The electrochemical water splitting to produce H
2 in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)
2 heterostructure is formed at the surface.
In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)
2 heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)
2 amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)
2 interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H
2-evolving current density of 10 mA/cm
2 and 153 mV at 100 mA/cm
2, as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and
in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)
2 heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)
2 interface reducing the energy barrier of H1 adsorption thus promoting the HER performance.
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