Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

散粒体的自组织临界性分析

基于二维模拟实验,研究竖向荷载下散粒体中的自组织临界性,揭示细观拱效应与宏观大崩塌的变化规律,以及拱效应与材料性质的关系.散粒体中每个小自组织的临界发展过程包括自组织搭拱、拱随遇平衡和拱崩塌的动力学演化.散粒体大坍塌是众多小自组织临界发生后的力学性质由量变到质变的过程.用随机理论细观探讨一个预期失败模式的理论模型,为研究散体材料结构自组织临界性系统的可预测性及灾害预测预报提供了科学依据.     

复合弯扭作用下预应力单箱组合梁的扭转承载能力分析

组合梁结构在实际工程中常处于弯扭复合受力状态,为探讨预应力单箱组合梁在复合弯扭作用下的扭转承载性能,引入了弯矩影响系数和预应力影响系数,提出了预应力单箱组合梁在弯扭作用下的开裂扭矩计算公式.并在大扭弯比条件下,基于空间桁架理论,推导了预应力单箱组合梁在弯扭作用下的极限扭矩计算公式.为了验证该理论的正确性,设计了4根模型梁试件进行弯扭加载试验.理论计算值与试验值的对比结果表明,由理论计算公式得出的结果与实际吻合良好,可为研究组合梁结构的复合弯扭问题提供一定的理论参考.     

Extended trajectory shaping guidance law considering a first-order autopilot lag

To satisfy the terminal position and impact angel constraints, an optimal guidance problem was discussed for homing missiles. For a stationary or a slowly moving target on the ground, an extended trajectory shaping guidance law considering a first-order autopilot lag (ETSGL-CFAL) was proposed. To derive the ETSGL-CFAL, a time-to-go-nth power weighted objection function was adopted and three different derivation methods were demonstrated while the Schwartz inequality method was mainly demonstrated. The performance of the ETSGL-CFAL and the ETSGL guidance laws was compared through simulation. Simulation results show that although a first-order autopilot is introduced into the ETSGL-CFAL guidance system, the position miss distance and terminal impact angle error induced by the impact angle is zero for different guidance time.     

Effect of tin addition on the microstructure and properties of ferritic stainless steel

This article reports the effects of Sn on the inclusions as well as the mechanical properties and hot workability of ferritic stainless steel. Precipitation phases and inclusions in Sn-bearing ferritic...     

Risk evaluation of rock burst through theory of static and dynamic stresses superposition

Rock burst is one of the most catastrophic dynamic hazards in coal mining. A static and dynamic stresses superposition-based(SDSS-based) risk evaluation method of rock burst was proposed to pre-evaluate rock burst risk. Theoretical basis of this method is the stress criterion incurring rock burst and rock burst risk is evaluated according to the closeness degree of the total stress(due to the superposition of static stress in the coal and dynamic stress induced by tremors) with the critical stress. In addition, risk evaluation criterion of rock burst was established by defining the "Satisfaction Degree" of static stress. Furthermore,the method was used to pre-evaluate rock burst risk degree and prejudge endangered area of an insular longwall face in Nanshan Coal Mine in China. Results show that rock burst risk is moderate at advance extent of 97 m, strong at advance extent of 97-131 m,and extremely strong(i.e. inevitable to occur) when advance extent exceeds 131 m(mining is prohibited in this case). The section of two gateways whose floor abuts 15-3 coal seam is a susceptible area prone to rock burst. Evaluation results were further compared with rock bursts and tremors detected by microseismic monitoring. Comparison results indicate that evaluation results are consistent with microseismic monitoring, which proves the method’s feasibility.     

Effects of COD to Phosphorus Ratios on the Metabolism of PAOs in Enhanced Biological Phosphorus Removal with Different Carbon Sources

To elucidate the phosphorus removal and metabolism under various COD / P ratio,a sludge highly enriched in PAOs was used to investigate the impacts of COD / P in batch tests under different carbon supply conditions. Acetate,propionate and a mixture of acetate and propionate at a ratio of 3 ∶ 1( COD basis) was used as carbon sources with the COD / P of 20,15,10 and 5. 0 g COD /gP,respectively. The minimum COD / P ratios for complete P removal were found to be 8. 24 g COD /gP for acetate,11. 40 g COD /gP for propionate and9. 10 g COD /gP for the 3 ∶ 1 mixture of acetate and propionate. Converted to a mass basis,all three cases had a very similar ratio of 7. 7 g VFA /gP,which represented a useful guide for operation of EBPR plants to identify possible shortages in VFAs. The trend in PHV accumulation during the anaerobic period along with the decrease of COD / P ratios suggested that,PAOs may use the TCA pathway for anaerobic VFA uptake to maintain the required NADH production with reduced glycogen degradation. During the aerobic phase,the glycogen pool was reduced but remained enough compared to the requirement for anaerobic VFA uptake,and the synthesis and degradation of glycogen was not the inhibition factor of PAOs.     

Hydraulic Self Servo Swing Cylinder Structure Optimization and Dynamic Characteristics Analysis Based on Genetic Algorithm

The dynamic characteristics of hydraulic self servo swing cylinder were analyzed according to the hydraulic system natural frequency formula. Based on that, a method of the hydraulic self servo swing cylinder structure optimization based on genetic algorithm was proposed in this paper. By analyzing the four parameters that affect the dynamic characteristics, we had to optimize the structure to obtain as larger the Dm(displacement) as possible under the condition with the purpose of improving the dynamic characteristics of hydraulic self servo swing cylinder. So three state equations were established in this paper. The paper analyzed the effect of the four parameters in hydraulic self servo swing cylinder natural frequency equation and used the genetic algorithm to obtain the optimal solution of structure parameters. The model was simulated by substituting the parameters and initial value to the simulink model. Simulation results show that: using self servo hydraulic swing cylinder natural frequency equation to study its dynamic response characteristics is very effective. Compared with no optimization, the overall system dynamic response speed is significantly improved.     

火驱燃烧前缘位置预测与影响因素研究

及时掌握火驱过程中火线的位置,有助于进行生产调控,通过调研现场预测火线位置的方法,得出一套针对不同特征油藏的适用方法:红外照相法适用于浅层油藏;用测温元件直接测试法适用于观察井和生产井密集的油藏;生产动态和物质平衡相结合的方法适用于均质性好且井网形式规范的油藏;示踪剂监测和生产动态相结合的方法适用于非均质性严重或井网形式不规范的油藏;压降试井法由于计算复杂,有待进一步研究。最后指出应在前期地质筛选的基础上,做到"少注气、多采油",并结合生产动态分析加强对油井的管理,引导燃烧前缘均匀稳定的推进。     

船舶电力推进系统稳定性分析

为获得变频驱动感应电机调速系统低频振荡产生的原因,以实验室一套船舶电力推进系统为例展开研究。建立了基于小扰动的感应电机、变频器及船舶电力推进系统的数学模型,分析了死区时间对系统稳定性的影响。利用根轨迹分析方法,通过解析计算与仿真分析绘制了系统的不稳定区域。讨论了电机定子电阻和漏感变化对系统稳定区域的影响,进行了试验验证,试验结果与解析计算得到的不稳定区域吻合较好,证明所建立的船舶电力推进系统小扰动数学模型以及采用的系统稳定性分析方法是正确可行的。