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951.
952.
953.
针对5G毫米波通信,研制了一种双极化有源相控阵天线模组。厚度为2 mm的多层PCB正面印制阵列天线,在其背面集成多通道波束成形芯片,通过中间层实现天线与芯片的互连以及供电、控制等。测试结果表明,研制的板状4×4双极化相控阵模组在E面和H面均实现了不小于±40度的波束扫描范围(不大于3 dB的电平下降)和低于-18 dB的归一化交叉极化电平,在24~27.5 GHz的频率范围内实现了V极化和H极化分别为42.6~45.7 dBm和43.5~46.1 dBm的等效全向辐射功率(EIRP)。 相似文献
954.
低维材料嵌入微腔已经广泛应用于纳米激光器和探测器等。为了实现增益材料和光学微腔之间的有效耦合,需要深入研究嵌埋材料对腔共振模式的影响。本文主要讨论了嵌埋材料的厚度、位置、腔层厚度以及分布式布拉格反射镜的对数对腔供着模式的影响。结果表明,腔共振模式随嵌埋材料位置的不同呈现周期性变化并且在λ/2光程周期内存在最大峰位移。最大峰位移随腔层厚度增加而减小,但与嵌埋材料的厚度成正比。分布式布拉格反射镜的对数不影响腔共振模式。这些结果为光学器件的设计和实验现象的分析提供了指导,并且可以应用于不同波长分布式布拉格反射腔结构。 相似文献
955.
高分三号卫星是我国首颗分辨率达到1 m的C波段 多极化合成孔径雷达(synthetic aperture radar,SAR) 卫星,其中扫描 式合成孔径雷达(scan synthetic aperture radar,ScanSAR)模式是高分三号卫星重要的工 作模式之一,由于该模式的工作机制导致生成的图像可能发生扇贝效应,一般呈现为明暗相 间的条纹。本文针对高分三号卫星ScanSAR模式下存在的扇贝效应,提出自注意力机制与循 环一致对抗网络(cycle-consistent adversarial networks,CycleGAN)结合的模型对Scan S AR图像进行处理,从而抑制扇贝效应产生的条纹现象。本文所示方法与传统扇贝效应抑制方 法和深度学习相关算法进行比较,并通过亮度均值、平均梯度等指标进行分析。实验结果表 明,本文方法可以对高分三号ScanSAR图像存在的扇贝效应进行较好的处理,有效抑制图像 的条纹现象,使得图像质量得到提升,具有较大的实用意义。 相似文献
956.
Jiacheng Yin Na Li Ming Liu Zhigang Li Xuemin Wang Mingren Cheng Ming Zhong Wei Li Yunhua Xu Xian-He Bu 《Advanced functional materials》2023,33(21):2211950
Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g−1 at 300 mA g−1), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g−1), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO4 unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials. 相似文献
957.
Dovletgeldi Seyitliyev Xixi Qin Manoj K. Jana Svenja M. Janke Xiaowei Zhong Wei You David B. Mitzi Volker Blum Kenan Gundogdu 《Advanced functional materials》2023,33(21):2213021
Electron–phonon interactions play an essential role in charge transport and transfer processes in semiconductors. For most structures, tailoring electron–phonon interactions for specific functionality remains elusive. Here, it is shown that, in hybrid perovskites, coherent phonon modes can be used to manipulate charge transfer. In the 2D double perovskite, (AE2T)2AgBiI8 (AE2T: 5,5“-diylbis(amino-ethyl)-(2,2”-(2)thiophene)), the valence band maximum derived from the [Ag0.5Bi0.5I4]2– framework lies in close proximity to the AE2T-derived HOMO level, thereby forming a type-II heterostructure. During transient absorption spectroscopy, pulsed excitation creates sustained coherent phonon modes, which periodically modulate the associated electronic levels. Thus, the energy offset at the organic–inorganic interface also oscillates periodically, providing a unique opportunity for modulation of interfacial charge transfer. Density-functional theory corroborates the mechanism and identifies specific phonon modes as likely drivers of the coherent charge transfer. These observations are a striking example of how electron–phonon interactions can be used to manipulate fundamentally important charge and energy transfer processes in hybrid perovskites. 相似文献
958.
Chuanming Tian Bin Li Yichuan Rui Hao Xiong Yu Zhao Xuefei Han Xinliang Zhou Yu Qiu Wei An Kerui Li Chengyi Hou Yaogang Li Hongzhi Wang Qinghong Zhang 《Advanced functional materials》2023,33(41):2302270
Despite the outstanding power conversion efficiency (PCE) of perovskite solar cells (PSCs) achieved over the years, unsatisfactory stability and lead toxicity remain obstacles that limit their competitiveness and large-scale practical deployment. In this study, in situ polymerizing internal encapsulation (IPIE) is developed as a holistic approach to overcome these challenges. The uniform polymer internal package layer constructed by thermally triggered cross-linkable monomers not only solidifies the ionic perovskite crystalline by strong electron-withdrawing/donating chemical sites, but also acts as a water penetration and ion migration barrier to prolong shelf life under harsh environments. The optimized MAPbI3 and FAPbI3 devices with IPIE treatment yield impressive efficiencies of 22.29% and 24.12%, respectively, accompanied by remarkably enhanced environmental and mechanical stabilities. In addition, toxic water-soluble lead leakage is minimized by the synergetic effect of the physical encapsulation wall and chemical chelation conferred by the IPIE. Hence, this strategy provides a feasible route for preparing efficient, stable, and eco-friendly PSCs. 相似文献
959.
Shan Zhang Lina Wu Wenqiang Shi Junchang Qin Wei Feng Yu Chen Ruifang Zhang 《Advanced functional materials》2023,33(29):2302360
Photodynamic therapy (PDT) as a non-invasive strategy shows high promise in cancer treatment. However, owing to the hypoxic tumor microenvironment and light irradiation-mediated rapid electron–hole pair recombination, the therapeutic efficacy of PDT is dramatically discounted by limited reactive oxygen species (ROS) generation. Herein, a multifunctional theranostic nanoheterojunction is rationally developed, in which 2D niobium carbide (Nb2C) MXene is in situ grown with barium titanate (BTO) to generate a robust photo-pyroelectric catalyst, termed as BTO@Nb2C nanosheets, for enhanced ROS production, originating from the effective electron–hole pair separation induced by the pyroelectric effect. Under the second near-infrared (NIR-II) laser irradiation, Nb2C MXene core-mediated photonic hyperthermia regulates temperature variation around BTO shells facilitating the electron–hole spatial separation, which reacts with the surrounding O2 and H2O molecules to yield toxic ROS, achieving a synergetic effect by means of combinaterial photothermal therapy with pyrocatalytic therapy. Correspondingly, the engineered BTO@Nb2C composite nanosheets feature benign biocompatibility and high antitumor efficiency with the tumor-inhibition rate of 94.9% in vivo, which can be applied as an imaging-guided real-time non-invasive synergetic dual-mode therapeutic nanomedicine for efficient tumor nanotherapy. 相似文献
960.
Lisi Yang Shuaishuai Shen Xiang Chen Huan Wei Dongdong Xia Chaowei Zhao Ningfang Zhang Yuanyuan Hu Weiwei Li Hao Xin Jinsheng Song 《Advanced functional materials》2023,33(36):2303603
The electron transport layer (ETL) is a critical component in achieving high device performance and stability in organic solar cells. Conjugated polyelectrolytes (CPEs) have become an attractive alternative due to film-forming properties and ease of preparation. However, p-type CPEs generally exhibit poor charge mobility and conductivity, incorporation of electron-withdrawing units forming alternated D-A conjugated backbone can make up for these deficiencies. Herein, the ratio of electron withdrawing moieties are further increased and two poly(A1-alt-A2) typed PIIDNDI-Br and PDPPNDI-Br based on the combination of naphthalene diimide (NDI) with isoindigo (IID) or diketopyrrolopyrrole (DPP) via direct arylation polycondensation are synthesized. These CPEs possess excellent alcohol solubility, a suitable lowest unocuppied molecular orbital energy level, and work function tunability. Surprisingly, the incorporation of IID and DPP units generate distinct self-doping behaviors, which are confirmed by UV–vis absorption and ESR spectra. However, no matter doped or undoped, both CPEs present better charge-transporting properties and conductivity when utilized as ETLs. The PIIDNDI-Br and PDPPNDI-Br display good universal compatibility with the blend of PM6:Y6 and PM6:L8-BO, and PCEs of 18.32% and 18.36% are obtained, respectively, which also present excellent storage stability. In short, the combination of two different acceptors demonstrates an efficient strategy to design highly efficient ETLs for high performance photovoltaic devices. 相似文献