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31.
Cu2O/ x Cu ( x =0–25 wt%) cermets were evaluated as a novel partially inert anode for aluminum (Al) production. The physical and mechanical properties, including the compressive strength, flexural strength, thermal expansion coefficient, thermal conductivity, and dc electrical conductivity were tested at room temperature and at temperatures up to 950°C. The coefficient of thermal expansion, compressive strength, flexural strength, thermal conductivity, and electrical conductivity of Cu2O/Cu cermets increased with increasing Cu content. High-temperature electrical conductivity measurements showed that with increasing temperature, the electrical conductivity increased when the Cu content was below the percolation threshold, while it decreased when the Cu content was above the percolation threshold. A relatively stable CuAlO2 layer formed on the cermet surface during electrochemical testing, and the corrosion rate of this anode was estimated to be about 1.8–1.9 cm/year in Al production.  相似文献   
32.
顺酐化SBS的钠离聚体形式与丙烯酰胺的乳液接枝共聚   总被引:2,自引:0,他引:2  
研究了顺酐化SBS的钠离聚体与丙烯酸胺以过氧化苯甲酰为引发剂的乳液聚合,得到了共聚的较佳条件.并以IR及DSC表征了试样的组成和多相结构.  相似文献   
33.
ABSTRACT

In this research, the effect of particle size on the surface oxidation and flotation behavior of galena in the lime system was studied. Coarse (?0.074 + 0.038 mm), intermediate (?0.038 + 0.025 mm) and fine (?0.025 mm) galena particles were used in the experiment. The dissolution tests, flotation tests, and sorption tests were accomplished. Through further analysis by XPS, the effect of particle size and lime was observed. The decrease of mineral particle sizes increased the adsorption ratio of collector and the dissolution of galena, while the hydrophilic product OH?/Ca(OH)+ produced by dissolution occupied the dominant position, which led to the minerals hydrophilic.  相似文献   
34.
本文论述了炼焦工艺的现状和发展方向,分析了存在的问题,提出了一种全新的连续型混热式冶金焦炉结构及其工艺流程,为焦化工业的发展探讨了一条新的途径。  相似文献   
35.
Synthesis of Biodiesel from Soybean Oil using Heterogeneous KF/ZnO Catalyst   总被引:7,自引:0,他引:7  
Biodiesel was produced by transesterification of soybean oil with methanol using ZnO loaded with KF as a solid base catalyst. It was found that the catalyst with 15 wt.% KF loading and calcined at 873 K showed the optimum activity. XRD, IR and Hammett indicator method were employed for the catalyst characterization. The results showed the activity of the catalysts was correlated with their basicity. The influence of various reaction variables on the conversion was also discussed.  相似文献   
36.
Fan Xie  Wei Yu  Defeng Wu 《Polymer》2005,46(19):8410-8415
In this study, the reaction kinetics of asymmetric polymer-polymer interface was experimentally and theoretically studied. A new rheological method correlating the change of rheological property of reactive system with the conversion of the in situ formed copolymers was applied to study the reaction kinetics of PBT/epoxy reactive system. Then, the new method was proved to be useful by comparing its results with that obtained from the conventional endgroup determination method. Moreover, the conversion of PBT/epoxy reactive system from rheological method could be well fitted by the numerical analysis, from which the kinetic constant and the diffusion constant of epoxy in PBT could be determined simultaneously.  相似文献   
37.
Reactive dyes have almost complete exhaustion and ideal fixation on aminated polyepichlorohydrin pretreated silk without addition of salt or alkali. The effects of varying pretreatments and dyeing conditions were studied. The dyeing behaviour of CI Reactive Red 15 on modified silk under pH 6 was investigated. Dyeings of modified silk showed good wash fastness, dry and wet rub fastnesses as well as light fastness. The quality of the dyed silks obtained after pretreatment was shown to be satisfactory and the dyeing effluent was less polluted.  相似文献   
38.
Well-crystallized bismuth tungstate (Bi2WO6) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi2WO6 powder mainly depends on the different reaction temperatures and the weight ratio of LiNO3–NaNO3 salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.  相似文献   
39.
Supported Vanadia Catalysts for Dehydrogenation of Ethylbenzene with CO2   总被引:1,自引:0,他引:1  
Alumina supported vanadia catalysts (V/Al) for selective oxidehydrogenation of ethylbenzene with CO2 were prepared by impregnation method. During preparation the effect of promoters and calcined temperature was investigated, it was found these two items had a strong influence on the activity of V/Al catalysts. Dehydrogenation reaction with CO2 was happened in the fixed-bed reactor at 450 °C. Results showed that 15.2% ethylbenzene conversion and 99.2% styrene selectivity were acquired when V2K/Al catalyst was used.  相似文献   
40.
A three-dimensional model is proposed for both furnace-side and wall-side heat transfer in circulating fluidized beds with membrane walls. Following previous publications (Int. J. Heat Mass Transfer (2003a, b)), a core-annulus flow structure is employed in the model, with consideration of the membrane wall influence on bed hydrodynamics. The model couples radiation, conduction and convection on the furnace side to conduction and convection on the wall side. Radiation in the wall layer is simulated by the moment method. A finite-element method is employed to solve the set of non-linear, partial differential equations. The solution is demonstrated for a typical example. The model gives predictions of suspension-to-wall heat transfer which show satisfactory agreement with published experimental data.  相似文献   
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