Photocatalytic oxidation of low concentration 2,4-D solution with new TiO2 fiber catalyst in a continuous flow reactor.

Environmental pollution by low concentrations of 2,4-Dichlorophenoxyacetic acid (2,4-D) is a concern these days due to ever increasingly stringent regulations. Photocatalysis with immobilized TiO2 fiber is a promising oxidation method. Laboratory experiments on photocatalytic degradation of 0.045 mmol l(-1) 2,4-D with the world's first high-strength TiO2 fiber catalyst were carried out in a continuous flow reactor in which the degradations were, in general, similar to those with high 2,4-D concentrations investigated elsewhere. Degradation and mineralization of 2,4-D were significantly enhanced with no initial pH adjustments. The rate constants for total organic carbon (TOC) without pH adjustment were about two-fold bigger than the pH adjustment cases. CO2 gas measurement and carbon mass-balance were carried out for the first time, where about 34% organic carbon converted into CO2 gas during four-hour oxidation. 2,4-Dichlorophenol (2,4-DCP), phenol, benzyl alcohol and two unknowns (RT = 2.65 and 3.78 min.) were detected as aromatic intermediates while Phenol was the new aromatic in HPLC analysis. Dechlorination efficiencies were high (> 70%) in all the cases, and more than 90% efficiencies were observed in chloride mass balance. Bigger flow rates and solution temperature fixed at 20 degrees C without pH adjustment greatly enhanced 2,4-D mineralization. These results can be an important basis in applying the treatment method for dioxin-contaminated water and wastewater.     

Operation of the dam of the Bureiskaya HPP during filling of the reservoir

Operation of the dam in a transitional mode is described. __________ Translated from Gidrotekhnicheskoe Stroitel’stvo, No. 1, January 2006, pp. 8–15.     

Occurrence and characterisation of the hydrogen-evolving enzyme in Frankia sp.

An increase in hydrogen evolution from the hydrogen-evolving enzyme in the actinomycete Frankia was recorded in the presence of nickel. Immunogold localisation analysis of the intracellular distribution of hydrogenase proteins indicated that they were evenly distributed in the membranes and cytosol of both hyphae and vesicles. In addition, molecular characterisation of the hydrogen-evolving enzyme at the proteomic level, using two-dimensional gel electrophoresis combined with mass spectrometry, confirmed that the Frankia hydrogen-evolving enzyme is similar to the cyanobacterial bidirectional hydrogenase of Anabena siamensis.     

Performance of thermostatic and electronic valves controlling the compressor capacity

The performance of the energy consumption of an electronic valve and a classical thermostatic valve has been compared when these expansion valves are adopted in a vapour compression plant subjected to a cold store. The main aim is to verify experimentally which type of expansion valve would be preferable from energy point of view when a classical thermostat or a fuzzy logic algorithm are used as the control system for the refrigeration capacity. The fuzzy logic‐based control is able to modulate continuously the compressor speed through an inverter. The results show that with a fuzzy algorithm, the thermostatic expansion valve allows an energy saving of about 8% in comparison with the electronic valve. When on–off control is used, the electric energy consumption obtained both with the electronic valve and with the thermostatic valve is comparable. Copyright © 2006 John Wiley & Sons, Ltd.     

Effect of surface waxes on the persistence of chlorpyrifos-methyl in apples, strawberries and grapefruits

The effects of the cuticle and epicuticular waxes of grapefruit, strawberry and apple on the photodegradation and penetration of chlorpyrifos-methyl were studied. Photodegradation experiments were conducted by exposing the insecticide to the light of a xenon lamp in the presence of a film of wax extracted from the fruit surface. The half-life of chlorpyrifos-methyl irradiated in absence of waxes was 9.6 min. The half-lives of pesticide irradiated in the presence of wax extracts of apple, grapefruit and strawberry were 83, 34 and 26 min, respectively. In penetration studies, fruit with and without wax layers were treated with an aqueous suspension of pesticide. The penetration of the pesticide from the cuticle to the pulp was measured after 24 h. Samples without wax contained a higher total amount of insecticide than those with wax. No pesticide was detected in samples of apple and grapefruit pulp. Residues were detected in all fractions of strawberry. The waxes and cuticle appear to have some effect on the photodegradation and penetration of chlorpyrifos-methyl in fruit samples.     

Dominant rock properties affecting the performance of conical picks and the comparison of some experimental and theoretical results

Conical picks are the essential cutting tools used especially on roadheaders, continuous miners and shearers and their cutting performance affects directly the efficiency and the cost of rock/mineral excavation. In this study, in order to better understand the effects of dominant rock properties on cutter performance, 22 different rock specimens having compressive strength values varying from 10 to 170 MPa are first subjected to a wide range of mechanical tests. Then, laboratory full-scale linear cutting tests with different depth of cut and cutter spacing values are realized on large blocks of rock specimens using one type of conical pick. Specific energy, cutting and normal force values for relieved and unrelieved cutting modes are recorded using a triaxial force dynamometer with capacity of 50 tonnes and a data acquisition system. Cutter force and specific energy values are correlated with rock properties and theoretical force and specific energy values obtained from widely used theoretical approaches.The results indicate that uniaxial compressive strength among the rock properties investigated is best correlated with the measured cutter performance values, which is in good agreement with previous studies. However, it is also emphasized in this study that Brazilian tensile strength, Schmidt hammer rebound values, static and dynamic elasticity modulus are also dominant rock properties affecting cutter performance.Theoretical specific energy defined by different researchers has a meaningful relationship with the experimental specific energy, which is an essential parameter for predicting the instantaneous cutting rates of mechanical excavation systems. It is also demonstrated that the experimental cutter forces obtained for 5 mm depth of cut are in good agreement with theoretical force values, if the friction angle between rock and cutting tool is included in the theoretical formulation. It is emphasized that, to some extend, laboratory tests can help to minimize high cost of a trial–error approach in the field.     

Tri-axial sensors and actuators made of a single piezoelectric cylindrical shell

Electromechanical transducers for sensing and actuating disturbances or vibrations have been used in many fields of applications. There have been transducers of different configuration developed for the unidirectional transduction. This paper demonstrates a single element transducer for tri-axial components made of a piezoelectric cylindrical shell. The separation of the tri-axial transductions is achieved by devising a proper electrode arrangement. The structure and the fundamental idea are first presented, and then the numerical analysis by means of the finite element modeling follows, and their characteristics and behaviors are then experimentally verified.     

A tree partitioning dynamic policy for OVSF codes assignment in wideband CDMA

This paper proposes some novel techniques to accommodate users with different rate requirements in a wideband code-division multiple-access system employing orthogonal variable spreading factor codes. Two simple static code assignment strategies are first considered, and an improvement based on multicode assignment. Then the new idea of tree partitioning is introduced and used to devise a dynamic code reassignment algorithm. The behavior of these different techniques is experimentally investigated, in terms of call blocking probability and number of required reassignments. The tree partitioning method exhibits very good performances.     

Ring‐opening polymerization of lactones initiated by diphenylzinc–coinitiator systems

Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in δ‐valerolactone polymerizations, although it was less efficient when used in the β‐butyrolactone and the β‐propiolactone polymerizations. Activity in the polymerization of β‐lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc–butanone combination was more effective than the diphenylzinc–water mixture in the polymerizations of β‐butyrolactone and β‐propiolactone. Copyright © 2003 Society of Chemical Industry