Characteristic strength and acoustic emission properties of weakly cemented sandstone at different depths under uniaxial compression

As coal mining is extended from shallow to deep areas along the western coalfield,it is of great significance to study weakly cemented sandstone at different de...     

Recent Advances in Porphyrin-Based Systems for Electrochemical Oxygen Evolution Reaction

Oxygen evolution reaction (OER) plays a pivotal role in the development of renewable energy methods, such as water-splitting devices and the use of Zn–air batteries. First-row transition metal complexes are promising catalyst candidates due to their excellent electrocatalytic performance, rich abundance, and cheap price. Metalloporphyrins are a class of representative high-efficiency complex catalysts owing to their structural and functional characteristics. However, OER based on porphyrin systems previously have been paid little attention in comparison to the well-described oxygen reduction reaction (ORR), hydrogen evolution reaction, and CO₂ reduction reaction. Recently, porphyrin-based systems, including both small molecules and porous polymers for electrochemical OER, are emerging. Accordingly, this review summarizes the recent advances of porphyrin-based systems for electrochemical OER. Firstly, the electrochemical OER for water oxidation is discussed, which shows various methodologies to achieve catalysis from homogeneous to heterogeneous processes. Subsequently, the porphyrin-based catalytic systems for bifunctional oxygen electrocatalysis including both OER and ORR are demonstrated. Finally, the future development of porphyrin-based catalytic systems for electrochemical OER is briefly prospected.     

A Multifunctional and Fast-Response Lysosome-Targetable Fluorescent Probe for Monitoring pH and Isoxaflutole

A new chemosensor, namely N-(2-morpholinoethyl)acetamide-4-morpholine-1,8-naphthimide (MMN), was designed and synthesized through an amidation reaction. MMN was fabricated as a multifunctional fluorescent probe for monitoring pH and isoxaflutole. MMN exhibited excellent stability in MeCN/H₂O (v/v, 9/1), with an obvious “off–on” fluorescence response toward pH changes due to intramolecular charge transfer (ICT), where the linear response ranges of MMN in the weakly acidic system were from 4.2 to 5.0 and from 5.0 to 6.0 with apparent pK_a = 4.62 ± 0.02 and 5.43 ± 0.02. Based on morpholine as the lysosome targetable unit, MMN could selectively locate lysosomes in live cells. MMN also successfully detected the presence of H⁺ in test papers. Finally, MMN could specifically recognize isoxaflutole at a detection limit of 0.88 μM. A possible sensing mechanism was identified based on density function theory calculations. These results indicate that MMN could be a superior potential chemosensor for detecting pH and isoxaflutole selectively and sensitively and could be used in real sample detection.     

不同酯化度果胶钙的结构特征与体外消化稳定性

为探究不同酯化度（DE）果胶形成的果胶钙的结构特征与消化稳定性,采用5种DE值的果胶与氯化钙反应获得5种DE的果胶钙,比较其产率、钙含量,红外、X衍射（XRD）、电镜（SEM）等结构特征与体外模拟消化稳定性。结果表明：果胶钙产率为50%～87%;DE=10%的果胶与Ca2+反应形成的果胶钙（DE10-CaP）的钙含量最高（88 mg/g）,DE59-CaP钙含量最低（43.6 mg/g）;果胶钙中Ca2+与羧酸根的结合形式为单齿配位结合型,并可分为3种结合区域,进一步完善了果胶钙的结合模式;XRD表明低酯果胶钙比高酯果胶钙多一处2θ=21.5°的衍射峰;SEM表明低酯果胶钙的表观结构更紧密,呈块状,高酯果胶钙则呈薄片状。体外模拟胃肠消化试验表明,高酯果胶钙的钙释放率及释放量更高。本研究有助于了解果胶钙的微观结构及应用性能。