pH/ORP测量应用中的问题解析

1 pH／ORP测量系统的组成 一个完整的测量系统包括pH／ORP电极、保护测量电极的安装支架和测量变送器。测量电极和安装支架的正确选择是组成一个良好的、功能完备的测量系统的必要前提。     

上海市吴淞工业区大气PM2.5水溶成分的元素分析及细胞毒性研究

通过ICP-MS测定了上海市吴淞地区大气PM2.5水溶成分金属元素含量,通过四唑盐(MTT)测定细胞存活率,通过超氧化歧化酶(SOD)和丙二醛(MDA)两个指标测定细胞氧化损伤,琼脂糖凝胶电泳测定细胞内DNA损伤,流式细胞仪(Flow cytometry)检测细胞凋亡和周期等实验研究了大气PM2.5水溶成分的细胞毒性.实验结果表明:PM2.5可溶成分中Zn元素含量最高,PM2.5在一定浓度范围内能导致细胞死亡,引起细胞的氧化损伤,影响DNA的复制,阻碍细胞增殖,但没有诱导细胞凋亡.PM2.5中可溶金属离子对细胞毒性表现为联合作用.     

葛洲坝电站2号水轮机转轮室中环修复

针对葛洲坝电站2号机组运行中出现转轮室中环损坏的现象,设计制造出转轮室现场机加工的大型专用机床,在修复改造过程中,解决了一系列技术难题,改造后技术指标均达到理想水平,为电站机组现场修复技术积累了宝贵经验.     

Ab initio calculations on the mechanism of isobutane and 2-butene alkylation reaction catalyzed by hydrofluoric acid

Ab initio method was employed to determine the mechanism of alkylation reaction of 2-butene with isobutane. The results indicated that 2-butene is rapidly protonated to form sec-butyl carbonium ion, which then reacts with isobutane to form tert-butyl carbonium ion. The resulting carbonium ion is then deprotonated to form isobutene that reacts rapidly with tert-butyl carbonium ion to form trimethylpentane (TMP) carbonium ion. Finally, the TMP⁺ carbonium ion is converted to TMP via the hydride transfer process. The transition states of the interactions were obtained by using the SCAN method (a calculation key word for potential energy surface) first and then the intrinsic reaction coordinates were traced using the Gaussian program. In addition, the energy changes and geometric parameters of the interactions were analyzed. The computed results indicated that the energy barriers are close to or less than zero for the interaction of isobutane with protonated 2-butene or for the interaction of tert-butyl carbonium ion with isobutene, suggesting rapid reaction steps of the carbonium ions. The 2,2,3-TMP is kinetically controlled, while the formation of 2,2,4-TMP is controlled by reaction equilibrium. The calculated results were in good agreement with the experimental results.     

太钢3号卷取机TDC控制系统开发与应用

太钢热连轧厂3号卷取机改造前所采用的美国西屋公司WDPF控制系统已不能满足目前生产和质量的要求，进而应用西门子公司的TDC控制系统对其进行了改造。该项目的设计、编程、调试由太钢自行完成，改造中采用了带钢头部张力优化控制、夹送辊张力控制、卷取机平滑曲线减张控制、卸卷小车横移极限升降极限模拟控制等多项新技术。其改造后产品产量、综合成卷率和卷形良好率均明显提高。     

水利利用外资工作的几点思考

当前国内外经济形势的变化为我国水利利用外资工作创造了条件。同时在水利利用外资工作中还面临着国际金融组织赠款减少、外资项目配套资金和还贷能力不足、项目管理体制不顺等问题。结合新时期水利发展思路和外国政府、国际金融组织对华援助战略，提出了今后一个时期水利利用外资工作的重点领域。     

碾压混凝土筑坝施工技术综述

水电八局自20世纪80年代开始全面开展碾压混凝土性能试验及筑坝施工技术研究工作,于1993年建成了当时世界最高的RCC拱坝—普定拱坝(坝高75m),该工程在RCC材料、坝体防渗、坝体分缝、入仓工艺、模板和施工工艺方面都取得一些高水平成果,此后,又相继建成了大朝山、红坡、沙牌、索风营、大花水等20余座碾压混凝土坝。通过积极与国内科研院所合作完成了一系列的科研攻关工作,在八.五期间已取得重要成果的基础上,结合国家“九五“等科技攻关项目,总结摸索出了一套先进成熟的施工工艺。在研究和使用新技术、新材料、新工艺和新设备等方面,取得了一批突破性的科技成果,较好的解决了碾压混凝土施工技术难题。本文回顾和简要介绍了水电八局各时期碾压混凝土筑坝技术特点和施工技术创新成果。     

Experimental Study on Energy Consumption of Combined Conventional and Dehumidification Drying

Conventional drying, dehumidification drying, and combined conventional-dehumidification drying of wood were experimentally studied in this article. The results showed that the energy consumption in the dehumidification drying is the least but its drying time is the longest. The energy consumption in the combined drying is more than that in the dehumidification drying but less than that in the conventional drying, and the drying time is half of that in the dehumidification drying. The advantages of the combined conventional and dehumidification drying are discussed from the experiments results.     

MTC技术在百色盆地林逢稠油热采井的研究与应用

针对林逢稠油热采井的地质特点和对固井质量的要求开发了早期强度高,低渗透,微膨胀,抗高温和流变性好的MTC矿渣泥浆固化液,并分析了矿渣泥浆固化液技术的固化机理及特点。结果表明,MTC水泥浆具有低温防水侵,强度发展迅速,固化体耐高温的特性。MTC技术实用性强,施工简单,水泥浆体系流变性好,密度易于控制,它与钻井液有良好的相容性,提高了林逢稠油热采井的固井质量。     

Role of Pits in Corrosion Fatigue of Offshore Structural Steel

From the corrosion fatigue test under intermit-tent wetting condition for offshore structural steelof A537 cl.l and data analysis,some results associ-ated with the role of pits in fatigue process havebeen discussed.