柴达木盆地西南部重力流沉积特征及其沉积模式研究

根据野外露头、岩心观察和测井分析,在柴西南古近纪发现浊流和碎屑流2种重力流沉积。碎屑流以湖底扇的形式发育于山前滨浅湖带;浊流以浊积扇形式发育于半深湖中,这2种重力流在盆缘交替沉积。该区重力流沉积分为陡坡欠补偿型和缓坡过补偿型,前者形成近岸湖底扇+碎屑流—浊积扇沉积组合,后者形成扇三角洲—浊积扇沉积组合。     

损伤变量对复合材料损伤演化过程的影响分析

复合材料层合板损伤模型中的刚度退化需要通过损伤变量来实现。针对通常采用的2种损伤变量定义,给出了统一表达式。此外,损伤刚度矩阵是损伤变量的函数,基于应变等效假设推导了三维损伤刚度矩阵,从而避免了对损伤刚度矩阵的人为假定。最后,通过复合材料层合板在冲击载荷作用下的数值模拟,讨论了损伤变量的2种定义对数值结果的影响,表明损伤变量的不同定义对分层和基体损伤分布存在一定的影响,对冲击载荷的影响不大。建议在复合材料损伤模拟中,应予关注损伤变量。     

生物拆分制备(S)-α-乙基-2-氧-1-吡咯烷乙酸工艺研究

耐酪氨酸冢村氏菌(Tsukamurella tyrosinosolvens)E105可选择性催化(R,S)-α-乙基-2-氧-1-吡咯烷乙酸乙酯生物拆分制备左乙拉西坦关键手性中间体(S)-α-乙基-2-氧-1-吡咯烷乙酸.通过单因素实验和响应面法对菌株产酶培养条件进行优化,并考察含酶静息细胞催化制备(S)-α-乙基-2-氧-1-吡咯烷乙酸的反应过程.结果表明:最优产酶培养条件为装液量30%,接种量4%,发酵36h;培养基组成为葡萄糖17.70g/L,酵母膏16.53g/L,NH4Cl 9.5g/L,K2HPO42g/L,KH2PO41g/L,NaCl 0.6g/L,MgSO4·7H2O 0.5g/L,初始pH值7.32.在优化条件下,酶活力为19.33U/g,细胞干重达4.13g/L,分别较优化前提高了32.6%和60.1%.当细胞加量为30g/L,底物浓度60mmol/L,反应体系为300mL,拆分24h后,产率和ee值分别为48%和99%,(S)-α-乙基-2-氧-1-吡咯烷乙酸浓度达28.8mmol/L,较优化前提高了32.1%.     

Dual-responsive shape memory hydrogels with self-healing and dual-responsive swelling behaviors

Shape memory hydrogels (SMHs) can fix the hydrogels in a provisional shape and restore the initial shape under external stimulation. Herein, a dual-responsive shape memory hydrogel with dual-responsive swelling and self-healing properties is presented in this work. The SMHs were fabricated by one-step emulsion copolymerization of acrylic acid (AAc), acrylamide (AAm) and stearyl methacrylate (SMA). Sodium alginate (SA) was introduced as an interpenetrating polymer in the network. With ionic cross-linking between -COO⁻ and Fe³⁺ or saline-reinforced hydrophobic association, the hydrogels can be fixed in a provisional shape, which can be restored by immersing the hydrogels in vitamin C solution or pure water, respectively. When the as-prepared hydrogels were immersed in FeCl₃ solutions, additional ionic cross-linking between Fe³⁺ and -COO⁻ could be formed, thus constructing the dual physically cross-linked (DPC) network, which endows the hydrogels with excellent fracture stress (2.6 MPa) and toughness (5.47 MJ/m³). Besides, the reversible physical cross-linkings endowed the hydrogel with outstanding self-healing capability. Furthermore, the pH and saline responsive swelling properties of the SMHs are additional fantastic properties. Therefore, we believe that this simple strategy provides a great opportunity for the preparation of SMHs with multiple intellectual performances.     

Fine grinding of thermoplastics by high speed friction grinding assisted by guar gum

High speed friction grinding has been used to grind plant and food substances in water but never been explored for grinding of thermoplastics like polylactic acid (PLA), low and high density polyethylene and polypropylene. Such grinding was investigated in this work and was made possible by using 0.5% guar gum solution instead of just water because increasing the viscosity of water reduced their settling and the speed of passing through the grinder. Tensile, flexural, and impact strengths of the plastics were studied and higher grinding efficiency of PLA could be explained by its low elongation-at-break compared to low density polyethylene, high density polyethylene, and polypropylene. The microplastics (2000–45 μm) were studied for mass and particle size distributions and by scanning electron microscopy, ¹³C CP/MAS NMR, Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. In addition, viscosity of guar gum and contact angles was measured. This new technology can produce finely ground microplastics (710–45 μm) for a variety of applications.     

Biosorption behaviors of Cu~(2 ),Zn~(2 ),Cd~(2 ) and mixture by waste activated sludge

1Introduction Waste activated sludge is the by-product of sewage treated by activated sludge process.According to incomplete statistic,in China sewage discharge amount is4.474×107m3/d[1],and there are more than100sewage treatment plants with different sc…     

小冲杆测试材料屈服载荷的有限元分析

文章通过ABAQUS有限元分析软件模拟小冲杆试验过程,重点分析2.25Cr1Mo、16MnR、20#、1.25Cr0.5Mo4种材料的小冲杆屈服载荷。试验结果表明,有限元模拟得到的材料屈服载荷与常规拉伸试验所得出的屈服强度存在显著的线性关系,并具有相当高的相关系数。为最终通过小冲杆试验评价材料的屈服强度提供了一条新的思路。     

熔铸法制造采煤机截齿的研究

介绍了熔铸法制造截齿的基本过程。所制截齿热处理后，沿粉末圆柱体齿头横截面上的硬度分布为：中心ＨＲＣ６８，过渡区６２，基体５５；结合层牢固，截齿的使用寿命增加。     

Ti(CN)基金属陶瓷微观组织的研究

用X－射线，电子探针及磁性测量等手段对Ti（CN）基金属陶瓷切削刀具的显微组织进行了系统分析，以瑞典山特维克同类刀具与国产刀具进行对比，发现国产刀具中Co-Ni粘结相中出现了无磁性的Ni3TiC相，从而降低了材料的磁饱和、矫顽磁力及抗弯强度。Ni3TiC的出现与烧结气氛有关，是烧结时材料脱碳的结果。文章对材料中的硬质相、粘结相等进行了微区成份定量分析，确认了各元素的分配状况。对于轻元素氮的分市则采用了X－射线波谱仪对刀具断面进行扫描，发现与国外名牌产品相比，国产刀具中氮的分布欠均匀。     

自锐性金刚石树脂砂轮磨削性能的研究

本文通过对比磨削试验，研究了自锐性金刚石(CSD)树脂砂轮的磨削性能。试验结果表明，由于CSD形状小规则，有许多凹入角和粗糙表面，树脂结合剂对CSD的把持力较普通金刚石强，所以在磨削各参数相同的条件下，自锐性金刚石砂轮与普通金刚石砂轮相比，其磨削比提高60％以上。且由于CSD的内部为许多单个亚晶粒所组成的镶嵌的颗粒，因此在应力作用下，只有很小的不规则的碎片崩掉，从而在每个颗粒的表面上留下许多新的小切削刃，故其加工工件的表面粗糙度值较低。