Highly efficient white organic light-emitting devices based on a multiple-emissive-layer structure

Characteristics of white organic light-emitting devices based on phosphor sensitized fluorescence are improved by using a multiple-emissive-layer structure, in which a phosphorescent blue emissive layer is sandwiched between red and green&yellow ones. In this device, bis[(4,6–difluorophenyl)–pyridinato–N,C²] (picolinato), bis(2,4–diphenyl–quinoline) iridium (III) acetylanetonate, fac tris (2-phenylpyridine) iridium, and 5,6,11,12–tetraphenylnaphthacene are used as blue, red, green, and yellow emitters, respectively. The device has a maximum luminance of more than 30,000 cd/m², a maximum luminous efficiency of 27 cd/A, a maximum external quantum efficiency of 12.4%, and a color rendering index of 81 at 100 cd/m².     

Effect of particle size distribution on green properties during high velocity compaction

Iron powders with two different particle size distributions were compacted by high velocity compaction. The influences of particle size distribution and impact velocity on green properties, including green density, springback, tensile strength and bending strength etc., were studied with scanning electron microscopy (SEM) and a computer controlled universal testing machine. The results show that the particle size distribution and the impact velocity strongly affect its properties. Wider size distribution results in green compact with higher density and better strength. Furthermore, springback of compacts is lower produced by the powder with wider size distribution, especially for radial springback. As impact velocity increases, its green density and green strength gradually increases, but the increasing rate of density decreases gradually. No special relation is found between springback and impact velocity. In addition, the axial springback and the bending strength are higher than the radial springback and the tensile strength, respectively.     

P(MMA-AN)/TiO2复合粒子的制备及光催化性能

采用原位乳液聚合方法制备了基于共价键结合的P(MMA-AN)/TiO2复合粒子,红外光谱和热失重分析结果表明P(MMA-AN)在TiO2表面接枝率为15.9%。以甲基橙溶液为目标污染物,研究了P(MMA-AN)/TiO2复合粒子和TiO2对甲基橙的吸附和光催化降解甲基橙溶液的性能,结果表明:两种粒子对甲基橙的吸附都很少;在相同时间内,P(MMA-AN)/TiO2复合粒子对甲基橙溶液的降解性能优于TiO2,紫外光照180 min后,P(MMA-AN)/TiO2复合粒子对甲基橙溶液的降解率达到了88%,而TiO2仅为74%。     

Leukocyte‐Repelling Biomimetic Immunomagnetic Nanoplatform for High‐Performance Circulating Tumor Cells Isolation

Downstream studies of circulating tumor cells (CTCs), which may provide indicative evaluation information for therapeutic efficacy, cancer metastases, and cancer prognosis, are seriously hindered by the poor purity of enriched CTCs as large amounts of interfering leukocytes still nonspecifically bind to the isolation platform. In this work, biomimetic immunomagnetic nanoparticles (BIMNs) with the following features are designed: i) the leukocyte membrane camouflage, which could greatly reduce homologous leukocyte interaction and actualize high‐purity CTCs isolation, is easily extracted by graphene nanosheets; ii) facile antibody conjugation can be achieved through the “insertion” of biotinylated lipid molecules into leukocyte‐membrane‐coated nanoparticles and streptavidin conjunction; iii) layer‐by‐layer assembly techniques could integrate high‐magnetization Fe₃O₄ nanoparticles and graphene nanosheets efficiently. Consequently, the resulting BIMNs achieve a capture efficiency above 85.0% and CTCs purity higher than 94.4% from 1 mL blood with 20–200 CTCs after 2 min incubation. Besides, 98.0% of the isolated CTCs remain viable and can be directly cultured in vitro. Moreover, application of the BIMNs to cancer patients' peripheral blood shows good reproducibility (mean relative standard deviation 8.7 ± 5.6%). All results above suggest that the novel biomimetic nanoplatform may serve as a promising tool for CTCs enrichment and detection from clinical samples.     

High-performance flat-panel solar thermoelectric generators with high thermal concentration

The conversion of sunlight into electricity has been dominated by photovoltaic and solar thermal power generation. Photovoltaic cells are deployed widely, mostly as flat panels, whereas solar thermal electricity generation relying on optical concentrators and mechanical heat engines is only seen in large-scale power plants. Here we demonstrate a promising flat-panel solar thermal to electric power conversion technology based on the Seebeck effect and high thermal concentration, thus enabling wider applications. The developed solar thermoelectric generators (STEGs) achieved a peak efficiency of 4.6% under AM1.5G (1 kW m(-2)) conditions. The efficiency is 7-8 times higher than the previously reported best value for a flat-panel STEG, and is enabled by the use of high-performance nanostructured thermoelectric materials and spectrally-selective solar absorbers in an innovative design that exploits high thermal concentration in an evacuated environment. Our work opens up a promising new approach which has the potential to achieve cost-effective conversion of solar energy into electricity.     

All Inorganic Halide Perovskites Nanosystem: Synthesis,Structural Features,Optical Properties and Optoelectronic Applications

The recent success of organometallic halide perovskites (OHPs) in photovoltaic devices has triggered lots of corresponding research and many perovskite analogues have been developed to look for devices with comparable performance but better stability. Upon the preparation of all inorganic halide perovskite nanocrystals (IHP NCs), research activities have soared due to their better stability, ultrahigh photoluminescence quantum yield (PL QY), and composition dependent luminescence covering the whole visible region with narrow line‐width. They are expected to be promising materials for next generation lighting and display, and many other applications. Within two years, a lot of interesting results have been observed. Here, the synthesis of IHPs is reviewed, and their progresses in optoelectronic devices and optical applications, such as light‐emitting diodes (LEDs), photodetectors (PDs), solar cells (SCs), and lasing, is presented. Information and recent understanding of their crystal structures and morphology modulations are addressed. Finally, a brief outlook is given, highlighting the presently main problems and their possible solutions and future development directions.     

Greatly Enhanced Anticorrosion of Cu by Commensurate Graphene Coating

Metal corrosion is a long‐lasting problem in history and ultrahigh anticorrosion is one ultimate pursuit in the metal‐related industry. Graphene, in principle, can be a revolutionary material for anticorrosion due to its excellent impermeability to any molecule or ion (except for protons). However, in real applications, it is found that the metallic graphene forms an electrochemical circuit with the protected metals to accelerate the corrosion once the corrosive fluids leaks into the interface. Therefore, whether graphene can be used as an excellent anticorrosion material is under intense debate now. Here, graphene‐coated Cu is employed to investigate the facet‐dependent anticorrosion of metals. It is demonstrated that as‐grown graphene can protect Cu(111) surface from oxidation in humid air lasting for more than 2.5 years, in sharp contrast with the accelerated oxidation of graphene‐coated Cu(100) surface. Further atomic‐scale characterization and ab initio calculations reveal that the strong interfacial coupling of the commensurate graphene/Cu(111) prevents H₂O diffusion into the graphene/Cu(111) interface, but the one‐dimensional wrinkles formed in the incommensurate graphene on Cu(100) can facilitate the H₂O diffusion at the interface. This study resolves the contradiction on the anticorrosion capacity of graphene and opens a new opportunity for ultrahigh metal anticorrosion through commensurate graphene coating.     

K-NN与SVM相融合的文本分类技术研究

提出了一种改进的K-NN(K Nearest Neighbor)与SVM(Support Vector Machine)相融合的文本分类算法。该算法利用文本聚类描述K-NN算法中文本类别的内部结构,用sigmoid函数对SVM输出结果进行概率转换,同时引入CLA(Classifier’s Local Accuracy)技术进行分类可信度分析以实现两种算法的融合。实验表明该算法综合了K-NN与SVM在分类问题中的优势,既有效地降低了分类候选的数目,又相应地提高了文本分类的精度,具有较好的性能。     

超声波流量测量技术及发展

本文叙述了超声波流量测量的原理、基本测量方法以及传统的多普勒和时差法超声波流量计的缺陷和测量局限性，分析了超声波流量测量最新进展所采取的新的测量技术和方法，并介绍了超声波相关流量计的原理和技术特点．