Recycling of glass in synthesis of MCM-48 mesoporous silica as catalyst support for Ni<Subscript>2</Subscript>O<Subscript>3</Subscript> photocatalyst for Congo red dye removal

Glass was successfully recycled in the synthesis of mesoporous silica MCM-48 which was used as catalyst support for nickel oxide photocatalyst. The resulted products were evaluated using X-ray diffraction, scanning electron microscope and UV–Vis spectrophotometer. The precipitated nickel oxide is of Ni₂O₃ form and loading of it onto MCM-48 resulted in a reduction in the band gap energy from about 3.66 eV to about 2.4 eV. The role of MCM-48 as catalyst support for Ni₂O₃ in enhancing the adsorption capacity and photocatalytic properties of nickel oxide was evaluated through series of equilibrium studies and photocatalytic degradation of Congo red dye under visible light. Using of glass-based MCM-48 as catalyst support for Ni₂O₃ showed enhancing the adsorption capacity by 31.3 and 14.8% higher than the adsorption capacity of Ni₂O₃ and MCM-48, respectively. Also, the photocatalytic degradation percentage increased by about 67.3% relative to the Ni₂O₃ degradation percentage. The nature of MCM-48/Ni₂O₃ adsorption mechanism is chemisorption and occurs in multilayer form throughout the heterogeneous surface of the composite. The using of MCM-48 as support for Ni₂O₃ photocatalyst enhanced the adsorption capacity through increasing the total surface area. The loading process resulted in fixing of the Ni₂O₃ particles throughout the porous structure which producing more exposed active photocatalyst sites and active adsorption sites for the incident photons as well as preventing the nickel oxide particles from agglomeration. Based on the obtained results, supporting of Ni₂O₃ particles onto MCM-48 is promising active centers for the degradation of Congo red dye molecules.     

Electrodes based on nano-tree-like vanadium nitride and carbon nanotubes for micro-supercapacitors

Vanadium nitride(VN) was deposited by DC-sputtering on a vertically aligned carbon nanotube(CNTs)template for the purpose of nano-structuration. This led to the fabrication of hierarchically composite electrodes consisting of porous and nanostructured VN grown on vertically aligned CNTs in a nano-treelike configuration for micro-supercapacitor application. The electrodes show excellent performance with an areal capacitance as high as 37.5 m F cm~(-2) at a scan rate of 2 mV s~(-1) in a 0.5 MK_2SO_4 mild electrolyte solution. Furthermore, the capacitance decay was only 15% after 20,000 consecutive cycles. Moreover,the capacitance was found to increase with VN deposit thickness. The X-ray photoelectron spectroscopy analyses of the electrodes before and after cycling suggest that the oxide layers that form at the VN surface is the responsible for the redox energy storage in this material. Such electrodes can compete with other transition metal nitride based electrodes for micro-supercapacitors.     

Extended Bayesian generalization model for understanding user’s intention in semantics based images retrieval

Multimedia Tools and Applications - Learning concepts from examples presented in user’s query and infer the other items that belong to this query is still a significant challenge for images...     

Adaptive motion/force control of uncertain nonholonomic mobile manipulator with estimation of unknown external force

This paper describes a stable adaptive motion/force control of uncertain nonholonomic mobile manipulator with the consideration of external force. As it is well known, unexpected external force makes the motion of the system unstable since there are no fixed points in the stationary coordinate. Here, a novel adaptive control scheme is utilized to estimate and compensate the unknown external force exerted to the end-effector even if the parameters of the system are uncertain. The important advantages of this approach are to achieve estimation without the requirement of force-sensing feedback and the knowledge of the system dynamic model. The update laws for the force and the parameters are derived from a Lyapunov function to guarantee the control system stability. Furthermore, a unified operational space dynamic formulation is presented to solve the problem of redundancy. As a result, the desired end-effector and platform trajectories are simultaneously tracked with a perfect coordination between the two subsystems. Therefore, the proposed controller proves that it can not only guarantee the stability, but also the tracking performance of the system in the task space. The effectiveness of the proposed algorithm is evaluated through extensive simulations and they demonstrate the stability, tracking trajectories and feasibility in estimating the external force and the dynamic uncertainties.     

Enhanced backstepping sliding mode controller for motion tracking of a nonlinear 2-DOF piezo-actuated micromanipulation system

Microsystem Technologies - In this paper a robust backstepping sliding mode controller is developed for tracking control of 2-DOF piezo-actuated micromanipulation system. The control approach is...     

Benchmarking large-scale data management for Internet of Things

The Journal of Supercomputing - In the current era of the Internet of Things (IoT), massive number of sensors are used in our daily lives. Sensors are everywhere around us. They exist in our homes,...     

Structural,Micromechanical and Tribological Characterization of Zn–Ni Coatings: Effect of Sulfate Bath Composition

Zn and Zn–Ni alloy coatings were electrodeposited on mild steel from sulfate-based bath containing Sn as additive. The effect of Ni content on the microstructure, morphology, microhardness and the tribological behavior of these coatings were studied and discussed. Adding Sn in the sulfate bath had a significant effect on the surface morphology, particularly on the Zn–8 wt% Ni coatings. By increasing the Ni concentration from 8 to 14 wt%, the X-ray patterns showed that the phase structure of Zn–Ni alloy coatings was changed from η-phase Ni₃Zn₂₂ to γ-phase Ni₅Zn₂₁. The plastic deformation and delamination were found to be wear mechanisms for the investigated coatings. While the Zn–14 wt% Ni alloys had the best wear resistance, Zn films had the most severe wear volume loss and the highest friction coefficient.     

CrowdOLA: Online Aggregation on Duplicate Data Powered by Crowdsourcing

Recently there is an increasing need for interactive human-driven analysis on large volumes of data. Online aggregation (OLA), which provides a quick sketch of massive data before a long wait of the final accurate query result, has drawn significant research attention. However, the direct processing of OLA on duplicate data will lead to incorrect query answers, since sampling from duplicate records leads to an over representation of the duplicate data in the sample. This violates the prerequisite of uniform distributions in most statistical theories. In this paper, we propose CrowdOLA, a novel framework for integrating online aggregation processing with deduplication. Instead of cleaning the whole dataset, CrowdOLA retrieves block-level samples continuously from the dataset, and employs a crowd-based entity resolution approach to detect duplicates in the sample in a pay-as-you-go fashion. After cleaning the sample, an unbiased estimator is provided to address the error bias that is introduced by the duplication. We evaluate CrowdOLA on both real-world and synthetic workloads. Experimental results show that CrowdOLA provides a good balance between efficiency and accuracy.     

Sectored Compact Space Reactor (SCoRe) concepts with a supplementary lunar regolith reflector

Design concepts of the Sectored Compact Space Reactor for Small power (SCoRe-S) have been developed for the avoidance of single-point failures in reactor cooling and energy conversion and a wide range of thermal powers. These modular, fast neutron spectrum, lithium cooled reactors with 16.0 cm thick BeO radial reflector are designed for at least +$2.00 hot-clean excess reactivity, and with a sufficient reactivity shutdown margin. They employ ¹⁵⁷GdN additives in the UN fuel and a 0.10 mm thick coating of ¹⁵⁷Gd₂O₃ on the outer surface of the reactor vessel to ensure that the bare reactors, when submerged in wet sand and flooded with seawater following a launch abort accident, remain at least ?$1.00 subcritical. In addition to identifying the smallest SCoRe-S concept that satisfies the design reactivity requirements, the benefit of using a lunar regolith as a supplementary reflector to decrease the thickness of the BeO radial reflector and hence, the launch mass of the SCoRe-S concepts for a lunar outpost is investigated. Calculations performed using MCNP5 confirmed that SCoRe-S₇ with a 16 cm thick BeO reflector is the smallest to satisfy the stated reactivity requirements. Results also show that a lunar regolith reflector alone is inadequate for this reactor to achieve a critical state at the beginning of life. However, when the regolith is used in conjunction with a BeO reflector of a reduced thickness, this reactor not only becomes critical, but also satisfies the reactivity design requirements at a significantly reduced launch mass. Using a supplementary reflector of regolith decreases the thickness of the BeO reflector for the SCoRe-S₇ from 16 cm to 8.0 cm, and to 5.7 cm for the SCoRe-S₁₁ of the largest core. The resulting decreases in the launch mass of the SCoRe-S concepts are ～34% or 150–200 kg.     

Frequency and Voltage Dependence of the Dielectric Properties of Ni/SiO 2 /P-Si (MOS) Structure

The frequency (10 - 107 Hz), temperature (303-363 K) or /and bias voltage (−2 to 2 V) dependence of the dielectric properties of