Structural characterizations of diglycerol monomyristate reverse micelles in aromatic solvent ethylbenzene

Using small-angle X-ray scattering (SAXS) we have investigated the shape and size of diglycerol monomyristate (designated as C14G2) nonionic surfactant reverse micelles in aromatic solvent ethylbenzene as a function of surfactant concentration, temperature, and water. When C14G2 is added into ethylbenzene globular type reverse micelles with maximum core diameter ca. 4.5 nm are formed under ambient conditions. The micellar structure (shape and size) did not change with the surfactant concentration. However, an increase in temperature decreased the micellar size due to an increase in the critical packing parameter (cpp). Surfactant becomes more lipophilic upon heating and the micellar curvature tends to become more negative at higher temperature. Addition of a small amount of water caused a significant micellar growth. For instance, incorporation of 0.3% water in the 5% C14G2/ethylbenzene system resulted in the formation of 2.1 time bigger micelles with a small water pool in the micellar core. Besides the micellar shape is modified into an ellipsoidal prolate, whose scenario can be understood in terms of hydration of the surfactant's headgroup. Hydration decreases the cpp and favors micellar growth. An increase of temperature of a water incorporated system decreased the micellar size due to dehydration, which is equivalent to rod-to-sphere type transition.     

How much hope should we have for biofuels?

This paper revisits the recent developments in biofuel markets and their economic, social and environmental impacts. Several countries have introduced mandates and targets for biofuel expansion. Production, international trade and investment have increased sharply in the last few years. However, some analysts linked biofuels to the 2007-2008 global food crisis. Existing studies diverge on the magnitude of the projected long-term impacts of biofuels on food prices and supply, with studies that model only the agricultural sector showing higher impacts and studies that model the entire economy showing relatively lower impacts. In terms of climate change mitigation, biofuels reduces GHG emissions only if GHG emissions related to land-use change are avoided. When biofuel production entails conversion of forest to cropland, net reduction of GHG would not be realized for many years. Existing literature does not favor the diversion of food for large-scale biofuels production, but the regulated expansion of biofuels in countries with surplus lands and a strong biofuel industry cannot be ruled out. Developments in non-food based or cellulosic (or second generation) biofuels may offer some hope, yet they still compete with food supply through land use and are currently constrained by a number of technical and economic barriers.     

An assessment by subsistence farmers of the risks to food security attributable to climate change in Makwanpur,Nepal

The potential impacts of climate change on the food security of subsistence farmers is a serious concern. This article explores the food security situations of two categories of subsistence farm households, vegetable- and cereal-based farming systems, in the Makwanpur district of Nepal in the context of climate change. Local climate data for the past 30 years were analyzed. Interviews with local farmers and key informants, and focus group discussions were carried out to collect the primary data. Empirical data showed that changes in climate variables for the study period were in line with farmers’ perceptions and that farming communities were negatively impacted. Perceived impacts were erratic rainfall, increased frequency of floods and droughts, soil degradation and insect pests, weeds and diseases. Farmers have modified traditional cropping patterns and calendar, changed crop varieties and increased fertilizer and pesticide applications in order to maintain crop yields. They have also sought off-farm employment. However, agricultural productivity in the area is declining and only one third of all households in the area were food secure. Household food insecurity was at mild to moderate levels, but vegetable-based households were more secure than cereal-based ones. At the household level, locally successful adaptive measures, such as rainwater harvesting, mulching, planting date adjustments, off-farm opportunities, including infrastructure and extension support, could increase production and contribute to reversing the impact of increased risk attributed to climate change.     

Highly active Zr co-doped Ag–ZnO photocatalyst for the mineralization of Acid Black 1 under UV-A light illumination

The Zr co-doped Ag–ZnO (Zr–Ag–ZnO) was successfully synthesized by precipitation–decomposition method. The photocatalytic activity of Zr–Ag–ZnO was investigated for the degradation of Acid Black 1 (AB 1) in aqueous solution using UV-A light. Co-dopants shift the absorbance of ZnO, both in UV and visible region. Zr–Ag–ZnO is found to be more efficient than Ag–ZnO, Zr–ZnO, commercial ZnO, prepared ZnO, TiO₂–P25 and TiO₂ (Merck) at pH 9 for the mineralization of AB 1 under UV-A light. The influence of operational parameters such as the amount of photocatalyst, dye concentration, initial pH on photo mineralization of AB 1 has been analyzed. The mineralization of AB 1 has been confirmed by COD measurements. Mechanism of degradation by Zr–Ag–ZnO is proposed. The catalyst is found to be reusable.     

Assurance of energy efficiency and data security for ECG transmission in BASNs

With the technological advancement in body area sensor networks (BASNs), low cost high quality electrocardiographic (ECG) diagnosis systems have become important equipment for healthcare service providers. However, energy consumption and data security with ECG systems in BASNs are still two major challenges to tackle. In this study, we investigate the properties of compressed ECG data for energy saving as an effort to devise a selective encryption mechanism and a two-rate unequal error protection (UEP) scheme. The proposed selective encryption mechanism provides a simple and yet effective security solution for an ECG sensor-based communication platform, where only one percent of data is encrypted without compromising ECG data security. This part of the encrypted data is essential to ECG data quality due to its unequally important contribution to distortion reduction. The two-rate UEP scheme achieves a significant additional energy saving due to its unequal investment of communication energy to the outcomes of the selective encryption, and thus, it maintains a high ECG data transmission quality. Our results show the improvements in communication energy saving of about 40%, and demonstrate a higher transmission quality and security measured in terms of wavelet-based weighted percent root-mean-squared difference.     

Flavonoid glycosides from cowpea seeds (Vigna sinensis K.) inhibit LDL oxidation

Six flavonoid glycosides were isolated from the n-butanol fraction of cowpea seeds (Vigna sinensis K.) through silica gel (SiO₂) and octadecyl silica gel (ODS) column chromatographies. Based on their chemical structures determined via interpretation of spectroscopic data including NMR, MS, and IR, the compounds were identified as kaempferol 3-O-β-d-sophoroside (1), quercetin 3-O-β-d-sophoroside (2), isoquercitrin (3), hyperin (4), catechin 7-O-β-d-glucopyranoside (5), and quercetin 3-O-β-Dglucopyranosyl( 1→6)-O-β-d-galactopyranoside (6). This is the first report of the isolation of these flavonoids from this plant. Among these flavonoids, compound 2, 5, and 6 significantly inhibited LDL oxidation exhibiting 96.0±0.1 (IC₅₀: 3.9 μM), 96.8±1.7 (IC₅₀: 2.9 μM), and 97.4±0.1% (IC₅₀: 3.5 μM) inhibition, respectively, at a concentration of 40 μM.     

Photovoltaics literature survey (no. 92)

In order to help keep readers up‐to‐date in the field each issue of Progress in Photovoltaics will contain a list of recently published journal articles most relevant to its aims and scope. This list is drawn from an extremely wide range of journals, including IEEE Transactions on Electron Devices, Journal of Applied Physics, Applied Physics Letters, Progress in Photovoltaics and Solar Energy Materials and Solar Cells. To assist the reader, the list is separated into broad categories, but please note that these classifications are by no means strict. Also note that inclusion in the list is not an endorsement of a paper's quality. If you have any suggestions please email Santosh Shrestha at s.shrestha@unsw.edu.au.