STUDY OF MECHANISM OF RQ EMBRITTLEMENT OF Fe_(73.5)Cu_1-Nb_3Si_(13.5)B_9 NANOCRYSTALLINE SOFT MAGNETIC ALLOY

Rapidly quenching embrittlement (RQE) sometimes appears in Fe73.5Cu1Nb3Si13.5B9 nanocrystalline soft magnetic alloy (FINEMET) during production process. As a re-sult of RQE the ductility of the as-quenched ribbon drops seriously. The mechanism of RQE has been elucidated in the recent works of current authors. It was believed that RQE is due to the structural relaxation but not related to a-Fe(Si) crystallization. In this paper, the high resolution TEM (HRTEM) method and image digital processing were applied to analyze the HRTEM images of two FINEMET rapidly quenched ribbons with different thicknesses in detail. In the thinner ductile sample, the ordering domains with the size of about 3nm are observed. In the thicker RQE sample, the metastable nanocrystalline domains with the size of 18nm are observed along with the structural relaxation. These domains seem to have Fe3B-like metastable phase struc-ture on nanometer scale. The result indicates that the local atomic ordering regions extend when RQE induced     

A STUDY OF B-P UNIFIED VISCOPLASTIC CONSTITUTIVE MODEL

By combining the Bodner-Partom constitutive model and equivalent stress function, finite element methods and program on analyzing non-elastic deformation and stress for thermal viscoplastic material are studied in this paper, and it's the first time that this material model is used in a kind of engineering software-MARC. Thermal viscoplastic behavior of high temperature alloy GH536 specimen with gap is analyzed by this program. The research results show it is feasible to analyze thermal viscoplastic behavior of specimen or structure by applying B-P model.     

EFFECTS OF SPECIFIED BLANK SIZE ON BODY WRINKLING DURING HYDRODYNAMIC DEEP DRAWING OF TAPERED RECTANGULAR BOX

1.~nonHydridapawhcdeepdrawing(HDD)belongstothefieldofsheetmetalfoeingandcanbeaPPliedinthefieldofautomotive,aerospace,drilitaryindustryetc.Ithasbeenrecognizedwidelyintheworld["'j.Fig.Ishowsitsprinciple:TheliqUidthatisfilledinthe~ngdiecavitywillbepressedwhenthepunchgoesdownsothattheeffectoffrictionkeepingandoverflowlubricatingcanbeformed,astherestilt,thefoeinglicitofsheetmetalwillbeimprovedareailvandthegualitVofthefinishedpartswillbeup~ed.BecauseofmanyadvantagesofHDDprocees,ithasbeenwidelys…     

氢氧化铝分解技术

引言自从1911年原拜耳法专利权消失以后,世界绝大多数氧化铝都是用拜耳法生产的。但直到50年代末,由于所用铝土矿的组成,能源价格和所用电解槽设计的不同,拜耳法一直用两种不同的工艺条件生产。“欧洲”拜耳法在用高温、高苛性碱浓度溶出和氢氧化铝分解的产出率高达60克/升以上的条件下,生产细粒、高温焙烧的粉状氧化铝。“美国”拜耳法     

气泡强化钨的烧结鼓胀

烧结的目的通常在于生产近理论密度的无孔隙试样,但在某些应用中,为了得到好的高温蠕变性能又需要借助气泡生成物造成稳定的残留孔隙。本文主要以KSiAl-掺杂钨压块在直流电烧结的最后阶段出现的反烧结(desintering)趋势为依据,概述了金属基体中的非溶性气相的某些观测结果。     

Rationally designed inhibitors as tools for comparing the mechanism of squalene-hopene cyclase with oxidosqualene cyclase

The inhibition of squalene-hopene cyclase (SHC) (E.C. 5.4.99.-), an enzyme of bacterial membranes catalyzing the formation of pentacyclic sterol-like triterpenes, was studied by using different classes of compounds originally developed as inhibitors of oxidosqualene cyclase (OCS) (E.C. 5.4.99.7), the enzyme of eukaryotes responsible for the formation of tetracyclic precursors of sterols. The mechanism of cyclization of squalene by SHC, beginning with a protonation of the 2,3 double bond by an acidic residue of the enzyme, followed by a series of electrophilic additions of the carbocationic intermediates to the double bonds, is similar to the mechanism of cyclization of 2,3-oxidosqualene by OSC. The inhibitors studied included: (i) analogs of the carbocationic intermediates formed during cyclization, such as aza-analogs of squalene and 2,3-oxidosqualene; (ii) affinity-labeling inhibitors bearing a methylidene reactive group; and (iii) vinyldioxidosqualenes and vinylsulfide derivatives of the substrates. Comparison of the results obtained with the two enzymes, SHC and OSC, showed that many of the most effective inhibitors of OSC were also able to inhibit SHC, while some derivatives acted as specific inhibitors. Differences could be easily explained on the basis of the different substrate specificity of the two enzymes.     

氧化硅有序介孔材料MCM-41的微波水热合成及用于组装ZnO纳米粒子

与传统水热合成工艺相比,采用微波水热合成新工艺可以快速合成比表面积大、孔体积和孔径大、孔径分布范围更窄、孔洞呈六方排布的有序介孔材料MCM-41.微波水热合成工艺合成的MCM-41具有合成效率高、成功率高等特点,为此类介孔材料商业化提供了高效的技术手段.采用传统水热工艺合成MCM-41通常需要48～72 h,而采用微波水热合成技术仅需要30 min.采用X射线粉晶衍射(XRD),氮气吸附等技术手段对合成MCM-41材料的物相、比表面积、孔体积、孔径等进行了表征.采用微波水热合成MCM-41的工艺参数为:微波处理的温度120 ℃,时间30 min,微波辐射功率500 W,经过滤、洗涤、干燥、焙烧等处理后,得到的MCM-41具有六方排布的孔系,晶格常数a0=4.4nm,比表面积可达1113 m2/g,平均孔径为2.7 nm,与选用同样配方采用传统水热合成工艺合成的MCM-41的性能相当,却极大提高了合成效率.采用微波水热合成工艺,同样可以合成立方晶系的MCM-48和六方晶系的SBA-15等介孔氧化硅分子筛材料.此外,在微波合成的MCM-41中采用液相工艺成功组装了ZnO纳米粒子,并对组装在MCM-41中的纳米ZnO粒子进行了光催化降解苯酚的实验研究.     

Influence of sources of dietary oils on the life span of stroke-prone spontaneously hypertensive rats

In recent studies, the life span of stroke-prone spontaneously hypertensive (SHRSP) rats was altered by a variety of dietary fats. It was relatively shorter in rats fed canola oil as the sole source of fat. The present study was performed to find out whether the fatty acid profile and the high content of sulfur compounds in canola oil could modulate the life span of SHRSP rats. SHRSP rats (47 d old, n=23/group) were matched by body weight and systolic blood pressure and fed semipurified diets containing 10% canola oil, high-palmitic canola oil, low-sulfur canola oil, soybean oil, high-oleic safflower oil, a fat blend that mimicked the fatty acid composition of canola oil, or a fat blend high in saturated fatty acids. A 1% sodium chloride solution was used as drinking water to induce hypertension. After consuming the diets for 37 d, five rats from each dietary group were killed for collection of blood and tissue samples for biochemical analysis. The 18 remaining animals from each group were used for determining their life span. The mean survival time of SHRSP rats fed canola oil (87.4±4.0 d) was not significantly different (P>0.05) from those fed low-sulfur canola oil (89.7±8.5 d), suggesting that content of sulfur in canola oil has no effect on the life span of SHRSP rats. The SHRSP rats fed the noncanola oil-based diets lived longer (mean survival time difference was 6–13 d, P<0.05) than those fed canola and low-sulfur canola oils. No marked differences in the survival times were observed among the noncanola oil-based groups. The fatty acid composition of the dietary oils and of red blood cells and liver of SHRSP rats killed after 37 d of treatment showed no relationship with the survival times. These results suggest that the fatty acid profile of vegetable oils plays no important role on the life span of SHRSP rat. However, phytosterols in the dietary oils and in liver and brain were inversely correlated with the mean survival times, indicating that the differential effects of vegetable oils might be ascribed, at least partly, to their different phytosterol contents.     

Small amphiphilic organics, coordination extended solids, and constant curvature structures

In this Account, we explore the role constant curvature structures play in amphiphilic small molecule crystals and extended coordination solids. A constant curvature structure is one in which there is a surface or interface that has the same curvature throughout its surface. Simple examples of such structures contain spheres (micelles), columns, or layers. Yet another family are cubic as is found in the gyroid topology. For amphiphilic systems, there are two domains, one generally hydrophobic and the other hydrophilic. We find that the interfaces between these two domains in small molecule structures resemble those in larger scale systems and adopt topologies related to constant curvature structures. The hydrophobic-to-total volume ratio, a molecular parameter, can be used to predict which type of constant curvature structure is adopted. In the case of three coordinate extended solids, constant curvature plays a role both in the extended net topology and in the hydrophobic-to-hydrophilic interface.