常压H2气氛烧结W-TiC合金的致密化行为和性能

采用粉末冶金方法在常压H2气氛下制备W-TiC合金,研究W-TiC合金的烧结致密化行为,并对合金的性能和组织结构进行分析.结果表明:添加微量强化烧结元素可改善W-TiC合金的烧结活性,在1700℃烧结120min后其相对密度达到99.2％;随着烧结温度的升高,W-TiC合金的拉伸强度提高,在2000℃烧结120 min...     

Influence of residual chirality on the conformation and enzymatic degradation of glycopolypeptide based biomaterials

Science China Technological Sciences - Glycopolypeptides as analogs of glycoproteins or glycosaminoglycans represent attractive building blocks for the construction of biomimetic biomaterials....     

基于中间件规范的容侵应用服务器研究与实现

针对现有的容忍入侵应用系统的构建需要针对不同的业务类型进行不同的个性化设计和开发以及系统或部件的可重用性较差的问题,在研究基于规范的容忍入侵中间件方法的基础上,提出了一种基于拦截器的容侵中间件模型,从逻辑上将系统分为容忍入侵服务提供者和容忍入侵服务管理者,可在满足既有规范情况下实现用户应用的业务逻辑与容忍入侵特性所依赖的非功能性服务的分离。对涉及的容忍入侵框架、容忍入侵策略组件、安全群组通信管理器、安全群组通信系统等进行了详细设计,在一个开源的J2EE应用服务器JBoss中实现了对容忍入侵功能的支持,可利用Java类加载机制完成容忍入侵服务的动态加载。     

Nanorod heterostructures showing photoinduced charge separation

Size- and shape-dependent property modifications of semiconductor nanocrystals have been a subject of intense interest because of their potential for future engineering devices. The bandgap and related optical-property tuning of these materials are mainly governed by the nature of their band edges. In addition, fusing one type of nanocrystal over another enables further control of material properties that are dependent on the relative alignments of their energy levels. On a molecular scale, the synthesis of supramolecular compounds has inspired advances in theories for photoinduced charge transfer. Heterostructured nanocrystals potentially provide a nanoscale analog of such systems. A method for preparing heterostructured nanocrystals of complex morphologies showing photoinduced charge separation is presented. It is shown that the energy and lifetime of the charge-transfer photoluminescence band can be tuned by changing the relative alignment of band edges in CdSe/CdTe heterostructure nanorods. The long-lived charge transfer states in these type II semiconductors may make them attractive for photovoltaic applications.     

Proactive multipath routing with a predictive mechanism in software‐defined networks

With the growth of network traffic volume, link congestion cannot be avoided efficiently with conventional routing protocols. By utilizing the single shortest‐path routing algorithm from link state advertisement information, standard routing protocols lack of global awareness and are difficult to be modified in a traditional network environment. Recently, software‐defined network (SDN) provided innovative architecture for researchers to program their own network protocols. With SDN, we can divert heavy traffic to multiple paths in order to resolve link congestion. Furthermore, certain network traffics come in periodic fashion such as peak hours at working days so that we can leverage forecasting for resource management to improve its performance. In this paper, we propose a proactive multipath routing with a predictive mechanism (PMRP) to achieve high‐performance congestion resolution. PMRP has two main concepts: (a) a proactive mechanism where PMRP deploys M/M/1 queue and traffic statistics to simulate weighted delay for possible combinations of multipaths placement of all subnet pairs, and leverage genetic algorithm for accelerating selection of optimized solution, and (b) a predictive mechanism whereby PMRP uses exponential smoothing for demand traffic volumes and variance predictions. Experimental results show a 49% reduction in average delay as compared with single shortest routing, and a 16% reduction in average delay compared with utilization & topology‐aware multipath routing (UTAMP). With the predictive mechanism, PMRP can decrease an additional 20% average delay. Furthermore, PMRP reduces 93% of flow table usage on average as compared with UTAMP.     

湘潭海泡石矿物学特征及提纯产物加工实验研究

湘潭海泡石矿属低品位沉积型非金属矿,具有较好的开发利用价值。为实现该海泡石矿资源的高效开发利用,采用化学多元素分析、粒度分析、光学显微镜分析、扫描电子显微镜分析等方法,进行了详细的矿物特性研究,并探究了海泡石选矿与应用建议。结果表明,随着粒度的降低,海泡石含量增加。方解石和石英呈颗粒状,海泡石呈束状集合体分布,且与其他矿物结合紧密。针对矿石性质,在确定了“筛分-化学分散-高速分散-分离”的原则工艺流程之后,进行了干燥和磨矿条件实验,进而获得了完整的沉积型海泡石提纯工艺流程。研究成果可为该海泡石矿石的开发利用提供技术支撑。     

In situ synchrotron X-ray diffraction analysis of deformation behavior of a Nb/NiTi composite for biomedical applications

The deformation behavior involved in Nb/NiTi composite for biomedical applications within a large macroscopic strain range was investigated by tensile loading-unloading test and in situ synchrotron X-ray diffraction(SXRD).Experimental results show that during loading,the Nb/NiTi composite experiences the elastic elongation of B2-NiTi austenitic,B19'-NiTi martensitic and β-Nb phases,B2→ B19' stress-induced martensitic(SIM) transformation and tensile plastic deformation of β-Nb phase.During unloading,the deformation behavior involved in Nb/NiTi composite includes the elastic recovery of B2-NiTi austenitic,B19'-NiTi martensitic and β-Nb phases,reverse phase transformation B19'→B2 and compressive deformation of p-Nb phase.The martensitic transformation in this composite is almost reversible and occurs in a localized manner.These results might contribute to a comprehensive understanding of the deformation mechanism involved in Nb/NiTi composite and shed some light on design and development of novel composites with a combination of good biocompatibility and excellent superelasticity for biomedical applications.     

基于多目标混料设计的重介质旋流器混料成分配比

为了准确掌握重介质旋流器各混料成分之间的配比关系,明确不同配比对旋流器产出质量和产量的影响,实现分选效果的最优化.分析了现有旋流器优化和混料配比研究的不足,探讨了采用混料设计方法解决上述问题的可行性和局限性。通过设计混料试验,运行试验得到试验结果,建立混料成分与各响应变量的数学模型,分析模型的有效性,以各响应变量的同时最佳为综合约束条件进行响应优化,通过求解苛求函数复合合意度最高时的各参数值,确定各混料成分的最优配比,并通过T假设检验验证试验结果用于生产的有效性。结合某选煤厂旋流器生产运行情况,明确旋流器中块煤、悬浮液和煤泥各混料的水平要求,采用极端顶点法设计混料试验并运行试验,建立三因子与精煤灰分和产率两个响应变量之间的回归模型,分析两响应变量同时最佳条件下最优的混料配比,得到三混料成分配比依次为15.5%、59.8%、24.7%,依据上述配比进行试生产,并采用T检验验证试验结果是有效的,从而为选煤厂高效生产和精确控制提供有效的支撑,也为后期实现自动化控制提供了可能。     

四川盆地中部中二叠统热液白云岩储渗空间类型及成因

近年来,四川盆地川西北地区有多口井在中二叠统栖霞组、茅口组钻获高产气流,展现出该层系巨大的天然气勘探潜力,但有关该盆地中二叠统白云岩储层的成因机理则众说纷纭,一直未达成共识。为此,基于川中地区栖霞组、茅口组岩心及薄片等岩相学特征,以及碳、氧、锶同位素和包裹体均一化温度等地球化学特征,开展了中二叠统热液白云岩储渗空间类型及储渗相特征研究,分析了白云岩储层的成因及其控制因素。结果认为:(1)茅口组、栖霞组石灰岩地层经历了构造控制热液活动,发育萤石、鞍状白云石、天青石的热液矿物组合和膨胀角砾结构;(2)较之于宿主石灰岩,细—中晶云岩和鞍状白云石均呈现出δ18O负偏移、87Sr/86Sr正偏移;(3)中二叠统形成由热液溶孔、热液白云岩晶间孔、热液溶洞、热液扩溶缝等4种储渗空间构成的热液白云岩储渗体。结论认为:(1)热液白云岩储集相发育和分布受深大断裂的控制,呈"透镜状"分布在具"下凹"地震反射特征的区域;(2)中二叠统热液白云岩储集相与下伏烃源岩和上覆封堵层的有机组合可构成有利的天然气勘探目标。     

Sub‐Millimeter‐Scale Monolayer p‐Type H‐Phase VS2

2D H‐phase vanadium disulfide (VS₂) is expected to exhibit tunable semiconductor properties as compared with its metallic T‐phase structure, and thus is of promise for future electronic applications. However, to date such 2D H‐phase VS₂ nanostructures have not been realized in experiment likely due to the polymorphs of vanadium sulfides and thermodynamic instability of H‐phase VS₂. Preparation of H‐phase VS₂ monolayer with lateral size up to 250 µm, as a new member in the 2D transition metal dichalcogenides (TMDs) family, is reported. A unique growth environment is built by introducing the molten salt‐mediated precursor system as well as the epitaxial mica growth platform, which successfully overcomes the aforementioned growth challenges and enables the evolution of 2D H‐phase structure of VS₂. The honeycomb‐like structure of H‐phase VS₂ with broken inversion symmetry is confirmed by spherical aberration‐corrected scanning transmission electron microscopy and second harmonic generation characterization. The phase structure is found to be ultra‐stable up to 500 K. The field‐effect device study further demonstrates the p‐type semiconducting nature of the 2D H‐phase VS₂. The study introduces a new phase‐stable 2D TMDs materials with potential features for future electronic devices.