Vapor Phase Growth of Centimeter-Sized Band Gap Engineered Cesium Lead Halide Perovskite Single-Crystal Thin Films with Color-tunable Stimulated Emission

Single crystal metal halide perovskites thin films are considered to be a promising optical, optoelectronic materials with extraordinary performance due to their low defect densities. However, it is still difficult to achieve large-scale perovskite single-crystal thin films (SCTFs) with tunable bandgap by vapor-phase deposition method. Herein, the synthesis of CsPbCl_3(1–x)Br_3x SCTFs with centimeter size (1 cm × 1 cm) via vapor-phase deposition is reported. The Br composition of CsPbCl_3(1–x)Br_3x SCTFs can be gradually tuned from x = 0 to x = 1, leading the corresponding bandgap to change from 2.29 to 2.91 eV. Additionally, an low-threshold (≈23.9 µJ cm⁻²) amplified spontaneous emission is achieved based on CsPbCl_3(1–x)Br_3x SCTFs at room temperature, and the wavelength is tuned from 432 to 547 nm by varying the Cl/Br ratio. Importantly, the high-quality CsPbCl_3(1–x)Br_3x SCTFs are ideal optical gain medium with high gain up to 1369.8 ± 101.2 cm⁻¹. This study not only provides a versatile method to fabricate high quality CsPbCl_3(1–x)Br_3x SCTFs with different Cl/Br ratio, but also paves the way for further research of color-tunable perovskite lasing.     

Recent Progress of Bismuth Effect on All-Inorganic Lead-Free Metal Halide Derivatives: Crystals Structure,Luminescence Properties,and Applications

Bismuth (Bi³⁺)-included lead-free metal halide (LFMH) materials attract much attention in lighting, display, photodetectors, X-ray detectors, and photovoltaic fields, due to the tunable luminescence and optoelectronic performance in response to crystal and electronic structure, morphology, and particle sizes. This review summarizes Bi³⁺-included LFMH materials about their preparation approach, crystal and electronic structure properties, luminescence performance, and emerging applications. Notably, Bi³⁺ ions not only can act as framework cation to construct stable LFMH structure, but can also incorporate into LFMH materials as activators or sensitizers to generate remarkable luminescence tuning and band engineering. The Bi³⁺ effect on the luminescence and optoelectronic properties of LFMH materials, including, promotion of exciton localization, enhancement of light absorption in near-ultraviolet region, action as sensitizer ions to transfer energy to rare earth or transition metal ions and emission of highly-efficient light is systematically summarized. The proposed structure-luminescence relationship offers guidance for the optimization of current Bi³⁺-included LFMH materials and the exploitation of new LFMH derivatives.     

Diamond semiconductor and elastic strain engineering

Diamond,as an ultra-wide bandgap semiconductor,has become a promising candidate for next-generation microelec-tronics and optoelectronics due to its numerous advantages over conventional semiconductors,including ultrahigh carrier mo-bility and thermal conductivity,low thermal expansion coefficient,and ultra-high breakdown voltage,etc.Despite these ex-traordinary properties,diamond also faces various challenges before being practically used in the semiconductor industry.This review begins with a brief summary of previous efforts to model and construct diamond-based high-voltage switching diodes,high-power/high-frequency field-effect transistors,MEMS/NEMS,and devices operating at high temperatures.Following that,we will discuss recent developments to address scalable diamond device applications,emphasizing the synthesis of large-area,high-quality CVD diamond films and difficulties in diamond doping.Lastly,we show potential solutions to modulate diamond’s electronic properties by the“elastic strain engineering”strategy,which sheds light on the future development of diamond-based electronics,photonics and quantum systems.     

基于卡口上下文和深度置信网络的车辆轨迹预测模型研究

针对车辆轨迹预测中节点序列的时序特性和实际路网中的空间关联性,该文提出一种基于深度置信网络和SoftMax (DBN-SoftMax)轨迹预测方法.首先,考虑到轨迹在节点集合中的强稀疏性和一般特征学习方法对新特征的泛化能力不足,该文利用深度置信网络(DBN)较强的无监督特征学习能力,达到提取轨迹局部空间特性的目的;然后,针对轨迹的时序特性,该文采用逻辑回归的预测思路,用当前轨迹集在路网特征空间中的线性组合来预测轨迹;最后,结合自然语言处理领域中的词嵌入的思想,基于实际轨迹中节点存在的上下文关系,运用节点的向量集表征了节点间的交通时空关系.实验结果表明该模型不仅能够有效地提取轨迹特征,并且在拓扑结构复杂的路网中也能得到较好的预测结果.     

Callback回调技术在数字化城管部件在线更新系统中的应用

通过分析.net中的CallBack回调技术和已有的基于ArcGIS Server构建的WebGIS系统的三层体系结构,结合数字化城管部件在线更新的系统的开发实例,搭建了一套多层体系结构和.net的CallBack回调技术相结合的体系框架,事实证明此框架有效的降低了服务器的负载,实现了页面异步调用和无刷新的局部显示,提升了用户体验。     

一种基于GIS动态服务技术的Agent迁移策略

针对现有分布式地理信息系统数据处理的瓶颈问题,利用Web服务和移动Agent技术解决GIS领域的动态服务问题,详细阐述GIS软件的系统结构和动态服务模型,介绍移动Agent和构件服务等相关实现技术,给出基于智能决策的Agent迁移策略及其算法描述.最后通过模拟仿真实验,验证了该迁移策略和算法的有效性.     

星上一体化电子系统的FDIR框架设计与研究

传统的卫星往往要在硬件设计开发后,才能针对具体硬件平台进行星载故障检测隔离恢复(FDIR)设计,这就使得整个卫星系统开发周期增长,FDIR软件也无法重用.首先分析了星上故障检测隔离和恢复的特殊性和必要性,在概述FDIR的基本概念、相关技术方法以及卫星数据模型(SDM)平台的基础上,提出了一个基于SDM平台的星上一体化综合电子系统FDIR框架,既克服传统卫星针对"一星一平台"的FDIR设计,又能方便整星的信息融合,提高FDIR能力.     

The Cournot game under a fuzzy decision environment

The conventional precision-based decision analysis methodology is invalid for business decision analysis when precise assessment data seldom exist. This paper considers the Cournot game with fuzzy demand and fuzzy costs that are assumed to be triangular fuzzy numbers. Our model utilizes the weighted center of gravity (WCoG) method to defuzzify the fuzzy profit function into a crisp value. We derive the equilibrium Cournot quantity of each firm by simultaneously solving the first-order condition of each firm. Our model explicitly derives the necessary condition to avoid an unreasonable outcome of negative equilibrium quantities and lack of flexibility for modification of the ranking method. In addition, we examine the standard deviation of the fuzzy profit resulting from the fuzziness of each firm’s cost and market demand functions. We conduct sensitivity analysis to investigate the effect of parameter perturbations on firms’ outcomes. The results indicate that the center of parameter plays an important role in sensitivity analysis and dominates over variations in equilibrium quantity due to a perturbation of fuzzy parameters.