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221.
Xiangrong Ma Rui Dang Ning Yang Xiao Li Ya zhang Ying Gong Zhipan Liu Wei Guo Yuanyuan Zhang Chunyan Li 《International Journal of Hydrogen Energy》2021,46(44):22842-22851
The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag3VO4 have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag3VO4 (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H2 production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H2 evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H2 evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions. 相似文献
222.
Xi Shen Li-Peng Cao Jian-Fa Zhao Wei-Peng Wang Qing-Qing Liu Yuan Yao Jun-Jie Li Chang-Zhi Gu Ming-Wei Chen Chang-Qing Jin Ri-Cheng Yu 《Journal of the American Ceramic Society》2019,102(11):6469-6474
We propose the question of the modulated structures of copper oxide is caused by the [CuO2] in-plane oxygen vacancy or apical oxygen vacancy. Sr2CuO3+δ single-crystal samples were prepared using high-temperature and high-pressure methods. The major phase of Sr2CuO3+δ (δ = 0.4) single-crystal system is found to be constituted by the 5 a modulated structure with the Fmmm space group, which originates from the [CuO2] in-plane oxygen vacancy appearing in octahedral Cu-O. Besides, the presence of the [CuO2] in-plane oxygen vacancy may obliterate the superconductivity of the system. Experimental results deduce that the oxygen vacancy may appear in the apical oxygen sites in high-temperature copper oxide superconductors. 相似文献
223.
刘家山排土场为民采排弃形成,已经出现大规模滑坡。为了保证上下游生产生活设施的安全,依据现场实际情况,结合现场调查,提出了削坡处理的方案。经过治理后,刘家山排土场平稳地渡过了雨季,目前处于稳定状态,达到了治理目的。 相似文献
224.
针对目标探测类空间红外相机大范围成像、高灵敏度探测、高精度定位等应用需求,文中提出采用像方远心光路和低温光学技术结合的解决方案,设计了物方视场角8°×8°、入瞳口径265 mm、工作温度200 K的像方远心折射式光学系统。镜头最大口径280 mm,采用多级分散的弹性支撑设计,解决大口径低温透镜装框、透镜组件支撑和镜头整体安装各环节的热应力卸载问题。在保证高刚度和低漏热的情况下,使低温下透镜的热应力对镜头能量集中度的影响降低到可接受范围内。镜头完成装调及室温下像质确认后,进行了力学振动试验,并将其制冷到200 K水平测试像质,测试结果表明,镜头能量集中度达到轴上75%,边缘视场72%。 相似文献
226.
227.
Wyatt L. Brown Douglas A. Day Harald Stark Demetrios Pagonis Jordan E. Krechmer Xiaoxi Liu Derek J. Price Erin F. Katz Peter F. DeCarlo Catherine G. Masoud Dongyu S. Wang Lea Hildebrandt Ruiz Caleb Arata David M. Lunderberg Allen H. Goldstein Delphine K. Farmer Marina E. Vance Jose L. Jimenez 《Indoor air》2021,31(1):141-155
Understanding the sources and composition of organic aerosol (OA) in indoor environments requires rapid measurements, since many emissions and processes have short timescales. However, real-time molecular-level OA measurements have not been reported indoors. Here, we present quantitative measurements, at a time resolution of five seconds, of molecular ions corresponding to diverse aerosol-phase species, by applying extractive electrospray ionization mass spectrometry (EESI-MS) to indoor air analysis for the first time, as part of the highly instrumented HOMEChem field study. We demonstrate how the complex spectra of EESI-MS are screened in order to extract chemical information and investigate the possibility of interference from gas-phase semivolatile species. During experiments that simulated the Thanksgiving US holiday meal preparation, EESI-MS quantified multiple species, including fatty acids, carbohydrates, siloxanes, and phthalates. Intercomparisons with Aerosol Mass Spectrometer (AMS) and Scanning Mobility Particle Sizer suggest that EESI-MS quantified a large fraction of OA. Comparisons with FIGAERO-CIMS shows similar signal levels and good correlation, with a range of 100 for the relative sensitivities. Comparisons with SV-TAG for phthalates and with SV-TAG and AMS for total siloxanes also show strong correlation. EESI-MS observations can be used with gas-phase measurements to identify co-emitted gas- and aerosol-phase species, and this is demonstrated using complementary gas-phase PTR-MS observations. 相似文献
228.
Yingchao Hu Wenqiang Liu Yuandong Yang Xianliang Tong Qianjun Chen Zijian Zhou 《Ceramics International》2018,44(14):16668-16677
Li4SiO4 sorbents for high-temperature CO2 removal have drawn extensive attention owing to their potential application in carbon capture and storage (CCS). The major challenge in the application lies in the poor CO2 capture performance under realistic conditions of low CO2 concentrations, owing to the dense structure and poor porosity. In this work, Li4SiO4 sorbents were prepared with porous micromorphologies and large contact areas using a variety of organometallic Li-precursors, achieving fast CO2 sorption kinetics, high capacity and excellent cyclic stability at a low CO2 concentration (15?vol%). It was found that a high conversion of ~?74% was maintained for pure Li4SiO4 even after 100 sorption/desorption cycles. Moreover, by doping with Na2CO3 to reduce the CO2 diffusion resistance, the conversion of the sorbent was further enhanced to 93.2%. The enhancement mechanism of alkali carbonate have been proven here to be ascribed to the formation of the eutectic melt of Li/Na carbonates, the existence and function of which has been confirmed in this study. 相似文献
229.
气烟囱效应——礁滩相岩性气藏的典型地震响应特征 总被引:14,自引:0,他引:14
品质良好的地震剖面上出现的地震模糊带称为气烟囱,发现和识别气烟囱是寻找大型气藏的有效方法。四川盆地东北部长兴组气藏是礁滩相岩性气藏,礁、滩作为一个独立的岩性体,与周围的地层、岩性结构差异较大,由此在构造应力场中形成力学尖点,从而产生气烟囱效应。已知的黄龙场、普光等气田,其气烟囱普遍存在。点礁通常形成下方的气烟囱,台缘礁通常在上方形成气烟囱;礁滩相在构造运动中控制了断层的发育过程,凸起的礁滩相上方可能发育对冲断层;斜坡较陡的台缘礁可能发育叠置的逆冲断层;礁、滩两侧边缘的断层一般都比较发育。断层发育加强了气烟囱效应。模拟试验验证了地震剖面解释结果。根据气烟囱地震相特征,预测黑池梁存在一个大型气藏。 相似文献
230.