负载化非茂单活性中心催化剂乙烯聚合的研究

在硅胶上负载了双(N-环己基-3-叔丁基水杨醛亚胺基)二氯化锆配合物,得到负载化非茂单活性中心催化剂。该催化剂用于乙烯聚合,考察了配合物用量、共聚单体1-己烯用量、聚合温度、聚合压力、聚合时间、三乙基铝用量对乙烯聚合性能的影响及对聚合物的相对分子质量、相对分子质量分布、熔体流动指数和密度的影响。实验结果表明,负载化非茂单活性中心催化剂保持了原均相催化剂的乙烯聚合性能;该催化剂在淤浆聚合工艺中聚合平稳,所得聚合物的颗粒形态良好。     

中原油田水平井钻井液技术

根据中原油田地层高温、高盐、易塌、易漏失及水平井的特点,优选了适用于水平井的强抑制强封堵聚合物钻井液体系,并进行了现场应用.室内实验结果表明,优选的强抑制强封堵聚合物钻井液具有良好的井眼净化、摩阻控制、井壁稳定及油层保护等性能.现场应用时能满足钻井、录井、测井的需要,钻井施工顺利,取得了良好的经济和社会效益.     

黄河下游滩区居民对安全的心理需求

黄河下游滩区居民对自身安全的需求非常强烈，具体表现在以下3个方面：对房屋采取垫高房台等安全措施，出于安全的原因愿意搬离现居住地，较高生育率与偏好男孩。他们建立在安全需求上的相应行为，增大了生活成本，影响着他们生存发展的空间，进而制约着滩区社会经济的发展。     

沉积物源的综合识别与岩性圈闭的确定——以柴达木盆地七个泉地区为例

 柴达木盆地西部南区的阿尔金山前带是寻找岩性地层油气藏的有利地区。但该区沉积物源多、砂层薄，仅用常规的、单一的方法难以取得岩性地层油气藏勘探的效果。本文通过建立层序地层格架确定寻找岩性油气藏的主要目的层段，应用重矿物组分、测井响应、波阻抗反演等多种方法进行沉积物源和岩性圈闭的综合识别，在柴达木盆地西部南区七个泉构造斜坡带上确定一个地层岩性圈闭，已获得钻探的证实。     

基于GPRS网络传输的雨水情遥测传输系统设计

远程雨水情遥测是现代化水利工程系统中一个重要环节,特别是在山洪地质灾害预警系统中,能准确及时掌握雨水情数据,为预警预报、合理决策、指挥调度提供了可靠的依据。文章介绍了一种利用GPRS网络传输,以PIC16C74单片机为核心的雨水情遥测设备,并给出了相关的硬件接口电路连接以及软件实现方法。     

Oxygen glow discharge experiment to remove deposited layers and to release trapped hydrogen isotopes in HT-7 superconducting tokamak

An experiment to remove re-deposited layers and to release hydrogen using a glow discharge in oxygen (O-GDC) has been performed in the HT-7 superconducting tokamak. In the absence of magnetic fields, the O-GDC wall conditioning had produced rapid, controlled co-deposit removal. Average removal rates, 5.2 × 10²² H-atoms/h, 5.65 × 10²¹ D-atoms/h and 5.53 × 10²² C-atoms/h, respectively, were obtained during 145 min O-GDC experiment in the pressure range 0.5-1.5 Pa. The corresponding removal rate of co-deposited films was ∼1.19 μm/day (26.5 g/day for carbon) based on an area of 12 m². Compared to thermo-oxidation and O-ICR experiment, high pressure O-GDC wall conditioning promoted the oxidation and improved the C and D atoms removal. In the O-GDC experiment, the removal rates of H-atoms and D-atoms as H₂O, HDO and D₂O were higher than that of H₂ and D₂ by factors of about 20 and 50, respectively. During the 145 min O-GDC experiment, about 14.5% O-atoms were converted into carbon oxides and hydroxides, and about 5.37 × 10²² O-atoms were adsorbed on the walls corresponding to a coverage of 4.5 × 10²¹ O/m² on an wall area of 12 m². In a 100 min helium glow discharge (He-GDC) following the O-GDC experiment, 1.53 × 10²² O-atoms, about 28.5% oxygen retained on the walls, were removed. The removal rate of H-atoms in He-GDC cleaning after O-GDC experiment was lower than that in He-GDC cleaning before O-GDC experiment, which indicates that the O-GDC wall conditioning had effectively reduced hydrogen retention on the walls.     

Inference and learning in hybrid probabilistic network

This paper proposed a novel hybrid probabilistic network, which is a good tradeoff between the model complexity and learnability in practice. It relaxes the conditional independence assumptions of Naive Bayes while still permitting efficient inference and learning. Experimental studies on a set of natural domains prove its clear advantages with respect to the generalization ability.     

Matrix partial fraction expansions of rational matrices

A general and rigorous derivation is made of a new formula, established recently in the literature, for matrix partial fraction expansion of a rational matrix. The procedure, by use of a minimal Jordan realization of the rational matrix, provides as a byproduct, general expressions for residue matrices in terms of products of columns of the output matrix and rows of the input matrix of the realization.     

Use of Fiber Bragg Grating Sensors for Determination of a Simply Supported Rectangular Plane Plate Deformation

A measurement method has been developed to determine the full-field deformation of a simply supported plane plate under transverse load. The method utilizes strain information provided by a set of four fiber Bragg grating sensors mounted on the plate in a way that all sensors measure strains along one certain direction. The sensors were interrogated using a wavelength swept fiber laser. Utilizing the strain information and the first four terms of Navier solution of simply supported rectangular plate, the necessary parameters for determining the deflection could be computed. By substituting the values of x- and -y- coordinates of each position on the rectangle plate, the full-field deformation information can be obtained. Single-point loading tests were experimentally performed to verify the accuracy of the method.     

Mass transfer kinetics of neodymium(III) extraction by calix[4]arene carboxylic acid using a constant interfacial area cell with laminar flow

BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (K_ao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (E_a) was calculated to be 21·41 kJ mol^?1 or 88·17 kJ mol^?1 (dependent on temperature) from the slope of log K_ao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (C_min) is lower than 4·19 × 10^?4 mol L^?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd³⁺]_(a)/dt = k_f[Nd³⁺]_(a)[H₄A]_(o)^0·727[H⁺]_(a)^?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry