低熔点合金填充聚合物材料断口形貌研究

研究了合金元素、加工温度、金属含量、第三组分对低熔点金属填充聚合物材料断口形貌的影响。实验结果表明:不同的合金对体系的影响很大,低分子量、低结晶性聚合物,高的成型加工温度可提高材料的相容性。     

普钙产品转化率的数值计算方法

对影响普钙产品转化率的各种因素进行了分析,利用MATLAB 软件包得到了转化率的计算公式,提出了确定未分解磷矿的比例和由倍半氧化物引起的有效磷退化幅度的方法,为生产系统的预测和调整提供了一种途径。     

金平水电站坝型比选研究

根据金平水电站坝址的水文气象和地形地质条件等基本资料,对砾石土心墙堆石坝和沥青混凝土心墙堆石坝进行技术经济比较。沥青混凝土心墙堆石坝防渗土料工程量小,施工环节少,占用土地少,环境影响小,施工技术成熟,工程投资省745万元,故采用了沥青混凝土心墙堆石坝方案,金平水电站已投产发电,运行良好。     

On the behaviour of tin-containing species in cryolite–alumina melts

Tin oxide (SnO2) dissolves in cryolite–alumina melts forming tetravalent tin species, but under reducing conditions it is reduced to divalent tin and, further, to metallic tin. Freezing point depression data for SnF2 and SnO in molten cryolite (Na3AlF6) corresponded to the formation of one and two new particles, respectively. By anodic dissolution of tin into cryolite-alumina melts divalent as well as tetravalent tin was formed, depending on current density and composition. During electrolysis of SnO2-based oxygen-evolving anodes, the condensate above the melt contained both divalent (SnF2) and tetravalent (SnO2) tin species.     

HT-730改性酚醛-丁腈胶粘剂的研制

对酚醛-丁腈胶粘剂进行改性，添加5．0％的硅烷偶联剂，改善了酚醛-丁腈胶粘剂的工艺性能，提高了粘接强度，特别是降低了酚醛-丁腈胶对环境湿度的敏感性。研制的HT-730胶在环境湿度90％时仍有很高的粘接强度，同时老化性能和适用期并没有受到影响。     

Synthesis and characterization of copolythiophene

Copolythiophenes (Co‐PTs), poly(3‐hexylthiophene‐co‐3‐thiophene carboxylic acid) (P3HT‐TCa), poly(3‐hexyloxylthiophene‐co‐3‐thiophene carboxylic acid) (P3HOT‐TCa), and poly(3‐phenylthiophene‐co‐3‐thiophene carboxylic acid) (P3PhT‐TCa), were synthesized by chemical oxidized polymerization to investigate the effect of copolymerization on the properties of polythiophenes (PTs). Gel permeation chromatography showed that the molecular weight (MW) of Co‐PT was lower than that of homopolythiophene. Fourier transform infrared (FTIR) spectra indicated that the copolymerization was successful between the monomers. The λ_max of Co‐PTs gave a “blue shift” in ultraviolet‐visible (UV‐VIS) spectra. Photoluminescence (PL) spectra showed that the PL intensity of Co‐PT became weaker than that of homopolythiophene and the disappearance of PL had been observed in P3HOT‐TCa. The thermal stability of Co‐PT was influenced by the carboxyl for its low decomposition temperature. Furthermore, the copolymerization between multi‐wall carbon nanotube containing thiophene ring (MWNT‐Th) and 3‐hexyloxylthiphene could also take place successfully. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

非木本木质素磺酸镁对水泥净浆和砂浆性能的影响

用红外光谱法等测定了非木本木质素磺酸镁的结构特征参数,研究了其对水泥净浆和砂浆性能的影响,并与木本木质素磺酸钙进行了对比。非木本木质素磺酸镁结构中的甲基、酚羟基、芳香环比木质素磺酸钙少;特性黏度为 0. 61mL/g,仅是木质素磺酸钙的 61%;磺化度为 0 78mmol/g,比木质素磺酸钙低约 40%。木质素磺酸镁溶液的最低表面张力为 49 82mN/m,起泡性能与木质素磺酸钙相近。非木本木质素磺酸镁对水泥净浆和砂浆减水分散作用为木本木质素磺酸钙的 86 6% ~91 1%。但掺质量分数 0 5%的木质素磺酸镁的砂浆, 28d的抗压强度比掺木质素磺酸钙的高 70 5%。     

一种新的S/PDIF接收机数据译码的实现方法

论文分析了S/PDIF音频数据流的特点,引入模式识别中的训练机对S/PDIF音频数据流进行现场脉冲宽度特征提取。依据训练机结果建立分类器实现脉冲宽度分类,根据脉冲宽度进行同步前置码和逻辑电平的解码。利用硬件描述语言Verilog进行设计实现与验证,仿真结果说明这种特征提取方法可以提高S/PDIF接收机数据解译码的适应性和准确性。     

冷冻凝聚工艺生产CR322的研制

对原电解质凝聚工艺生产CR322(混合调节型氯丁橡胶)进行了改进，实现了冷冻凝聚新工艺法生产切块CR322，即主乳化剂由松香皂／脂肪酸皂复合型代替了单一松香皂。新工艺解决了冷冻转鼓装置生产CR322过程中“黏杆”及干胶门尼黏度控制等问题。产品无焦烧粒子。且焦烧时间明显延长。     

PBT共混改性研究最新进展

综述了最近几年国内外聚对苯二甲酸丁二醇酯(PBT)共混改性的研究进展,分类介绍PBT/聚烯烃、PBT/同系聚酯、PBT/液晶、PBT/弹性体、PBT/聚碳酸酯等不同共混体系,讨论了各体系中的相行为、相容性、热稳定性、力学性能等,并对该类共混物的发展趋势作了简要的分析。