Charge/discharge characteristics of sulfur composite cathode materials in rechargeable lithium batteries

The charge and discharge characteristics of lithium batteries with sulfur composite cathodes have been investigated. The sulfur composites showed novel electrochemical characteristics. The analysis of the differential capacity indicated that the discharge process showed two voltage plateaus of 2.10 V and 1.88 V, and the charge process also presented two voltage plateaus of 2.22 V and 2.36 V. The overcharge test showed that the composite cannot be charged over 4.0 V, the voltage always stopped at about 3.9 V during charging, indicating that the composite presented the intrinsic safety for the overcharge of lithium batteries. The overcharge can cause serious safety problem for the conventional Li-ion batteries. The overcharge test also showed that the batteries with sulfur composite were destroyed when the upper cut-off voltage was over 3.6 V. However, the composite presented good reversible capacity after it was deep discharged even to 0 V. It showed stable cycleability and high cycling capacity of 1000 mAh g⁻¹ when cycling between 0.1 V and 3.0 V, indicative of the different characteristic from the conventional oxide cathode materials. The prototype polymer battery with the composite cathode material presented the energy density of 246 Wh kg⁻¹ and 401 Wh L⁻¹.     

大学生党支部建在班上的实践与思考

以漳州师范学院为例,总结了党支部建在班上的实践经验,并对大学生班级党支部的设置方式、工作模式和内涵建设进行了思考.     

基于复制技术的电力自动化系统容错模型的实现

从提高电力自动化系统的可靠性、安全性和实时性出发,在建立的基于复制技术的电力自动化系统容错模型的基础上,详细地介绍了系统模型的实现方法.设计的容错系统在三机表决系统的基础上,对系统结构和表决算法上进行了一定的改进,具有较强的容错性,为坚强、自愈的智能电网中的电力自动化系统的建设提供了参考意见.     

三氯甲烷萃取——毛细管气相色谱法测定维生素B12生产废水中的丙酸

维生素B12生产产生的废水中含有大量可回收的丙酸,对废水中丙酸的测定进行了研究,建立了测定丙酸的三氯甲烷萃取——气相色谱方法,方法的结果表明:检出限为5×10-2mg/L,精密度RSD为1.32%,加标回收率为97.2%—103.3%。     

Optimal operation of distillation processes under uncertain inflows accumulated in a feed tank

A new method of optimizing the operation of distillation processes with uncertain inflow streams from upstream plants is discussed. The case considered is the streams that will be first accumulated in a tank before feeding to the column. To minimize the total amount of operating energy while keeping a stable column operation under these inflows, a novel decomposed optimization strategy consisting of two steps was used. For an optimal planning of the dynamic operation, a smooth feed flow policy to the column is developed in the first step by stochastic optimization under chance constraints by ensuring a predefined probability of holding the tank level inside the desired range. An easy-to-use method developed computes the maximum reachable probability of holding the constraints so that a feasible solution of the chance constrained problem can be guaranteed. Since the uncertainty in the inflow stream variability is absorbed in the stochastic optimization over the tank, the operation of the dowstream distillation column is deterministic. Therefore, in the second step, the reflux and reboiler duty policies of the column are developed by deterministic dynamic optimization. The optimal overall strategy is obtained by the maximized smoothness of the feed flow to the distillation column. The approach is applied to a pilot column, and the developed operating policies are implemented on the real plant by experiment.     

原料预均化及其在优质矾土生产中的应用

原料预均化的基本原理为“平铺直取”．标准偏差和均化效果是考核均化过程的两个重要指标。标准偏差越小表示物料成分越均匀。原料预均化方式有多种，料仓式原料预均化库综合了各种方式的优点，它具有投资少，密封性好，占地面积小，无粉尘，操作条件和均化效果好等特点。     

Thermogravimetric analysis of methyl methacrylate‐graft‐natural rubber

The thermal degradations of methyl methacrylate‐graft‐natural rubber (MG) at different heating rates (B) in nitrogen were studied by thermogravimetric analysis. The results indicate that the thermal degradation of MG in nitrogen is a one‐step reaction. The degradation temperatures increase along with the increment of heating rates. The temperature of initial degradation (T₀) is 0.448B + 362.4°C, the temperature at maximum degradation rate, that is, the peak temperature on a differential thermogravimetric curve (T_p) is 0.545B + 380.7°C, and the temperature of final degradation (T_f) is 0.476B + 409.4°C. The degradation rate at T_p is not affected by B, and its average value is 48.9%; the degradation rate at T_f is not affected by B either, and its average value is 99.3%. The reaction order (n) is 2.1 and is not affected by B. The reaction activation energy (E) and the frequency factor (A) increase along with B, and the apparent reaction activation energy (E₀) is 254.6 kJ/mol. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2952–2955, 2002     

基于PWAS的层合板导波传播特性和损伤响应FEM分析及试验验证

导波无损检测（Non-Destructive Testing, NDT）技术由于适用范围广、检测速度快等优势,已成为结构安全性检测的重要技术手段之一。不过,导波在各向异性介质中的传播表现为频散特性与波传播方向的关联性、多模态特性与各向异性的相互作用以及不同模态与损伤的相互作用。导波在复合材料无损检测应用中的复杂性对检测技术和检测方法提出了更高的要求,所以对碳纤维复合材料层合板中的导波传播特性和损伤响应进行分析具有十分重要的意义。文中采用理论分析、仿真和试验相结合的方法,对不同碳纤维增强聚合物基（Carbon Fiber Reinforced Polymer, CFRP）层合板中的导波传播特性和各模态波与损伤的相互作用进行了分析。首先根据群速度、波长等参数建立有限元模型,并在边界设置阻尼递增吸收区域来弱化边界反射波的干扰;然后分析基于压电晶片有源传感器（Piezoelectric Wafer active Sensors, PWAS）的不同层合板中导波传播差异,之后在结构中引入损伤来分析不同模态波与不同损伤的相互作用;最后通过试验分析和验证有限元仿真的准确性。     

Expectation Maximization Algorithm for Time-delay Output-error Models Based on Finite Impulse Response Method

International Journal of Control, Automation and Systems - In this paper, an output error (OE) model with random time delay is identified by using the expectation maximization (EM) algorithm. Since...     

显著性的无人机远距离障碍物检测

针对旋翼无人机的避障问题,结合人眼视觉的显著性注意机制和HOG特征,提出一种实时的障碍物检测算法。该算法首先采用形态Haar小波分解的方法构建增强图像,然后根据增强图像的投影曲线提取出障碍物的候选区域。其后,对障碍物候选区域进行尺度归一化后提取HOG特征,并采用线性SVM分类器进行分类判别。该算法采用C++语言实现,在Celeron 2.3GHz处理器、2G内存的单板计算机上测试分辨率为640×480的VGA视频图像的处理速度约为14f/s。实验结果表明该算法满足无人机在低空环境下的障碍物的实时检测需求。