Supercritical hydrothermal synthesis of organic-inorganic hybrid nanoparticles

We have developed supercritical hydrothermal synthesis method of metal oxide nanoparticles where metal salt aqueous solution is mixed with high temperature water to rapidly increase the temperature of the metal salt solution and thus reduce the reactions and crystallizations during the heating up period. By using this method, we succeeded in the continuous and rapid production of metal oxide nanocrystals. A new method proposes to synthesize organic-inorganic fused materials based on the methods of supercritical hydrothermal synthesis. By introducing organic materials in a reaction atmosphere of supercritical hydrothermal synthesis, we successfully synthesized metal oxide nanoparticles whose surface was modified with organic materials. In supercritical state, water and organic materials form a homogeneous phase, which provides an excellent reaction atmosphere for the organic modification of nanoparticles. Modification with bio-materials including amino acids was also possible. By changing organic modifiers, particle morphology and crystal structure were changed. This organic surface modification provides a various unique characteristics for the nanoparticles: Dispersion of nanoparticles in aqueous solutions, organic solvents or in liquid polymers can be controlled by selecting hydrophilic or hydrophobic modifiers.     

Adaptive backstepping control of wheeled inverted pendulum with velocity estimator

In this paper, we introduce a backstepping control design of a wheeled inverted pendulum. Based on a second-order motion equation of the body angle, an adaptive integral backstepping controller is designed to stabilize the body angle. It is shown that the σ-modification rule in the adaptive update law guarantees the boundedness of the errors in estimating the time-varying signal that is an output of a linear system with every bounded input signal. Then, the stabilizing controller for the wheel angle is constructed by a PD-type positive feedback. The derived controller requires the full-state measurements. In the output feedback case, the K filter or the observer backstepping is needed. However, the structure of the controller becomes complicated. We propose a non-model-based differentiator based on the adaptive update law. Since the non-model-based differentiator does not require any knowledge of the dynamic structure of the signal, we can use it as a velocity estimator for unknown nonlinear systems. Therefore, we replaced the velocity measurement with the estimates by the non-model-based differentiator. Finally, simulation results for the proposed controller are presented.     

高速公路膨胀土地段路基施工技术

针对青岛—红其拉甫公路鲁冀界至邯郸段高速公路膨胀土实际工程,对典型膨胀土路段的膨胀土进行了物理力学性质指标试验,评价了该段膨胀土的的工程特性,并提出了膨胀土的处理、设计与施工方案,对指导膨胀土路基的设计与施工具有重要的意义。     

制药工程工艺设计课程教学改革的探索

制药工程工艺设计是制药工程专业的必修课程,本文围绕课程的建设,分析制药工程专业教学中存在的具体问题,结合学校培养应用性技术人才的特色,对教学内容、教学方法和教学手段进行探索和改革,旨在培养学生具备完整的制药工程工艺设计理念和初步的工艺设计能力,满足社会对应用型人才的需要。通过对该课程的教学改革,已经取得了不错的教学成果。     

凝胶色谱在腈纶溶剂净化工艺中的应用

根据凝胶色谱的工作原理,介绍了凝胶色谱在腈纶聚合原液除杂、腈纶纺丝溶剂除铁、腈纶废水预处理等三个方面的应用。实践表明:凝胶色谱即使长期使用也无需用化学试剂再生,使用寿命比离子交换树脂更长,是一种比较理想的溶剂净化手段。     

基于异或自反性与射频指纹的无线组播密钥生成方法

随着物联网技术的发展, 组播通信的需求日益增大。异或加密作为最简单高效的加密方法之一, 在信息安全方面有着广泛的应用。本文针对组播通信安全需求, 设计了一种基于异或自反性和射频指纹的组密钥生成方法。为解决多个终端在密钥生成过程中的传输资源选择冲突问题, 提出基于扩频和公私钥密码体系的用户标识方法。先利用射频指纹对用户认证, 并在组播用户间形成密钥随机源; 然后, 利用异或的自反特性实现分布式密钥生成。将射频指纹与公私钥密码体系结合, 不仅为射频指纹的识别结果提供了参考, 还为组播通信下密钥协商时的通信资源选择提供了方法。为评估射频指纹识别的影响, 提出并实验验证了一种基于时频分析与深度学习的射频指纹识别算法。最后, 分析了所提方法的密钥生成率、资源选择冲突和密钥生成效率,展示了所提方法的可行性和有效性。分析发现所提方法相比于传统方法, 分布式的密钥源使得密钥生成效率随着节点数的增大而提高。对组密钥被攻破概率的窃听模型仿真结果表明, 在生成同样长度的密钥时, 与遍历搜索密钥空间比较, 基于窃听者遍历搜索设备射频指纹特性的条件, 破解所提方法组密钥的复杂度要高出一至四个数量级, 验证了本文方法的安全性。     

一种提高802.11无线Ad Hoc网络公平性的新机制-FFMA

实现多个数据流对无线信道的公平共享是802.11无线Ad Hoc网络中的一个重要议题,但802.11DCF机制在无线Ad Hoc网络中存在严重的公平性问题,甚至有可能出现单个节点或数据流独占信道而其他节点和数据流处于"饥饿"状态的情况.论文提出了一种新颖的保证数据流间公平性的MAC层接入机制FFMA(Flow rate-based Fair Medium Access),通过公平调度和公平竞争的方式,FFMA能够在数据流间公平地分配信道带宽资源.仿真结果表明,在无线Ad Hoc网络中,FFMA可以在保证信道吞吐量的前提下取得远优于802.11 DCF的数据流间的公平性.     

齿啮式快开压力容器整体有限元塑性载荷分析

通过接触单元来数值模拟啮合齿的接触过程，建立了基于整体有限元分析的齿啮式快开压力容器塑性载荷计算方法。大量实际设计和工程应用表明，按该方法设计的容器满足结构强度和寿命要求。     

亚硝基血红蛋白和红曲红联合使用对红肠颜色和品质的影响

研究了亚硝基血红蛋白和红曲红联合使用对红肠品质特性的影响。实验共分为4组,分别为对照组(添加120mg/kg亚硝酸钠),添加1g/kg的亚硝基血红蛋白和100mg/kg的红曲红复配组、添加2g/kg的亚硝基血红蛋白组、添加1g/kg亚硝基血红蛋白和60mg/kg的亚硝酸钠组。测定红肠在0、3、7、10、15d的色差、亚硝酸盐残余量、pH、硫代巴比妥酸反应物值(TBARS)、菌落总数和感官评价。结果显示,亚硝基血红蛋白和红曲红联合使用,可以显著增加红肠红度值,降低红肠的菌落总数以及亚硝酸含量。这表明两者联合使用可以改善红肠的颜色和品质。     

光子晶体光纤的基本特性与应用

光子晶体光纤(PCF)独特的结构和导模机制使它具有了许多普通光纤所不具备的优越特性。根据不同的导模机理,分别论述了基于全内反射和光子禁带效应导光的光子晶体光纤的损耗、色散、非线性等基本特性,并探讨了它们的重要应用价值和发展前景。