单苯环氯取代指数法预测二噁类化合物PCDDs的正辛醇/水分配系数

采用单苯环氯取代指数作为氯代二苯并二口恶口英类化合物 (PCDDs)的分子结构描述符 ,通过正向逐步线性回归方法建立了PCDDs的logKow与分子结构描述符之间的定量关系模型。与文献报道的MOD模型相比 ,该模型不仅具有显著的相关性 (n =43,Radj=0 898,SE =0 195 ,在α =0 0 5时 ,F =2 0 45 5 ,p =0 0 0 0 0 ) ,而且对于分子结构具有更好的区分能力。利用建立的模型 ,对没有logKow文献值的其他 33种PCDDs化合物给出了预测值     

在CORBA中实现异步调用

介绍了CORBA中的四种异步激发方式：多线程方式、单向异步激发方式、延迟同步激发方式以及异步方法调用方式,并讨论了各种异步激发方式的优缺点。     

基于有效裁剪被遮挡单元的非规则数据场体绘制算法

提出了一种被遮挡单元的裁剪算法,以加速非规则数据场的体绘制过程。在基于一组平行切割平面的体绘制方法上,新算法通过对图像不透明度缓冲区中的值进行求平均操作,并将所计算的结果存储在一个与不透明度缓冲区间同样大小的平均不透明度缓冲区中,使得只需根据每一数据单元重心投影点在平均不透明度缓冲区中的值,就可得到此数据单元的可见性,从而有效裁剪掉被遮挡单元,降低需处理的数据量,加速体绘制过程。     

原子吸收光谱法快速测定松香皂中几种金属元素

提出了用原子吸收光谱法快速测定松香皂中几种金属元素的方法。考察了元素干扰情况及灰化温度。该方法快速、简便、准确 ,RSD为 0 .95 %～ 2 .2 1% ,回收率为 95 .6 %～ 10 8.7%。     

Electrochemical investigtion of solubility and chemical diffusion of lithium in aluminum

The solubility of lithium in aluminum and the chemical diffusion coefficient in this solid solution have been investigated as a function of temperature between 400 and 600°C using the electrochemical cell: (-)A1, “LiAl”/LiCl-KCl(eut.)/Al(Li)(+) The solubility limit of lithium in aluminum was found to decrease from 13.8 at. pct at 595°C to 8.0 at. pct at 395°C, in good agreement with data previously reported by other investigators using different techniques. The chemical diffusion coefficient has been measured by two different electrochemical transient techniques. The data can be represented by the relation: 1 $$\tilde D = 0.155\exp (--\Delta H/RT)cm^2 /s$$ where ΔH is 119.2 kJ/mol. This electrochemical technique has also been used to obtain values of the composition dependence of the Gibbs free energy of mixing and the enhancement factor d lna_Li/dlnX_Li which relates the chemical diffusion coefficient and the self diffusion coefficients within the Li-Al solid solution.     

膜催化反应器的分析与模拟

分析了膜反应器的出现、发展和最新研究。论述了几种膜反应器中气体的传递机理,定量分析了膜反应器中控制传递与反应的模型方程式以及计算机模拟和实验研究结果。最后评价了两类膜反应器的操作特性,以⊿n<0、⊿n=0和⊿n>0三类不同的催化反应作为模型反应与传统的PFR 和 MFR 的操作特性作了对比。     

Low-frequency wide-band hybrid energy harvester based on piezoelectric and triboelectric mechanism

Recently,hybrid energy harvester has been considered as an attractive potential approach to response the worldwide energy crisis due to the combination of advantages from different harvesting mechanism.In this paper,a novel low-frequency wide-band hybrid energy harvester based on piezoelectric and triboelectric mechanism is presented and systematically studied including structural design,fabrication process,working principle simulation and measurement.With a vibrational excitation,the polyvinylidene fluoride(PVDF) cantilevers will vibrate and impact the polydimethylsiloxane(PDMS) film on the substrate,producing a piezoelectric output as well as a triboelectric output.The structural parameters of each cantilever are optimized using finite element simulation,and the well-designed PVDF cantilevers with controllable PDMS mass not only reduce the device working frequency but also enlarge the bandwidth.Under a sweep-frequency test,three voltage peaks induced by the piezoelectric part are observed at 15,32.5 and 47.5 Hz,with the value of 320,288 and 264 mV,respectively.With the combined triboelectric part,a 20 V peak-peak voltage is generated at 15 Hz.The electrical driving ability of this hybrid energy harvester also has been demonstrated by lighting up a commercial light emitting diode(LED).     

A very sensitive ion collection device for plasma-laser characterization

In this paper a very sensitive ion collection device, for diagnostic of laser ablated-target plasma, is described. It allows for reducing down to few microvolts the signal threshold at digital scope input. A standard ion collector is coupled to a transimpedance amplifier, specially designed, which increases data acquisition sensitivity by a gain ≈1100 and does not introduce any significant distortion of input signal. By time integration of current intensity, an amount of charge as small as 2.7 × 10(-2) pC can be detected for photopeak events.     

基于ABAQUS真空联合覆水预压法仿真模拟与分析

以龙湾燃煤电厂V-3区采用真空联合覆水预压处理软土地基工程为基础,利用大型通用有限元ABAQUS程序中的孔压边界条件模拟真空荷载,运用二维固结有限元进行模拟,分析其在真空联合覆水预压过程中的沉降情况以及超孔压分布情况,对类似工程有借鉴和指导意义。     

石墨化炉的供电特点及发展趋势

通过对石墨化炉的特点及其供电方面的有关问题的分析，论述了石墨化炉供电的特点及其发展的趋势，并对石墨化炉在交、直流电源供电方面提出了看法，以不断提高石墨化炉供电的设计水平．