and rheological behavior of polystyrene/silica nanocomposites: Investigation of nanoparticle content

In this work, solvent blending in combination with extruding are applied to provide polystyrene/silica nanocomposite specimens. Transmission electron microscope (TEM) and scanning electron microscope (SEM) show same nanoparticle dispersion in PS matrix in low to high filler loadings. Differential scanning calorimetry (DSC), dynamic mechanical thermal analyzer (DMTA) and thermogravimetric analyzer (TGA) were used to study the thermophysical characteristic of the nanocomposites in solid state. In addition, the melt state rheological behavior of the samples was investigated under constant and zero shear rates. Interestingly, different behaviors were detected in nanocomposites in low and high nanoparticle loadings. In addition, rheological characteristics of molten polymer are dramatically affected in samples with low nanosilica concentration while stabilized in high filler loadings.