Preparation,structural elucidation,molecular weight determination,and molecular recognition of first‐ and second‐tier dendrimer molecules

1,3,5‐Triglyceratetriazine [first tier (G₁)] and tri(1,3,5‐triglycerate) triazine [second tier (G₂)] dendrimers were prepared with 1,3,5‐trichlorotriazine and sodium glycerate in a 1 : 3 mass ratio in an ethanolic medium.G₁ and G₂ were amorphous, white, solid substances. Their structures were elucidated with IR, ¹H‐NMR, and ¹³C‐NMR, and their thermal stability was studied with thermogravimetric analysis. The activation energy was calculated with the Freeman–Carroll model. Densities, viscosities, and surface tensions for 0.01–0.08 mol/kg aqueous solutions increased at 0.01 mol/kg for sodium glycerate, 1,3,5‐trichlorotriazine, 1,3,5‐triazine triglycerate chloride, G₁, and G₂. These values were measured at 298.15 K. The apparent molal volume, reduced viscosity, and inherent viscosity were calculated from the densities and viscosities, respectively. The data were regressed for the limiting densities, limiting apparent molal volumes, intrinsic viscosities, limiting inherent viscosities, and limiting surface tensions for solute–solvent interactions. The positive limiting apparent molal volume values were noted in the order of G₂ > 1,3,5‐triazine triglycerate chloride > G₁ > 1,3,5‐trichlorotriazine > sodium glycerate, with weaker hydrophilic intermolecular interactions of G₂. The higher intrinsic viscosity and limiting inherent viscosity values for G₂ implied stronger G₂–H₂O hydrophilic interactions, and the higher limiting apparent molal volume of G₂ indicated slightly higher dynamic conformational changes in comparison with G₁, with stronger structural activities. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

浅析改进的SET协议在电子商务中的作用

随着网络的发展，电子商务越来越引起人们的注意，如何保证传输数据的安全性成为电子商务能否普及的最重要因素之一。本文根据信息隔离和隐藏的原则改进了SET协议，改进后的SET协议允许持卡人参与帐目汇报，以及在电子商务中提供信用卡代理以便隐藏信用卡卡号。改进后的SET协议可有效对抗小范围内交易的机密侵密和大范围内的数据聚合。     

CO毒化AB5型合金分形特征研究

研究了三种贮氢合金 L a Ni5、L a Ni4 .7Al0 .3、Ml Ni4 .5Al0 .5被 10 0× 10 - 6 CO毒化后的分形特征 ,求出这三种合金在含 10 0× 10 - 6 CO的氢中循环 ,分维分别为 0 .2 5 4 7、0 .170 9、0 .0 72 5。可以较好的解释合金被毒化的宏观现象。     

聚丙烯酸酯防水乳液的研究进展

综述了聚丙烯酸酯防水乳液的理论研究进展，重点评述了组合功能单体、优选乳化体系和进行粒子设计三方面的改性手段。     

浅析当今写意青花的题材选择

青花装饰是景德镇的传统装饰方法之一，其中的写意青花又以其简约萧疏的艺术特征获得了人们的普遍喜爱。针对时代的变化影响，研究了当今写意青花在题材选择上与传统写意青花的差异。     

Plasma properties of laser-ablated St target in air

Ｐｌａｓｍａｐｒｏｐｅｒｔｉｅｓｏｆｌａｓｅｒ－ａｂｌａｔｅｄＳｔｔａｒｇｅｔｉｎａｉｒＷａｎｇＸｉａｎｇ－Ｔａｉ（王象泰）；ＭａｎＢａｏ－Ｙｕａｎ（满宝元）；ＷａｎｇＧｏｎｇ－Ｔａｎｇ（王公堂）；ＦａｎＸｉ－Ｊｕｎ（樊锡君）；ＷａｎｇＪｕｎ（王军）...     

硼预淀积对自组织生长Ge量子点尺寸分布的影响

研究了以不同B2H6流量预淀积硼对UHV/CVD自组织生长Ge量子点尺寸分布的影响。在适当的生长条件下,得到了尺寸分布很窄的均匀Ge量子点,用AFM对量子点的形貌进行观察,Ge量子点尺寸的涨落小于±3%,量子点的水平尺寸和高度分别为60nm和10nm,密度为8×109cm-2。实验结果表明,通过预淀积硼表面处理,可以得到尺寸分布很窄的量子点,以满足量子点光电器件方面应用的要求。     

RELAP5程序与三维时空中子动力学模型的耦合以及改进研究

引入堆芯物理计算的两群三维时空中子动力学模型,对RELAP5程序的点堆中子动力学模型进行了改进,同时设计了可视化界面,可方便地实现人.机交互操作.计算结果与实际应用表明,改进后的RELAP5程序计算功能和精度得到提高,使用更加方便,在核动力装置的仿真方面有很好的应用前景.     

光纤电流差动保护接口复用通道误码分析及处理办法

光纤电流差动保护通过通信专业PCM的64kbit/s复接接口传输命令,现已广泛应用在220 kV及以上高压线路中,但在一些线路保护投运时或运行中出现了由于误码太高造成了保护通道退出运行的情况.作者根据广西电网电流差动保护在光纤复用通道的实际运行中出现的几种误码问题进行具体分析,提出在设计、施工、验收过程中的改进意见.