New approach to model the buckling and stable length of multi walled carbon nanotube probes near graphite sheets

Modeling the buckling of multi walled carbon nanotube (MWCNT) probes/actuators in the vicinity of thin and thick graphite has been carried out for the first time via two analytical approximation methods as well as a numerical one. A hybrid nano-scale continuum model based on Lennard-Jones potential is applied to simulate the intermolecular force-induced deflection of MWCNT. The critical values of MWCNT tip deflection and MWCNT-graphite attraction at the onset of the instability are computed. In addition, minimum nanotube-graphite initial gap and stable length of freestanding CNT are determined as basic parameters for engineering applications and nano-devices design. The stable length of MWCNT is determined as a function of its geometrical and material characteristics, initial gap and number of graphene layers.     

The significance of asbestos exposure in the diagnosis of mesothelioma: a 28-year experience from a major urban hospital

A continued increase in the incidence of diffuse mesothelioma has been attributed to greater industrial use of asbestos but is also due in part to wider acceptance of this tumor by pathologists. In this retrospective study, the epidemiology, clinical presentation, and pathology of asbestos and non-asbestos-related mesothelioma from a major urban hospital were reviewed. Of the 36 cases of mesothelioma on file, 19 were not associated with exposure to asbestos. Although a retrospective study raises the possibility of inadequate occupational histories, the lack of history of asbestos exposure correlated with postmortem histology by light microscopy. When postmortem material was reviewed, evidence of asbestos exposure was present in all cases of mesothelioma with history of exposure to asbestos, and in no cases in which the patient denied history of asbestos exposure. Using strict histologic and histochemical criteria, the diagnosis of mesothelioma was confirmed in 8 of 9 patients with asbestos-related mesothelioma but in only 4 of 13 cases of non-asbestos-related mesothelioma. The diagnosis of diffuse methelioma is often difficult to make even wtih complete autopsy examinations. It should be entertained only with adherence to strict clinical and pathologic criteria, especially in women with no history to exposure to asbestos dust.     

Phytochemical and Antioxidant Properties of Achillea Millefolium from the Eastern Region of Iran

The aim of present study was to evaluation the antioxidant potential of Achillea millefolium on the basis of the chemical compositions of oils obtained by hydrodistillation. In the case of Achillea millefolium, 24 compounds were identified representing the 83.76% of the total oil. The major constituents of the oil were described as α-pinene (10.12%), camphene (4.23%), limonene (5%), borneol (5%), γ-terpinene (8%), carvone (5%), bornyl acetate (2.43%), thymol (15.32%), and carvacrol (20.43%). The oils were also subjected to screening for their possible antioxidant activity using 2,2-diphenyl-1-picrylhydrazyl assays. Thymol (12.0 ± 0.1 µg/mL) and carvacrol (14.43 ± 0.0 µg/mL) showed appreciable antioxidant activity in 2,2-diphenyl-1-picrylhydrazyl test. Antioxidant activity guided fractionation of the oil was carried out by The TLC-bioautography screening and fractionation resulted in the separation of the main antioxidant compound which were identified as thymol (65%) and carvacrol (25%).     

Determination of fracture energy,process zone longth and brittleness number from size effect,with application to rock and conerete

The dependence of the fracture energy and the effective process zone length on the specimen size as well as the craek extension from the notch is analyzed on the basis of BaN at failure is reformulated in a manner in which the parameters are the fracture energy and the effective (elastically equivalent) process zone length. A method to determine these material properties from _N-data by linear and nonlinear regressions is shown. This method permits these properties to be evaluated solely on the basis of the measured maximum loads of specimens of various sizes and possibly also of different shapes. Variation of both the fracture energy and the effective process zone length as a function of the specimen size is determined. The theoretical results agree with previous fracture tests of rock as well as concrete and describe them adequately in relation to the inevitable random scatter of the tests.

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Résumé En se reposant sur la loi des effets dimensionnels approximatifs développée par Ba     

Mechanical and morphological properties of wood plastic composites based on municipal plastic waste

Production and characterization of wood plastic composites (WPC) from the light fraction of municipal plastic wastes (post‐consumer) and wood processing residues (sawdust) were investigated. Composition analysis revealed the presence of polyethylene (PE) and polypropylene (PP) as the two main components of the matrix. In order to improve compatibility and adhesion between all the phases, an ethylene–octene copolymer was used to compatibilize the polymer phases and was also acting as an impact modifier, while the addition of maleated polyethylene and maleated polypropylene (MAPP) were acting as coupling agents between the polymer matrix and the wood flour. The combined effect of all the components was found to produce composites with interesting morphological (dispersion and adhesion) and mechanical properties (tension, torsion, flexion, and impact) after optimization of the additive package (blend of coupling agents). POLYM. COMPOS., 2013. © 2013 Society of Plastics Engineers     

PHENOLIC WASTEWATER TREATMENT BY SUPPORTED LIQUID MEMBRANE USING DIFFERENT COOKING OILS AS LIQUID MEMBRANE

Transport of phenol through a flat sheet supported liquid membrane (SLM) containing cooking oil as liquid membrane (LM) was investigated. Factors affecting permeation of phenol such as membrane phase, support material, feed phase pH, stripping phase concentration, stirring speed, and initial concentration of phenol were studied. It was found that these parameters strongly influence phenol removal efficiency; PTFE membrane as support material, grape seed oil as liquid membrane, feed pH of 2.0, initial phenol concentration of 100 mg/L, stirring speed of 350 rpm, and 0.2 M sodium hydroxide as effective stripping agent were found as the best conditions for greater phenol transport. Under these conditions, permeability was found to be 7.46 × 10^?6 m/s. After 10.5 h, phenol was completely removed from the feed phase to strip phase. According to stability experiments, it was observed that the SLM is stable after 22 h. Thus, the use of cheap, nontoxic, and naturally oil as a novel and green membrane for recovery of phenol from wastewater was demonstrated.     

Cyclic voltammetry and scanning electrochemical microscopy studies of methylene blue immobilized on the self-assembled monolayer of n-dodecanethiol

Electron transfer (ET) kinetics through n-dodecanethiol (C₁₂SH) self-assembled monolayer on gold electrode was studied using cyclic voltammetry (CV), scanning electrochemical microscopy (SECM) and electrochemical impedance spectroscopy (EIS). An SECM model for compensating pinhole contribution, was used to measure the ET kinetics of solution-phase probes of ferrocyanide/ferricyanide (Fe(CN)₆^4−/3−) and ferrocenemethanol/ferrociniummethanol (FMC^0/+) through the C₁₂SH monolayer yielding standard tunneling rate constant () of (4 ± 1) × 10⁻¹¹ and (3 ± 1) × 10⁻¹⁰ cm s⁻¹ for Fe(CN)₆^4−/3− and FMC^0/+ respectively. Decay tunneling constants (β) of 0.97 and 0.96 Å⁻¹ for saturated alkane thiol chains were obtained using Fe(CN)₆⁴⁻ and FMC respectively. Also, it was found that methylene blue (MB) molecules are effectively immobilized on the C₁₂SH monolayer and can mediate the ET between the solution-phase probes and underlying gold substrate. SECM-mediated model was used to simultaneously measure the bimolecular ET between the solution-phase probes and the monolayer-immobilized MB molecules, as well as tunneling ET between the monolayer-immobilized MB molecules and the underlying gold electrode, allowing the measurement of k_BI = (5 ± 1) × 10⁶ and (4 ± 2) × 10⁷ cm³ mol⁻¹ s⁻¹ for the bimolecular ET and and (7 ± 3) × 10⁻² s⁻¹ for the standard tunneling rate constant of ET using Fe(CN)₆^4−/3− and FMC^0/+ probes respectively.